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Volume 34
Main Index

Issue 1


A Novel Layered Mixed-Valence Vanadium Phenanthroline Complex: Hydrothermal Synthesis and Crystal Structure of [VIVVV2O7(phen)]n
Chung-ying Duan, Yu-peng Tian, Zhong-lin Lu, Xiao-zeng You, and Xiao-ying Huang
pp 1 - 2; DOI:
10.1021/ic00105a001
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Photodriven Energy Transfer from Cuprous Phenanthroline Derivatives
Felix N. Castellano, Mark Ruthkosky, and Gerald J. Meyer
pp 3 - 4; DOI:
10.1021/ic00105a002
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Samarium(II) Surrounded by Only Oxygen Donor Ligands: [KSm(.mu.-OC6H2But2-2,6-Me-4)3(THF)]n
William J. Evans, Reiner Anwander, Mohammad A. Ansari, and Joseph W. Ziller
pp 5 - 6; DOI:
10.1021/ic00105a003
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Os(phen)2(dppz)2+: A Red-Emitting DNA Probe
R. Erik Holmlin and Jacqueline K. Barton
pp 7 - 8; DOI:
10.1021/ic00105a004
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An Organoimido Derivative of the Hexatungstate Cluster: Preparation and Structure of [W6O18(NAr)]2- (Ar = 2,6-(i-Pr)2C6H3)
Thomas R. Mohs, Glenn P. A. Yap, Arnold L. Rheingold, and Eric A. Maatta
pp 9 - 10; DOI:
10.1021/ic00105a005
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Use of 2,2'-Biphosphinines for the Stabilization of Reduced Transition Metal Species: Electrochemical Reduction of Bis(2,2'-biphosphinine)nickel(0)
Pascal e LeFloch, Louis Ricard, Francois Mathey, Anny Jutand, and Christian Amatore
pp 11 - 12; DOI:
10.1021/ic00105a006
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Per- and Polyfluoroaryl Mono- and Disiloxanes as Transfer Reagents in the Synthesis of Highly Fluorinated Mono- and Diethers
Nimesh R. Patel, Jianguo Chen, Robert L. Kirchmeier, and Jean'ne M. Shreeve
pp 13 - 17; DOI:
10.1021/ic00105a007
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Gas-Phase Reactions of Dicoordinated Boron Cations with Alcohols
Thilini D. Ranatunga and Hilkka I. Kenttaemaa
pp 18 - 27; DOI:
10.1021/ic00105a008
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Chemistry of Borohydride Reduction of Iron(II) and Iron(III) Ions in Aqueous and Nonaqueous Media. Formation of Nanoscale Fe, FeB, and Fe2B Powders
George N. Glavee, Kenneth J. Klabunde, Christopher M. Sorensen, and George C. Hadjipanayis
pp 28 - 35; DOI:
10.1021/ic00105a009
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Photoinduced Intramolecular Electron Transfer in 1,2,4,5-Tetrakis(diphenylphosphino)benzene-Bridged OsII-MII Dimetallic Complexes (M = Ni, Pd, Pt)
Pei-Wei Wang and Marye Anne Fox
pp 36 - 41; DOI:
10.1021/ic00105a010
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31P NMR Studies on Sulfur/Oxygen-Bridged Incomplete Cubane-Type Molybdenum Cluster Compounds. X-ray Structures of [Mo3OS3(DTP)4(CH3CN)] and [Mo3OS3(OAc)(DTP)2(Py)2(OC2H5)]
Yuangen Yao, Haruo Akashi, Genta Sakane, Takashi Shibahara, and Hitoshi Ohtaki
pp 42 - 48; DOI:
10.1021/ic00105a011
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Synthesis and Characterization of the New Selenolate Ligand -SeC6H3-2,6-Mes2 (Mes = C6H2-2,4,6-Me3) and Its Two-Coordinate Zinc and Manganese Derivatives: Factors Affecting Bending in Two-Coordinate Metal Complexes with Aryl-Substituted Ligands
Jeffrey J. Ellison, Karin Ruhlandt-Senge, Hakon H. Hope, and Philip P. Power
pp 49 - 54; DOI:
10.1021/ic00105a012
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Iridium .mu.-Imido/Amido A-Frame Complexes
Changqing Ye and Paul R. Sharp
pp 55 - 59; DOI:
10.1021/ic00105a013
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Trans Influence of Phosphines on Dimer-Monomer Interconversion of 2-Pyridinethiolate Complexes: Structures of [Pd(.mu.-.eta.2-pyS-N,S)Cl(L)]2 (L = PMe2Ph, PMePh2) and Pd(.eta.2-pyS)Cl(PPh3)
Mukta Gupta, Roger E. Cramer, Kachum Ho, Christina Pettersen, Staffany Mishina, Jack Belli, and Craig M. Jensen
pp 60 - 65; DOI:
10.1021/ic00105a014
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.kappa.2-.kappa.3 Isomerism in Rhodium(I) Tris(pyrazolyl)borate Complexes of the Type Tp3R,4R,5RRh(LL) (LL = 2CO, COD, and NBD) and Their Dynamic Behavior in Solution. X-ray Crystal Structure of TpMeRh(NBD)
Urs E. Bucher, Antonio Currao, Reinhard Nesper, Heinz Rueegger, Luigi M. Venanzi, and Elizabeth Younger
pp 66 - 74; DOI:
10.1021/ic00105a015
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Syntheses, Structures, and Spectroscopic Properties of Gold(I) Complexes of 1,3,5-Triaza-7-phosphaadamantane (TPA). Correlation of the Supramolecular Au.cntdot. .cntdot. .cntdot.Au Interaction and Photoluminescence for the Species (TPA)AuCl and [(TPA-HCl)AuCl]
Zerihun Assefa, Brain G. McBurnett, Richared J. Staples, John P. Fackler, Bernd Assmann, Klaus Angermaier, and Hubert Schmidbaur
pp 75 - 83; DOI:
10.1021/ic00105a016
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Control of the Bridgehead Donor Atom in the Tripodal Ligand over Oxidative Addition of Au(PPh3)+ to [X(CH2CH2PPh2)3RhH] (X = N, P). X-ray Diffraction and Multinuclear (103Rh, 31P, 1H) NMR Studies
Claudio Bianchini, Cornelis J. Elsevier, Jan M. Ernsting, Maurizio Peruzzini, and Fabrizio Zanobini
pp 84 - 92; DOI:
10.1021/ic00105a017
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Hexadentate N4O2 Amine Phenol Complexes of Gallium and Indium
Ernest Wong, Shuang Liu, Thomas Luegger, F. Ekkehardt Hahn, and Chris Orvig
pp 93 - 101; DOI:
10.1021/ic00105a018
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An Unusual Near-Eclipsed Porphyrin Ring Orientation in Two Crystalline Forms of (.mu.-Oxo)bis[(octaethylporphinato)iron(III)]. Structural and Molecular Mechanics Studies
Beisong Cheng, J. David Hobbs, Peter G. Debrunner, Jonah Erlebacher, John A. Shelnutt, and W. Robert Scheidt
pp 102 - 110; DOI:
10.1021/ic00105a019
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Oxidative Addition Reactions to Novel Heterotrinuclear Iridium Complexes with Mixed Bridging Ligands. Crystal Structure of [{Ir(.mu.-pz)(.mu.-StBu)I2(CO)[P(OMe)3]}2Pd]
M. Teresa Pinillos, Anabel Elduque, Eduardo Martin, Nuria Navarro, Fernando J. Lahoz, Jose A. Lopez, and Luis. A. Oro
pp 111 - 115; DOI:
10.1021/ic00105a020
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Antimony(V) and Bismuth(V) Methyl Compounds: A Structural Comparison
Stephan Wallenhauer and Konrad Seppelt
pp 116 - 119; DOI:
10.1021/ic00105a021
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Properties and Structures of Thallium(I) Derivatives of Aromatic Diols
Ahmed A. El-Hadad, James E. Kickham, Stephen J. Loeb, Lorena Taricani, and Dennis G. Tuck
pp 120 - 123; DOI:
10.1021/ic00105a022
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Synthesis and Spectroscopic Characterization of O-Alkyl Dithiocarbonate (Xanthate) Derivatives of Dimethyl- and Diphenyltellurium(IV). Crystal Structures of Me2Te[S2COEt]2 and Ph2Te[S2COEt]2
Jane H. E. Bailey, John E. Drake, Layla N. Khasrou, and Jincai Yang
pp 124 - 133; DOI:
10.1021/ic00105a023
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Structural and Spectroscopic Properties of Antiferromagnetically Coupled FeIIIMnII and FeIIMnII Complexes
Theodore R. Holman, Zhigang Wang, Michael P. Hendrich, and Lawrence Que
pp 134 - 139; DOI:
10.1021/ic00105a024
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Synthesis and Crystal Structure of [guanidinium][Ni(dmit)2]2 and [1,1-dimethylguanidinium][Ni(dmit)2]2 (dmit = 2-Thioxo-1,3-dithiole-4,5-dithiolate). Intermolecular Orbital Overlap Calculations and Electrical Conductivities
Yvonne S. J. Veldhuizen, Nora Veldman, Anthony L. Spek, Christophe Faulmann, Jaap G. Haasnoot, and Jan Reedijk
pp 140 - 147; DOI:
10.1021/ic00105a025
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Synthesis, Structure and Reactivity of Some Functionalized Zinc and Copper(II) Phosphonates
Stephanie Drumel, Pascal Janvier, Philippe Barboux, Martine Bujoli-Doeuff, and Bruno Bujoli
pp 148 - 156; DOI:
10.1021/ic00105a026
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Alternating Ferro- and Antiferromagnetic Interactions in Unusual Copper(II) Chains
Giovanni De Munno, Miguel Julve, Francesc Lloret, Juan Faus, Michel Verdaguer, and Andrea Caneschi
pp 157 - 165; DOI:
10.1021/ic00105a027
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La4Ti5Si4-xPxO22 (x = 0, 1): A New Family of Two-Dimensional Solids. Synthesis and Structure of the First Member (m = 1) of the Mixed-Valence Titanium(III/IV) Oxosilicate Series, La4Ti(Si2O7)2(TiO2)4m
Shumin Wang and Shiou-Jyh Hwu
pp 166 - 171; DOI:
10.1021/ic00105a028
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The P,T-State Diagram and Solid Phase Synthesis of Aluminum Hydride
Sergei K. Konovalov and Boris M. Bulychev
pp 172 - 175; DOI:
10.1021/ic00105a029
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Trioxorhenium and Trioxotechnetium as Strong Acceptor Groups. 3. Charge Transfer and Bonding Energetics in O3M-M(CO)5 (M = Re,Tc)
Miquel Costas, Josep M. Poblet, Marie-Madeleine Rohmer, and Marc Benard
pp 176 - 183; DOI:
10.1021/ic00105a030
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Cr4+ in Tetrahedral Coordination of Oxidic Solids: A Spectroscopic and Structural Investigation
D. Reinen, U. Kesper, M. Atanasov, and J. Roos
pp 184 - 192; DOI:
10.1021/ic00105a031
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Electronic and structural investigations of technetium compounds by x-ray absorption spectroscopy
Ilham Almahamid, Jeffrey C. Bryan, Jerome J. Bucher, Anthony K. Burrell, Norman M. Edelstein, Eric A. Hudson, Nikolas Kaltsoyannis, Wayne W. Lukens, Heino Nitsche, and et al.
pp 193 - 198; DOI:
10.1021/ic00105a032
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Intermolecular Forces in Porphyrin Crystals
Wenhua Chen and Jan A. K. Paul
pp 199 - 201; DOI:
10.1021/ic00105a033
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Antitumor Active Platinum Blue Complexes: Syntheses and Solution Behaviors of 3,3-Dimethylglutarimidate- and Glutarimidate-Bridged Platinum Blue Complexes and Their Reactions with 5'-Guanosine Monophosphate
Jun Matsunami, Hiroshi Urata, and Kazuko Matsumoto
pp 202 - 208; DOI:
10.1021/ic00105a034
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Complexation of Manganese(II) by Cyclohexano-15-crown-5 in Propylene Carbonate: Calorimetric and X-ray Crystallographic Investigation
Yanpei Deng, John H. Burns, and Bruce A. Moyer
pp 209 - 213; DOI:
10.1021/ic00105a035
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Kinetics of H2 Dissociation from Some Iridium-Dihydrogen Complexes with Structurally Different (H2) Ligands
Vladimir I. Bakhmutov, Evgenii V. Vorontsov, and Alexey B. Vymenits
pp 214 - 217; DOI:
10.1021/ic00105a036
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Magnetic Circular Dichroism and Electron Paramagnetic Resonance Studies of Cobalt-Substituted Horse Liver Alcohol Dehydrogenase
Mark T. Werth, Syou-Fen Tang, Grazyna Formicka, Michael Zeppezauer, and Michael K. Johnson
pp 218 - 228; DOI:
10.1021/ic00105a037
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Copper(III) Complexes of Tripeptides with Histidine and Histamine as the Third Residue
Michael R. McDonald, William M. Scheper, Hsiupu D. Lee, and Dale W. Margerum
pp 229 - 237; DOI:
10.1021/ic00105a038
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Theoretical Study of the Relativistic Effects on the Bonds between HfCl3 and H and between ThCl3 and H
Egbert M. Wezenbeek, Evert Jan Baerends, and Tom Ziegler
pp 238 - 246; DOI:
10.1021/ic00105a039
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Structures of Gas Phase Oligomeric Gold-Oxygen-Hydrogen Negative Ions Formed by Cesium Ion Bombardment of Vapor-Deposited Gold Surfaces
Gerard Bolbach, Dennis E. Main, Kenneth G. Standing, and John B. Westmore
pp 247 - 253; DOI:
10.1021/ic00105a040
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Synthesis, Structure and Properties of Five-Coordinate Copper(II) Complexes of Pentadentate Ligands with Pyridyl Pendant Arms
Grant A. McLachlan, Gary D. Fallon, Raymond L. Martin, and Leone Spiccia
pp 254 - 261; DOI:
10.1021/ic00105a041
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The Bicyclic Structure of a Novel TMEDA-Solvated Lithium Chloride Tetramer [(LiCl)4.cntdot.3.5TMEDA]2: X-ray Structural Analysis and MO Investigations
Daniele Hoffmann, Andrea Dorigo, Paul von Schleyer, Hubert Reif, Dietmar Stalke, George M. Sheldrick, Erwin Weiss, and Maren Geissler
pp 262 - 269; DOI:
10.1021/ic00105a042
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A Comprehensive Study of Exchange Coupling in a Macrocyclic Binuclear Copper(II) Complex in the Solid and Solution States
Pravat K. Mandal, Kamalaksha Nag, and P. T. Manoharan
pp 270 - 277; DOI:
10.1021/ic00105a043
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Metal Hydride vs SIDE-ON .sigma.-Bonded Trichlorosilane Complexes of Arene-Chromium Derivatives: (.eta.6-Arene)Cr(CO)(H)2(SiCl3)2
Balaji R. Jagirdar, Roger Palmer, Kenneth J. Klabunde, and Lewis J. Radonovich
pp 278 - 283; DOI:
10.1021/ic00105a044
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Synthesis, Spectroscopy, Bonding and Structure in Phosphido Bridged Bimetallics Derived from Bent Metallocenes of Molybdenum and Tungsten and from Group 6 Metal Carbonyls
Christophe Barre, Patrick Boudot, Marek M. Kubicki, and Claude Moiese
pp 284 - 291; DOI:
10.1021/ic00105a045
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Reactivity of Deprotonated Mn2(.mu.-H)(.mu.-PCyH)(CO)8: Valence Isomerization and Rearrangement of Mn2(AuPR3)2(.mu.4-PCy)(CO)8 and Mn2(.mu.-AuPR3)(.mu.3-PCy(AuPR3))(CO)8 (R = Ph, p-C6H4F, p-C6H4OMe, Cy, Et, (CH2)2CN)
H.-J. Haupt, M. Schwefer, and U. Floerke
pp 292 - 297; DOI:
10.1021/ic00105a046
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Synthesis and Characterization of Three Novel Selenidohexacobalt Carbonyl Clusters. Crystal Structures of [(.mu.3-Se)Co3(CO)7]2.mu.4-(Se2) and Co6(.mu.3-Se)8(Co)6.cntdot.2C6H6
G. Gervasio, S. F. A. Kettle, F. Musso, R. Rossetti, and P. L. Stanghellini
pp 298 - 305; DOI:
10.1021/ic00105a047
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.pi.-Arene Aqua Complexes of Cobalt, Rhodium, Iridium, and Ruthenium: Preparation, Structure, and Kinetics of Water Exchange and Water Substitution
Lynda Dadci, Horst Elias, Urban Frey, Andreas Hoernig, Ulrich Koelle, Andre E. Merbach, Helmut Paulus, and Jens Stefan Schneider
pp 306 - 315; DOI:
10.1021/ic00105a048
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Electrochemical And IR Spectroelectrochemical Investigations of the Series Mo(CO)6-n(CNR)n (n = 1-6) (R = 2,6-Dimethylphenyl): In situ Observation of fac-mer and cis-trans Isomerizations
Leslie J. Lyons, Stephanie L. Pitz, and David C. Boyd
pp 316 - 322; DOI:
10.1021/ic00105a049
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Transition Metal Rimmed-Calixresorcinarene Complexes
Wei Xu, Jonathon P. Rourke, Jagadese J. Vittal, and Richard J. Puddephatt
pp 323 - 329; DOI:
10.1021/ic00105a050
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X-ray Crystallographic Study of the Complexes Cr(PCl3)(CO)5, W(PCl3)(CO)5, Cr(PBr3)(CO)5, W(PBr3)(CO)5 and Mo(PMe3)(CO)5: Insight into .pi.-Acceptance by Phosphorus
Murray S. Davies, Manuel J. Aroney, Irmi E. Buys, Trevor W. Hambley, and Jane L. Calvert
pp 330 - 336; DOI:
10.1021/ic00105a051
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Synthesis and Reactivity of [Fe3(CO)9Te]2-
Lisa C. Roof, Donna M. Smith, Gregory W. Drake, William T. Pennington, and Joseph W. Kolis
pp 337 - 345; DOI:
10.1021/ic00105a052
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Temperature-Dependent Axial Ligation Changes and Photoreduction of Iron-Protoporphyrin-IX Dimethyl Ester Chloride at Low Temperatures Monitored by Resonance Raman Technique
N. K. Chaudhury, G. S. S. Saini, and A. L. Verma
pp 346 - 349; DOI:
10.1021/ic00105a053
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Interactions of Enantiomeric Ruthenium (II) Complexes with Polynucleotides as Studied by Circular Dichroism, Electric Dichroism Measurements, and Photolysis
Kyaw Naing, Masayuki Takahashi, Masahiro Taniguchi, and Akihiko Yamagishi
pp 350 - 356; DOI:
10.1021/ic00105a054
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Effect of Ligand Constraints upon the Stabilities and Potentials of Macrocyclic Polythiaether Complexes. Copper(II) and Copper(I) Complexes with Cyclohexyl and Phenyl Derivatives of [14]aneS4 in Water, 80% Methanol, and Acetonitrile
Luciana Aronne, Brian C. Dunn, James R. Vyvyan, Chad W. Souvignier, Michael J. Mayer, Turner A. Howard, Cynthia A. Salhi, Scott N. Goldie, L. A. Ochrymowycz, and D. B. Rorabacher
pp 357 - 369; DOI:
10.1021/ic00105a055
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Electrochemical and Spectroscopic Characterization of {Ta6Cl12}z+ Chloride Clusters in Acetonitrile and in The Aluminum Chloride-1-Methyl-3-ethylimidazolium Chloride Molten Salt
Charles L. Hussey, Robert Quigley, and Kenneth R. Seddon
pp 370 - 377; DOI:
10.1021/ic00105a056
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Square pyramidal clusters in La3In5 and Y3In5. La3In5 as a metallic Zintl phase
Jing-Tai Zhao and John D. Corbett
pp 378 - 383; DOI:
10.1021/ic00105a057
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Stereochemistry and Stability of Free and Coordinated Secondary Phosphines. Crystal and Molecular Structure of [S-[(R*,R*),(R*)]]-(+)589-[PtCl{1,2-C6H4(PMePh)2}(PHMePh)]PF6.cntdot.CH2Cl2
Armin Bader, Trevor Nullmeyers, Michael Pabel, Geoffrey Salem, Anthony C. Willis, and S. Bruce Wild
pp 384 - 389; DOI:
10.1021/ic00105a058
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Single-Crystal X-ray Structure of C60.cntdot.6SbPh3. A Well-Ordered Structure of C60 and a New Fullerene Solvent
Milan Fedurco, Marilyn M. Olmstead, and W. Ronald Fawcett
pp 390 - 392; DOI:
10.1021/ic00105a059
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Crystal Structures and Spectra of Two Forms of Chloro(triphenylarsine)gold(I)
B. Weissbart, L. J. Larson, M. M. Olmstead, C. P. Nash, and D. S. Tinti
pp 393 - 395; DOI:
10.1021/ic00105a060
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Hard/Soft Interactions in Early Transition Metal Thioether Macrocyclic Chemistry: Synthesis and Single Crystal Structure of cis-[CrCl2([14]aneS4)]PF6 ([14]aneS4 = 1,4,8,11-tetrathiacyclotetradecane)
Neil R. Champness, Sarah R. Jacob, Gillian Reid, and Christopher S. Frampton
pp 396 - 398; DOI:
10.1021/ic00105a061
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New Bonding Mode for Cyanoacetylene: A Tungsten(II) Fluoride Carbonyl Complex in Which Cyanoacetylene Serves as a Four-Electron Donor Alkyne Ligand
Jaqueline L. Kiplinger, Atta M. Arif, and Thomas G. Richmond
pp 399 - 401; DOI:
10.1021/ic00105a062
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Iron(III)-Promoted Hydrolysis of 4-Nitrophenyl Phosphate
Novelette P. Sadler, Chin-Chia Chuang, and Ronald M. Milburn
pp 402 - 404; DOI:
10.1021/ic00105a063
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Molecular Structure and Electronic Properties of Oxomolybdenum(V) Catecholate Complexes
Partha Basu, Michael A. Bruck, Zheng Li, Ish K. Dhawan, and John H. Enemark
pp 405 - 407; DOI:
10.1021/ic00105a064
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Oxalate and 2,2'-Bipyrimidine as Useful Tools in Designing Layered Compounds
Giovanni e De Munno, Rafael Ruiz, Francesc Lloret, Juan Faus, Roberta Sessoli, and Miguel Julve
pp 408 - 411; DOI:
10.1021/ic00105a065
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Visible and near-IR spectroscopic studies of uranium(IV) oxychloride in a MgCl2-KCl melt
S. Dai, L. M. Toth, G. D. Del Cul, and D. H. Metcalf
pp 412 - 413; DOI:
10.1021/ic00105a066
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Synthesis, Characterization, and Halogenation of Decakis(acetoxymercurio)osmocene. Crystal and Molecular Structure of Decachloroosmocene
Sally A. Kur, Arnold L. Rheingold, and Charles H. Winter
pp 414 - 416; DOI:
10.1021/ic00105a067
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Oxidized and Reduced [Fe2Q2] (Q = S, Se) Cores of Spinach Ferredoxin: a Comparative Study Using 1H NMR Spectroscopy
Stefano Benini, Stefano Ciurli, and Claudio Luchinat
pp 417 - 420; DOI:
10.1021/ic00105a068
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Issue 2


Synthesis of the New Asymmetric Tripodal Amine Ligand abap: Crystal Structure of [Co(abap)(O2NO)](ClO4)2 and Stability and Reactivity of [Co(abap)(OH2)2]3+ toward Phosphate Esters
Rachel L. Fanshawe and Allan G. Blackman
pp 421 - 423; DOI:
10.1021/ic00106a001
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Photochemistry and C-H Bond Activation Reactivity of (HBPz*3)Rh(CO)2 (Pz* = 3,5-Dimethylpyrazolyl) in Hydrocarbon Solution
Agus A. Purwoko and Alistair J. Lees
pp 424 - 425; DOI:
10.1021/ic00106a002
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The Trimetallic Cation [Hg2Pt(CH2P(S)Ph2)4]2+ in [Hg2Pt(CH2P(S)Ph2)4]X2, X = BPh4-, PF6- An Isoelectronic Analog of Au2Pt(CH2P(S)Ph2)4
Thomas F. Carlson, John P. Jr. Fackler, Richard J. Staples, and Richard E. P. Winpenny
pp 426 - 431; DOI:
10.1021/ic00106a003
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Structure and Bonding of a Novel Mercuracycle Complex Containing B-Hg Bonds at Carborane Vertices
Zhiping Zheng, Carolyn B. Knobler, Carol E. Curtis, and M. Frederick Hawthorne
pp 432 - 435; DOI:
10.1021/ic00106a004
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Synthesis, structural characterization, and properties of new single and double cubanes containing the MoFe3S4 structural unit and molybdenum-bound polycarboxylate ligands. Clusters with a molybdenum-coordination environment similar to that in the iron-molybdenum cofactor of nitrogenase
Konstantinos D. Demadis and Dimitri Coucouvanis
pp 436 - 448; DOI:
10.1021/ic00106a005
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Solvent-Dependent Ester Elimination and Ligand Exchange Reactions between Trimethylsilyl Acetate and Tin(IV) Tetra-tert-Butoxide
James Caruso, Christophe Roger, Fritz Schwertfeger, Mark J. Hampden-Smith, Arnold L. Rheingold, and Glenn Yap
pp 449 - 453; DOI:
10.1021/ic00106a006
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Polynuclear Copper-Lanthanide Complexes with Amino Alcohol Ligands. Syntheses, Structures, and Magnetic and Spectroscopic Studies of CuII(bdmmp)2(H2O), PrIIICuII(bdmmp)(bdmmpH)(.mu.-OH)(hfacac)3, [LaIIICuII(bdmmp)(bdmmpH)(.mu.-OH)(O2CCF3)3]2, and CuII4(bdmmp)2(.mu.4-O)(O2CCF3)4, (bdmmpH = 2,6-Bis[(dimethylamino)methyl]-4-methylphenol; hfacac = Hexafluoroacetylacetonato)
Liqin Chen, Steven R. Breeze, Roger J. Rousseau, Suning Wang, and Laurence K. Thompson
pp 454 - 465; DOI:
10.1021/ic00106a007
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Oxo-Vanadium(IV) Dimer of 3-Hydroxy-3-methylglutarate: X-ray Crystal Structure, Solid State Magnetism, and Solution Spectroscopy
Stephanie L. Castro, Marion E. Cass, Frederick J. Hollander, and Stuart L. Bartley
pp 466 - 472; DOI:
10.1021/ic00106a008
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Influence Of Electronic Delocalization In Metal-to-Ligand Charge Transfer Excited States
Geoffrey F. Strouse, Jon R. Schoonover, Richard Duesing, Stephen Boyde, Wayne E. Jr. Jones, and Thomas J. Meyer
pp 473 - 487; DOI:
10.1021/ic00106a009
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.pi.-Stabilized, yet Reactive, Half-Sandwich Cp*Ru(PR3)X Compounds: Synthesis, Structure, and Bonding
Todd J. Johnson, Kirsten Folting, William E. Streib, James D. Martin, John C. Huffman, Sarah A. Jackson, Odile Eisenstein, and Kenneth G. Caulton
pp 488 - 499; DOI:
10.1021/ic00106a010
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Local Order and Metal-Metal Bonding in Li2MoO3, Li4Mo3O8, LiMoO2, and H2MoO3, Determined from EXAFS Studies
S. J. Hibble and I. D. Fawcett
pp 500 - 508; DOI:
10.1021/ic00106a011
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Electron Transfer. 124. Oxidations of Trinuclear Tungsten Cations
Manik C. Ghosh, S. Mandal, S. K. Chandra, and E. S. Gould
pp 509 - 512; DOI:
10.1021/ic00106a012
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Kinetics and Mechanism for Reduction of Tetrachloroaurate(III), trans-Dicyanodichloraurate(III), and trans-Dicyanodibromoaurate(III) by Sulfite and Hydrogen Sulfite
Johan Berglund and Lars I. Elding
pp 513 - 519; DOI:
10.1021/ic00106a013
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Solid-State Tetramer vs. Solution-State Dimer. Reinvestigation of [Ag2(OAc)2(dppm)]2 and Its dppm Addition Product [Ag(OAc)(dppm)]2 (dppm = Ph2PCH2PPh2)
Soh Ping Neo, Zhong-Yuan Zhou, Thomas C. W. Mak, and T. S. Andy Hor
pp 520 - 523; DOI:
10.1021/ic00106a014
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[(Co(H2O)4)2(H2W12O42)]n6n-: A Novel Chainlike Heteropolyanion Formed by Paradodecatungstate and Cobalt(II) Ions
Carlos Gimenez-Saiz, Jose Ramon Galan-Mascaros, Smaiel Triki, Eugenio Coronado, and Lahcene Ouahab
pp 524 - 526; DOI:
10.1021/ic00106a015
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Issue 3


Synthesis and Characterization of (Imido)titanium(IV) Porphyrin Complexes. X-ray Structure of (Phenylimido)(tetratolylporphyrinato)titanium(IV)
Lisa M. Berreau, Victor G. Young, and L. Keith Woo
pp 527 - 529; DOI:
10.1021/ic00107a001
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Drastic Structural Change in Silver(I) Complexes with Alteration of the Optical Activity of a Pyridine Derivative Ligand: Helical Arrays with Extended Structure and an Optically Inactive Dinuclear Complex
Takayoshi Suzuki, Hiyoshizo Kotsuki, Kiyoshi Isobe, Narimasa Moriya, Yuichi Nakagawa, and Masamitsu Ochi
pp 530 - 531; DOI:
10.1021/ic00107a002
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Synthesis, Characterization, and Electrochemical Behavior of (5,10,15-Tri-X-phenyl-2,3,7,8,12,13,17,18-octamethylcorrolato)cobalt(III) Triphenylphosphine Complexes, Where X = p-OCH3, p-CH3, p-Cl, m-Cl, o-Cl, m-F, or o-F
Victor A. Adamian, Francis D'Souza, Silvia Licoccia, Maria Luisa Di Vona, Emanuela Tassoni, Roberto Paolesse, Tristano Boschi, and Karl M. Kadish
pp 532 - 540; DOI:
10.1021/ic00107a003
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Absorption Spectra, Luminescence Properties, and Electrochemical Behavior of Cyclometalated Iridium(III) and Rhodium(III) Complexes with a Bis(pyridyl)triazole Ligand
Giuseppe Calogero, Gaetano Giuffrida, Scolastica Serroni, Vittorio Ricevuto, and Sebastiano Campagna
pp 541 - 545; DOI:
10.1021/ic00107a004
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Proton-Coupled Electron Transfer in Acetonitrile Solution. Irreversible Disproportionation of [RuIII(bpy)2(py)(OH)]2+
Robert A. Binstead, Laura K. Stultz, and Thomas J. Meyer
pp 546 - 551; DOI:
10.1021/ic00107a005
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Synthesis and Selectivity in Metal Ion Coordination of the New Ligands 1,4,7-Trimethyl-1,7-bis(4-carboxybenzyl)-1,4,7-triazaheptane (L) and 1,4,7,16,19,22-Hexamethyl-1,4,7,16,19,22-hexaaza[9.9]paracyclophane (L1). Crystal Structures of [PdLH2Cl]NO3.cntdot.3H2O and [Cu2L1Cl2](BPh4)(ClO4).cntdot.CH3CN
Carla Bazzicalupi, Andrea Bencini, Antonio Bianchi, Vieri Fusi, Claudia Giorgi, Piero Paoletti, Annalisa Stefani, and Barbara Valtancoli
pp 552 - 559; DOI:
10.1021/ic00107a006
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Kinetics and Mechanism of Oxygen Exchange and Inversion along the M:O Axis in the Diprotonated and Monoprotonated Dioxotetracyanometalate Complexes of Re(V), Tc(V), W(IV), and Mo(IV)
Andreas Roodt, Johann G. Leipoldt, Lothar Helm, Amira Abou-Hamdan, and Andre E. Merbach
pp 560 - 568; DOI:
10.1021/ic00107a007
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Octaazacryptand Complexation of the Fluoride Ion
Sean D. Reilly, Guru Rattan K. Khalsa, Doris K. Ford, James R. Brainard, Benjamin P. Hay, and Paul H. Smith
pp 569 - 575; DOI:
10.1021/ic00107a008
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Structural Diversity in Solvated Lanthanide Halide Complexes
William J. Evans, Julie L. Shreeve, Joseph W. Ziller, and Robert J. Doedens
pp 576 - 585; DOI:
10.1021/ic00107a009
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Trans-Cis Isomerization in [Os(tpy)(Cl)2(N)]+
Darryl S. Williams, George M. Coia, and Thomas J. Meyer
pp 586 - 592; DOI:
10.1021/ic00107a010
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Synthetic and Structural Studies on trans-Tetrapyridine Complexes of Ruthenium(II)
Benjamin J. Coe, Thomas J. Meyer, and Peter S. White
pp 593 - 602; DOI:
10.1021/ic00107a011
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Properties of Fluoroformyl Hypofluorite, FC(O)OF, Revisited
G. A. Argueello, G. Balzer-Joellenbeck, B. Juelicher, and H. Willner
pp 603 - 606; DOI:
10.1021/ic00107a012
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Lithioboranes. A Theoretical Study
Matthias Wagner, Nicolaas J. R. van Eikema Hommes, Heinrich Noeth, and Paul v. R. Schleyer
pp 607 - 614; DOI:
10.1021/ic00107a013
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Gas-Phase Chelation Reactions of Monopositive Cations with Heteroaromatic Ligands
Hui-Fen Wu and Jennifer S. Brodbelt
pp 615 - 621; DOI:
10.1021/ic00107a014
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Linkage Isomerization Equilibria in (Chloranilato)palladium(II) Complexes with Amine Ligands. Crystal Structure of (Chloranilato)bis(acetonitrile)palladium(II)
Andrew J. Bessire, Bruce R. Whittlesey, and Robert A. Holwerda
pp 622 - 627; DOI:
10.1021/ic00107a015
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Single-Source Precursors of Lead Titanate: Synthesis, Molecular Structure and Reactivity of Pb2Ti2(.mu.4-O)(.mu.3-O-i-Pr)2(.mu.-O-i-Pr)4(O-i-Pr)4
Stephane Daniele, Renee Papiernik, Liliane G. Hubert-Pfalzgraf, Susan Jagner, and Mikael Hakansson
pp 628 - 632; DOI:
10.1021/ic00107a016
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Novel Contrast Agents for Magnetic Resonance Imaging. Synthesis and Characterization of the Ligand BOPTA and Its Ln(III) Complexes (Ln = Gd, La, Lu). X-ray Structure of Disodium (TPS-9-145337286-C-S)-[4-Carboxy-5,8,11-tris(carboxymethyl)-1-phenyl-2-oxa- 5,8,11-triazatridecan-13-oato(5-)]gadolinate(2-) in a Mixture with Its Enantiomer
Fulvio Uggeri, Silvio Aime, Pier Lucio Anelli, Mauro Botta, Marino Brocchetta, Christoph de Haeen, Giuseppe Ermondi, Maurizio Grandi, and Paola Paoli
pp 633 - 643; DOI:
10.1021/ic00107a017
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Effects of Ortho-Substituents in the Synthesis and Stability of Cyclomanganated Benzylamine Derivatives. X-ray Crystal Structure of Mn{C6H2(OCH3)2-4,6-CH2NMe2-2}(CO)4
Michel Pfeffer, Esteban P. Urriolabeitia, and Jean Fischer
pp 643 - 650; DOI:
10.1021/ic00107a018
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Selenoether Macrocyclic Chemistry: Syntheses, NMR Studies, Redox Properties, and Single-Crystal Structures of [M([16]aneSe4)](PF6)2.cntdot.2MeCN (M = Pd, Pt; [16]aneSe4 = 1,5,9,13-Tetraselenacyclohexadecane)
Neil R. Champness, Paul F. Kelly, William Levason, Gillian Reid, Alexandra M. Z. Slawin, and David J. Williams
pp 651 - 657; DOI:
10.1021/ic00107a019
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Carbon-Sulfur Bond Formation on the Disulfide Bridging Ligand of a Dinuclear Ruthenium Compound in the Reaction with Acetone
Kazuko Matsumoto, Hiroyuki Uemura, and Masaki Kawano
pp 658 - 662; DOI:
10.1021/ic00107a020
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Electronic Structure of the 16 Valence Electron Fragments M(CO)3(PR3)2 (M = Mo, W; R = iPr, Cy) in Their Complexes with H2, THF, and Three .pi.-Conjugated Dinucleating Ligands: Electrochemistry and Spectroscopy of Different Oxidation States
Wolfgang Bruns, Wolfgang Kaim, Eberhard Waldhoer, and Michael Krejcik
pp 663 - 672; DOI:
10.1021/ic00107a021
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Coordination Properties of Silver Diphosphine Complexes. Crystal and Molecular Structures of Ag2X2(m-PP)2 (X = I, Cl, NO3; m-PP = 1,3-Bis[(diphenylphosphino)methyl]benzene) and Ag2X2(o-PP)2 (X = I, Cl; o-PP = 1,2-Bis[(diphenylphosphino)methyl]benzene). Synthesis and 1H- and 31P-NMR Spectroscopy of Silver Diphosphine Complexes
Francesco Caruso, Mercedes Camalli, Heinrich Rimml, and Luigi M. Venanzi
pp 673 - 679; DOI:
10.1021/ic00107a022
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1H NMR Studies of the Imidazole Complex of Cytochrome c: Resonance Assignment and Structural Characterization of the Heme Cavity
Weiping Shao, Hongzhe Sun, Yiming Yao, and Wenxia Tang
pp 680 - 687; DOI:
10.1021/ic00107a023
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Spectroscopic and Electronic Structure Studies of met-Hemerythrin Model Complexes: A Description of the Ferric-Oxo Dimer Bond
Carl A. Brown, Glenn J. Remar, Ronald L. Musselman, and Edward I. Solomon
pp 688 - 717; DOI:
10.1021/ic00107a024
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Novel Reactions of Iron(III) Tetraphenylporphyrin .pi.-Cation Radicals with Pyridine
Krystyna Rachlewicz and Lechoslaw Latos-Grazynski
pp 718 - 727; DOI:
10.1021/ic00107a025
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Structure of Dicopper Complexes of N,N,N',N'-Tetrakis[(2-benzimidazolyl)methyl]-2-hydroxy-1,3-diaminopropane with Chloride Counterions
Weng Feng Zeng, Cheu Pyeng Cheng, Sung Mao Wang, Ming-Chu Cheng, Gene-Hsian Lee, and Yu Wang
pp 728 - 736; DOI:
10.1021/ic00107a026
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Paramagnetic NMR spectroscopy and coordination structure of cobalt(II) Cys112Asp azurin
Mario Piccioli, Claudio Luchinat, Tadashi J. Mizoguchi, Benjamin E. Ramirez, Harry B. Gray, and John H. Richards
pp 737 - 742; DOI:
10.1021/ic00107a027
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Metal Complexes of Benzene Derivatives. 45. Dinuclear Bis(.eta.6-arene)vanadium and -chromium Complexes Containing 1,3-Disilacyclobutane as a Spacer. An EPR Study of Intermetallic Communication
Christoph Elschenbroich, Annette Bretschneider-Hurley, James Hurley, Andreas Behrendt, Werner Massa, Sigrid Wocadlo, and Edward Reijerse
pp 743 - 745; DOI:
10.1021/ic00107a028
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Isolation and Characterization of Anionic Titanium Tris(glycolate) Complexes
G. J. Gainsford, T. Kemmitt, C. Lensink, and N. B. Milestone
pp 746 - 748; DOI:
10.1021/ic00107a029
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Synthesis of New Neutral and Cationic Phosphido-Bridged Dinuclear Platinum(II) Hydrides
Piero Leoni, Silvia Manetti, and Marco Pasquali
pp 749 - 752; DOI:
10.1021/ic00107a030
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Molecular and Crystal Structure of a Binuclear .mu.-Acetato-Coupled ZnN3-Zn Porphyrin, N3 = Bis(2-picolyl)amine: Synthetic Approach To Model the Cytochrome c Oxidase Active Site
Nilkamal Bag, Shuenn-Shing Chern, Shie-Ming Peng, and C. K. Chang
pp 753 - 756; DOI:
10.1021/ic00107a031
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Issue 4


A New Class of Layered Microporous Materials: Crystal Structure of Disodium Pentakis(trimethylphenylammonium) Bis[tris(oxalato(2-))chromate(III)] Chloride Pentahydrate
Rodney P. Farrell, Trevor W. Hambley, and Peter A. Lay
pp 757 - 758; DOI:
10.1021/ic00108a001
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Do Poly(indazolyl)borates Have Abnormal Regiochemistry?
Arnold L. Rheingold, Glenn Yap, and Swiatoslaw Trofimenko
pp 759 - 760; DOI:
10.1021/ic00108a002
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Complexes of New Electrochemically-Active p-Quinonyl-/p-hydroquinonylphosphines: Multiple Electron/Proton Transfer Reactions and Electrochemical/pH Control of p-Quinonyl-/p-Hydroquinonyl o-Oxygen Atom Coordination
Seri Bima Sembiring, Stephen B. Colbran, and Donald. C. Craig
pp 761 - 762; DOI:
10.1021/ic00108a003
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Molecular and Crystal Structures of New Binuclear Thiooxalate-Bridged Complexes: (.mu.-Trithiooxalato-S,S':S',S'')bis[bis(triphenylphosphine)silver(I)], the First Verified Simultaneously End-on/Side-on Coordinated Thiooxalate, and (.mu.-1,1-Dithiooxalato-S,O:S',O')bis[bis(triphenylphosphine)metal(I)] (Metal = Copper, Silver)
P. Strauch, W. Dietzsch, L. Golic, J. Sieler, A. Franke, I. Muenzberg, K. Truebenbach, R. Kirmse, J. Reinhold, and E. Hoyer
pp 763 - 766; DOI:
10.1021/ic00108a004
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Trisubstituted Heteropolytungstates as Soluble Metal-Oxide Analogs. Isolation and Characterization of [(C5Me5)Rh.cntdot.P2W15Nb3O62]7- and [(C6H6)Ru.cntdot.P2W15Nb3O62]7-, Including the First Crystal Structure of a Dawson-Type Polyoxoanion-Supported Organometallic Complex
Matthias Pohl, Yin Lin, Timothy J. R. Weakley, Kenji Nomiya, Masahiko Kaneko, Heiko Weiner, and Richard G. Finke
pp 767 - 777; DOI:
10.1021/ic00108a005
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Crystal Structure and Spectroscopic and Magnetic Properties of Two Novel Mono(.mu.-halo) Copper(II) Chains with an Unusual Zigzag Arrangement: [Cu(C13H13N3)X]PF6 (X = Cl, Br)
Roberto Cortes, Luis Lezama, J. I. Ruiz de Larramendi, Gotzon Madariaga, J. Luis Mesa, F. Javier Zuniga, and Teofilo Rojo
pp 778 - 786; DOI:
10.1021/ic00108a006
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Aqueous Peroxynitric Acid (HOONO2): A Novel Synthesis and Some Chemical and Spectroscopic Properties
Evan H. Appelman and David J. Gosztola
pp 787 - 791; DOI:
10.1021/ic00108a007
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1,1,3,3-Tetraoxopolyfluoro-1,3-dithiacycloalkanes. CH2SO2(CF2)nSO2 (n = 2-5) and 2-Substituted Derivatives
Shi-Zheng Zhu, William T. Pennington, and Darryl D. DesMarteau
pp 792 - 795; DOI:
10.1021/ic00108a008
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A Novel Route to Dinuclear Heteroleptic Rhodium(III) Complexes of 1,4,7-Trithiacyclononane
Hyun-Joon Kim, Jin-Ho Lee, Il-Hwan Suh, and Youngkyu Do
pp 796 - 801; DOI:
10.1021/ic00108a009
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Lipid Peroxidation by Synthetic Analogs of Iron Bleomycin: Possible Role of a Low-spin {Hydroperoxo}iron(III) Intermediate in Lipid Peroxidation Induced by Bleomycin
Richard J. Guajardo and Pradip K. Mascharak
pp 802 - 808; DOI:
10.1021/ic00108a010
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Electrochemistry of Nonplanar Zinc(II) Tetrakis(pentafluorophenyl)porphyrins
Julia A. Hodge, Michael G. Hill, and Harry B. Gray
pp 809 - 812; DOI:
10.1021/ic00108a011
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Oxo-Bridged Linear Diosmium Complexes with Unsymmetric Ligand Environment. Structures of the Diosmium(IV,IV) Complex, [(py)2Cl2(CH3COO)Os(.mu.-O)Os(py)2Cl3] (py = pyridine) and Its Mixed-Valence (III,IV) Analog
Yoichi Imbe, Keisuke Umakoshi, Chikako Matsunami, and Yoichi Sasaki
pp 813 - 820; DOI:
10.1021/ic00108a012
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Ground- and Excited-State Properties of Ruthenium(II) Complexes Containing Tridentate Azine Ligands, Ru(tpy)(bpy)L2+, Where L Is a Polymerizable Acetylene
Seth C. Rasmussen, Silvia E. Ronco, Debra A. Mlsna, Mark A. Billadeau, William T. Pennington, Joseph W. Kolis, and John D. Petersen
pp 821 - 829; DOI:
10.1021/ic00108a013
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Formation of Antiferromagnetic Heteronuclear Thiolate- and Sulfide-Bridged Complexes. 3. Preparation, Magnetic Properties, and Structures of Cr2W Clusters and Nitrosylchromium Complexes
Igor L. Eremenko, Stephan Rosenberger, Sergei E. Nefedov, Heinz Berke, and Vladimir M. Novotortsev
pp 830 - 840; DOI:
10.1021/ic00108a014
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Induced Internal Electron Transfer Chemistry in Rhenium Sulfide Systems
Henry H. Murray, Liwen Wei, Suzanne E. Sherman, Mark A. Greaney, Kenneth A. Eriksen, Barbara Carstensen, Thomas R. Halbert, and Edward I. Stiefel
pp 841 - 853; DOI:
10.1021/ic00108a015
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Steric and Electronic Effects on Ligand Substitution of Cationic Carbonyl Nitrosyl Complexes of Molybdenum(0) Containing Bis(3,5-dimethylpyrazol-1-yl)methane-N,N'
Kom-Bei Shiu, Sheng-Ting Lin, Dei-Wei Fung, Tsung-Jung Chan, Shie-Ming Peng, Ming-Chu Cheng, and J. L. Chou
pp 854 - 863; DOI:
10.1021/ic00108a016
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Luminescence Properties of Terbium(III) Complexes with 4-Substituted Dipicolinic Acid Analogs
Jagannath B. Lamture, Z. Hong Zhou, A. Suresh Kumar, and Theodore G. Wensel
pp 864 - 869; DOI:
10.1021/ic00108a017
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Structure and Physical Properties of the Tetraphenylphosphonium-[Ni(dmit)2]3 (dmit = 2-thioxo-1,3-dithiol-4,5-dithiolate) Salt
Takayoshi Nakamura, Allan E. Underhill, A. Treeve Coomber, Richard H. Friend, Hiroyuki Tajima, Akiko Kobayashi, and Hayao Kobayashi
pp 870 - 876; DOI:
10.1021/ic00108a018
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Synthesis, Characterization, and Crystal Structure of a Vanadium(V)-Vanadium(IV)-Vanadium(V) Mixed-Valence Trinuclear Complex with a Tridentate Quinato Ligand, (NH4)2{[VV(O)2]2[VIV(O)](.mu.-(-)-quinato(3-))2}.cntdot.H2O
Rachel Codd, Trevor W. Hambley, and Peter A. Lay
pp 877 - 882; DOI:
10.1021/ic00108a019
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Basic Properties of Mg2+1-xAl3+x Layered Double Hydroxides Intercalated by Carbonate, Hydroxide, Chloride, and Sulfate Anions
Vera R. L. Constantino and Thomas J. Pinnavaia
pp 883 - 892; DOI:
10.1021/ic00108a020
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Synthesis Optimization and Crystal Structures of Layered Metal(IV) Hydrogen Phosphates, .alpha.-M(HPO4)2.cntdot.H2O (M = Ti, Sn, Pb)
Sebastian Bruque, Miguel A. G. Aranda, Enrique R. Losilla, Pascual Olivera-Pastor, and Pedro Maireles-Torres
pp 893 - 899; DOI:
10.1021/ic00108a021
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Synthesis and Properties of the Sodium Lithium Silicate Silinaite
Klaus Beneke, Peter Thiesen, and Gerhard Lagaly
pp 900 - 907; DOI:
10.1021/ic00108a022
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Decomposition and Cycloaddition Reactions of hfacac, and Syntheses and Structures of LnIII2(hfacac)4(bdmap)2(H2O)2(THF)2, LnIIICuII(bdmapH)2(hfacac)2(O2CCF3)L, and LnIIICuII2(hfacac)(bdmap)3(O2CCH3)2(O2CCF3)(hfacacH) (Ln = Y, Pr, Nd; hfacac = hexafluoroacetylacetonato; bdmap = 1,3-bis(dimethylamino)-2-propanolato; L = 2-methyl-2,4,6-tris(trifluoromethyl)-1,3-dioxane-4,6-diolato)
Suning Wang, Zhen Pang, Karen D. L. Smith, You-sheng Hua, Chris Deslippe, and Michael J. Wagner
pp 908 - 917; DOI:
10.1021/ic00108a023
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183W NMR Studies of Tungstate Complexes of Carbohydrates. 3. Species Formed with All-threo Alditols Acting as Tridentate, Tetradentate, or Pentadentate Ligands
Stella Chapelle, Jean-Paul Sauvage, P. Koell, and Jean-Francois Verchere
pp 918 - 923; DOI:
10.1021/ic00108a024
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First Characterization of the Influence of Paramagnetic Heteropoly Complexes of Tungsten on Relaxation Times of Water. Separation of Various Contributions to Relaxivities
Jennifer Gilbert, Darren Kassab, James H. Pawlow, Robert J. Fiel, Vishwas N. Joshi, and Mariusz Kozik
pp 924 - 927; DOI:
10.1021/ic00108a025
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Influence of the Anion on the Stability of Second-Sphere Coordination of Ferrioxamine B with Dicyclohexano-18-crown-6
Ines Batinic-Haberle and Alvin L. Crumbliss
pp 928 - 932; DOI:
10.1021/ic00108a026
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Kinetic Study of the Two-Electron Oxidation of Cobalt Tetraneopentoxyphthalocyanine by Thionyl Chloride
P. A. Bernstein and A. B. P. Lever
pp 933 - 937; DOI:
10.1021/ic00108a027
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Conformation of (S-Glutathionato)(2,2':6',2''-terpyridine)platinum(II) Ion, [Pt(trpy)GS]+, Determined from Cross-Relaxation Effects in Two-Dimensional 1H NMR Spectra. Importance of Ligand-Ligand Hydrophobic Interactions in Metal-Peptide Complexes
Nenad Juranic, Vladimir Likic, Nenad M. Kostic, and Slobodan Macura
pp 938 - 944; DOI:
10.1021/ic00108a028
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Theoretical Study of NCNCO and Its Isomers
Miklos Feher, Tibor Pasinszki, and Tamas Veszpremi
pp 945 - 951; DOI:
10.1021/ic00108a029
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Sterically Hindered [Tris(imidazolyl)phosphine]copper Complexes: Formation and Reactivity of a Peroxo-Dicopper(II) Adduct and Structure of a Dinuclear Carbonate-Bridged Complex
Thomas N. Sorrell, William E. Allen, and Peter S. White
pp 952 - 960; DOI:
10.1021/ic00108a030
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Theoretical ab Initio Study of Neutral and Charged B3Hn (n = 3-9) Species. Importance of Aromaticity in Determining the Structural Preferences
Anatoli A. Korkin, Paul v. R. Schleyer, and Michael L. McKee
pp 961 - 977; DOI:
10.1021/ic00108a031
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Hypervalence and the Octet Rule
Ronald J. Gillespie and Edward A. Robinson
pp 978 - 979; DOI:
10.1021/ic00108a032
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A Heterobimetallic .mu.-SO2 Complex
Aaron F. Bartlone, Michael J. Chetcuti, Ralph Navarro, and Maoyu Shang
pp 980 - 983; DOI:
10.1021/ic00108a033
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Synthesis and Crystal Structure of (2,7,12,17-Tetrapropylporphycenato)bis[tricarbonylrhenium(I)]
Chi-Ming Che, Zao-Ying Li, Chun-Xiao Guo, Kwok-Yin Wong, Shuenn-Shing Chern, and Shie-Ming Peng
pp 984 - 987; DOI:
10.1021/ic00108a034
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An Unsymmetrical Ligand Arrangement in the Complex Re2(.mu.-mp)4Cl2 (mp = Monoanion of 2-Mercaptopyridine)
Robert M. Tylicki, Wengan Wu, Phillip E. Fanwick, and Richard A. Walton
pp 988 - 991; DOI:
10.1021/ic00108a035
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Preparation and Characterization of cis-.LAMBDA.-[Ru(bpy)2(py)(O)]2+
Xiao Hua and A. Graham Lappin
pp 992 - 994; DOI:
10.1021/ic00108a036
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Metal Complexes in Inorganic Matrixes. 13. Nickel Complexes with Lysinate-Substituted Titanium Alkoxides as Ligands. X-ray Structure Analysis of [(EtO)3Ti(glycinate)]2
Ulrich Schubert, Stefan Tewinkel, and Frank Moeller
pp 995 - 997; DOI:
10.1021/ic00108a037
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Preparation and X-ray Crystal Structures of [(.eta.6-chrysene)(.eta.6-4-methylisopropylbenzene)ruthenium][BF4]2 and [(.eta.6-perylene)(.eta.6-4-methylisopropylbenzene)ruthenium][BF4]2
Leigh Christopher Porter, Jayapal Reddy Polam, and Swamy Bodige
pp 998 - 1001; DOI:
10.1021/ic00108a038
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Convenient Procedures for the Laboratory Preparation of Borazine
Thomas Wideman and Larry G. Sneddon
pp 1002 - 1003; DOI:
10.1021/ic00108a039
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Synthesis and X-ray Structure of the Unusual Cysteine-Complex OsH2{OC(=O)CH[NHC(=O)CH3]CH2S}(PiPr3)2
Reinaldo Atencio, Miguel A. Esteruelas, Fernando J. Lahoz, Luis A. Oro, and Natividad Ruiz
pp 1004 - 1006; DOI:
10.1021/ic00108a040
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Theoretical Study of the Structure of Borate Complex Ions
Richard Pizer, P. J. Ricatto, and Solomon Jacobson
pp 1007 - 1008; DOI:
10.1021/ic00108a041
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Issue 5


The First hypho-Borane Dianion, Undecahydropentaborate(2-), B5H112-
Robert W. McGaff and Donald F. Gaines
pp 1009 - 1010; DOI:
10.1021/ic00109a001
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Telluride Alkylation and Formation of Novel Metal Carbonyl Polytelluride Clusters in Superheated Alcohols. Isolation of the Complexes [M4(Te2)2(Te)2(TeMe)2(CO)8]2- (M = Fe, Ru)
Birinchi K. Das and Mercouri G. Kanatzidis
pp 1011 - 1012; DOI:
10.1021/ic00109a002
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Spectroelectrochemical Characterization of [Re2(.mu.-NCS)2(NCS)8]z-, (z = 1-4): Evidence for the Interconversion of an Edge-Shared Bioctahedral and a Direct Metal-Metal-Bonded Structure
Stephen P. Best, Robin J. H. Clark, and David G. Humphrey
pp 1013 - 1014; DOI:
10.1021/ic00109a003
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Carboxylation of Kinetically Inert Platinum(IV) Hydroxy Complexes. An Entr.acte.ee into Orally Active Platinum(IV) Antitumor Agents
Christen M. Ciandomenico, Michael J. Abrams, Barry A. Murrer, Jean F. Vollano, Melanie I. Rheinheimer, Sandra B. Wyer, Gerald E. Bossard, and John D. Higgins
pp 1015 - 1021; DOI:
10.1021/ic00109a004
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Dimerization of trans-[Pt(NH3)(1-MeC-N3)(H2O)2]2+ and Oxidation to a Diplatinum(III) Species in the Presence of Glycine. Relevance for Platinum Cytosine Blue
Thomas Wienkoetter, Michal Sabat, Gerd Fusch, and Bernhard Lippert
pp 1022 - 1029; DOI:
10.1021/ic00109a005
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Structure and Reactivity of Fe(II)-SAr Complexes: Relevance to the Active Site of Isopenicillin N Synthase
Yan Zang and Lawrence Que
pp 1030 - 1035; DOI:
10.1021/ic00109a006
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X-ray Absorption Pre-Edge Studies of High-spin Iron(II) Complexes
Clayton R. Randall, Lijin Shu, Yu-Min Chiou, Karl S. Hagen, Masami Ito, Nobumasa Kitajima, Rene J. Lachicotte, Yan Zang, and Lawrence Que
pp 1036 - 1039; DOI:
10.1021/ic00109a007
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Exchange Coupling Approach to the Radical Disposition of an Intermediate in Escherichia coli Ribonucleotide Reductase
Natarajan Ravi and Emile L. Bominaar
pp 1040 - 1043; DOI:
10.1021/ic00109a008
PDF
Synthesis and Characterization of High-Spin Iron(III) 2-Hydroxy-5,10,15,20-tetraphenylporphyrin. The Unprecedented Example of the Cyclic Iron Porphyrin Trimer
Jacek Wojaczynski and Lechoslaw Latos-Grazynski
pp 1044 - 1053; DOI:
10.1021/ic00109a009
PDF
Synthesis and Characterization of Gallium(III) 2-Hydroxy-5,10,15,20-tetraphenylporphyrin. A Novel Example of a Cyclic Gallium(III) Porphyrin Trimer
Jacek Wojaczynski and Lechoslaw Latos-Grazynski
pp 1054 - 1062; DOI:
10.1021/ic00109a010
PDF
A Simple Method for Preparing Magnesium Porphyrins
Jonathan S. Lindsey and Jeffrey N. Woodford
pp 1063 - 1069; DOI:
10.1021/ic00109a011
PDF
Supramolecular Assembly of Porphyrins and Monoclonal Antibodies
A. Harada, K. Shiotsuki, H. Fukushima, H. Yamaguchi, and M. Kamachi
pp 1070 - 1076; DOI:
10.1021/ic00109a012
PDF
Synthesis and Characterization of Oxotechnetium(V) Complexes with Aza-Substituted 2,6-Dimethyl-4-azaheptane-2,6-dithiol Ligands and Benzyl Mercaptan as Coligand
D. M. Spyriounis, M. Pelecanou, C. I. Stassinopoulou, C. P. Raptopoulou, A. Terzis, and E. Chiotellis
pp 1077 - 1082; DOI:
10.1021/ic00109a013
PDF
Dynamics of the Coordination Equilibria in Solutions Containing Copper(II), Copper(I), and 2,9-Dimethyl-1,10-phenanthroline and Their Effect on the Reduction of O2 by Cu(I)
Yabin Lei and Fred C. Anson
pp 1083 - 1089; DOI:
10.1021/ic00109a014
PDF
Synthesis and Electrochemistry of Mo[BH(Me2pz)3](NO)[S(CH2)2CONH(CH2)2S] as a Probe of the Effects of N-H.cntdot..cntdot..cntdot.S Hydrogen Bonding on Redox Potentials
Jiong Huang, Robert L. Ostrander, Arnold L. Rheingold, and Marc Anton Walters
pp 1090 - 1093; DOI:
10.1021/ic00109a015
PDF
Factors Affecting Chelation of Carboxylates to cis-Diaqua Co(III) Complexes: Implications on the Reactivity of the Metal Complexes for Hydrolyzing Esters, Amides, Nitriles, and Phosphates
James A. Connolly, Jung-Hee Kim, Mariusz Banaszczyk, Marc Drouin, and Jik Chin
pp 1094 - 1099; DOI:
10.1021/ic00109a016
PDF
Synthesis and Characterization of Water-Soluble [Pd(triphosphine)(CH3CN)](BF4)2 Complexes for CO2 Reduction
Andrew M. Herring, Bryan D. Steffey, Alex Miedaner, Sheryl A. Wander, and Daniel L. DuBois
pp 1100 - 1109; DOI:
10.1021/ic00109a017
PDF
Synthesis and Structure of Novel Group IV Tridentate Alkoxide Complexes and Ceramic Thin Films Derived Therefrom. X-ray Structures of (H3CC(CH2-.mu.3-O)(CH2-.mu.-O)2)2Ti4(OCH(CH3)2)10, (H3CCH2C(CH2-.mu.3-O)(CH2-.mu.-O)2)2Ti4(OCH(CH3)2)10, and (H3CC(CH2-.mu.-O)3)2Zr4(.mu.-OCH(CH3)2)2(OCH(CH3)2)8
Timothy J. Boyle, Robert W. Schwartz, Robert J. Doedens, and Joseph W. Ziller
pp 1110 - 1120; DOI:
10.1021/ic00109a018
PDF
Synthesis, Characterization, and Photobehavior of .DELTA.- and .LAMBDA.-fac-Tris((S)-tryptophanato)chromium(III)
Noel A. P. Kane-Maguire, T. W. Hanks, Dennis G. Jurs, Ronald M. Tollison, Ann L. Heatherington, Laurel M. Ritzenthaler, Luanne M. McNulty, and Hugh M. Wilson
pp 1121 - 1124; DOI:
10.1021/ic00109a019
PDF
Effects of Ligand Substituents (F for H; OR for R) on Mesogenic Properties of M(Salen) Derivatives (M = Cu, Ni, VO). New Fluoro-Substituted Complexes and Crystal Structure of the Mesogen Ni(5-hexylSalen)
Antony B. Blake, John R. Chipperfield, Wasif Hussain, Reinhard Paschke, and Ekkehard Sinn
pp 1125 - 1129; DOI:
10.1021/ic00109a020
PDF
Mechanistic and Stereochemical Investigation of Imino Ethers Formed by Alcoholysis of Coordinated Nitriles: X-ray Crystal Structures of cis- and trans-Bis(1-imino-1-methoxyethane)dichloroplatinum(II)
Renzo Cini, Paola A. Caputo, Francesco P. Intini, and Giovanni Natile
pp 1130 - 1137; DOI:
10.1021/ic00109a021
PDF
Reactions of Cp*3Co3(.mu.3-H)(.mu.2-H)3 with Carbon Dioxide, Carbon Disulfide, and Phenyl Isocyanate
Charles P. Casey, Ross A. Widenhoefer, and Randy K. Hayashi
pp 1138 - 1144; DOI:
10.1021/ic00109a022
PDF
Synthesis, Characterization, and Coordination Chemistry of a Novel Edge-Shared M2L9 Species, Mo2(.mu.-S)(.mu.-Cl)Cl3(PMe3)4
Keith A. Hall and James M. Mayer
pp 1145 - 1158; DOI:
10.1021/ic00109a023
PDF
Electronic Structure, Chemical Bonding, and Jahn-Teller Distortions in CdPS3
Vladlen Zhukov, Florent Boucher, Pere Alemany, Michel Evain, and Santiago Alvarez
pp 1159 - 1163; DOI:
10.1021/ic00109a024
PDF
Nature of the Carbonyl Semibridge Bond in Coordinatively Unsaturated Metal Carbonyl Compounds. Solvated and Semibridged Forms in Photolysis of MM'(CO)10 (M, M' = Mn, Re) in 3-Methylpentane
Theodore L. Brown and Shulin Zhang
pp 1164 - 1171; DOI:
10.1021/ic00109a025
PDF
Valence Tautomerism for Quinone Complexes of Manganese: Members of the MnIV(N-N)(Cat)2-MnIII(N-N)(SQ)(Cat)-MnII(N-N)(SQ)2 Series
Attia S. Attia and Cortlandt G. Pierpont
pp 1172 - 1179; DOI:
10.1021/ic00109a026
PDF
S,S'-Diorgano Derivatives of the 1,5-Ph4P2N4S2 Ring: Lithium Halide Adducts, Conformational Isomerism, and N-Methylation
Tristram Chivers, Xiaoliang Gao, Robert W. Hilts, Masood Parvez, and Rainer Vollmerhaus
pp 1180 - 1186; DOI:
10.1021/ic00109a027
PDF
Enhanced Cross Polarization in Magic Angle Spinning NMR of Metal Complexes
May Han, Olve B. Peersen, James W. Bryson, Thomas V. O'Halloran, and Steven O. Smith
pp 1187 - 1192; DOI:
10.1021/ic00109a028
PDF
Effect of High External Pressures on the Infrared and Micro-Raman Spectra of Crystalline, Octahedral Mixed Carbonyl-tert-Butyl Isocyanide Complexes of Chromium(0)
Hongqi Li and Ian S. Butler
pp 1193 - 1197; DOI:
10.1021/ic00109a029
PDF
Influence of Bridging Ligand Unsaturation on Excited State Behavior in Mono- and Bimetallic Ruthenium(II) Diimine Complexes
Aaron I. Baba, Harry E. Ensley, and Russell H. Schmehl
pp 1198 - 1207; DOI:
10.1021/ic00109a030
PDF
A Theoretical Study of Rectangular Tetrasulfur in a Gas Phase and in the Tetranuclear [{Rh2(.eta.5-C5Me5)2(.mu.-CH2)2}2(.mu.-S4)]2+ Complex
Alexander M. Mebel, Keiji Morokuma, and Kiyoshi Isobe
pp 1208 - 1211; DOI:
10.1021/ic00109a031
PDF
A Theoretical Investigation of the Structure and Electronic Spectra of Porphyrin Homolog Macrocycles. Hexaazacyclophane and its Nickel and Copper Complexes
Guillermina L. Estiu, Alicia H. Jubert, Jose Molina, Juan Costamagna, Juan Canales, and Juan Vargas
pp 1212 - 1220; DOI:
10.1021/ic00109a032
PDF
In Vacuo and In Crystal Molecular-Mechanical Modeling of Copper(II) Complexes with Amino Acids
Jasmina Sabolovic and Kjeld Rasmussen
pp 1221 - 1232; DOI:
10.1021/ic00109a033
PDF
Oxovanadium Pyrazole Complexes: Synthesis and Structure
Madan Mohan, Marcus R. Bond, Tom Otieno, and Carl J. Carrano
pp 1233 - 1242; DOI:
10.1021/ic00109a034
PDF
Structural Preferences of Bicyclic Pentaoxyphosphoranes with Eight-Membered Rings
T. K. Prakasha, A. Chandrasekaran, Roberta O. Day, and Robert R. Holmes
pp 1243 - 1247; DOI:
10.1021/ic00109a035
PDF
Rare Earth Metal Boron Carbide MBC Compounds Containing Monodimensional Branched Zigzag Chains of non-metal Atoms: Theoretical Aspects
Fabrice Wiitkar, Samia Kahlal, Jean-Francois Halet, Jean-Yves Saillard, Josef Bauer, and Peter Rogl
pp 1248 - 1256; DOI:
10.1021/ic00109a036
PDF
Synthesis in Molten Alkali Metal Polyselenophosphate Fluxes: A New Family of Transition Metal Selenophosphate Compounds, A2MP2Se6 (A = K, Rb, Cs; M = Mn, Fe) and A2M'2P2Se6 (A = K, Cs; M' = Cu, Ag)
Timothy J. McCarthy and Mercouri G. Kanatzidis
pp 1257 - 1267; DOI:
10.1021/ic00109a037
PDF
Crystal Structure and Conformational Studies of the Ferric Hexadentate N,N,N-Tris[2-(3-hydroxy-2-oxo-1,2-dihydropyridin-1-yl)acetamido]ethylamine Complex (FeCP130) as a Specific Iron(III) Chelator
Gaoyi Xiao, Dick van der Helm, Robert C. Hider, and Paul S. Dobbin
pp 1268 - 1270; DOI:
10.1021/ic00109a038
PDF
Predicted Structures of Precursors B4N6H8, B4N8H8, and B4N8H6 and the B24N36 Analog of C60
Richard D. Bardo, Clyde T. Stanton, and Walter H. Jones
pp 1271 - 1272; DOI:
10.1021/ic00109a039
PDF
Transition Metal Chemistry of Main Group Hydrazides. Part 11. Synthesis and Coordination Chemistry of Novel Tetraphosphino Phosphorinanes. X-ray Crystal Structure of [{W(CO)4}2{.mu.-[PhPN(Me)N(P(OCH2CF3)2)]2}]
V. Sreenivasa Reddy, Kattesh V. Katti, and Charles L. Barnes
pp 1273 - 1277; DOI:
10.1021/ic00109a040
PDF
X-ray structure determination and magnetic behavior of the new uniform S = 1 chain [{Ni(Me2[14]-1,3-dieneN4)(.mu.-N3)}n](ClO4)n. Magneto-structural correlations
Ramon Vicente, Albert Escuer, Joan Ribas, M. Salah El Fallah, Xavier Solans, and Merce Font-Bardia
pp 1278 - 1281; DOI:
10.1021/ic00109a041
PDF
Long-Range Electron Transfer Quenching and Recombination in a Rhenium-Pyridiniumylacrylamide Complex
Nestor E. Katz, Sandra L. Mecklenburg, and Thomas J. Meyer
pp 1282 - 1284; DOI:
10.1021/ic00109a042
PDF
Structures of M(allyl)4 (M = Mo, W, Zr)
Clark Landis, Thomas Cleveland, and Charles P. Casey
pp 1285 - 1287; DOI:
10.1021/ic00109a043
PDF
Synthesis and Molecular Structure of a Nickel(II) Complex Containing a Pyrazolone-Derived Phosphine Ligand: [Ni(.eta.5-C5Ph5){Ph2PC:C(O)N(Ph)N:C(Me)}]
Dominique Matt, Michael Huhn, Michel Bonnet, Igor Tkatchenko, Ulli Englert, and Wolfgang Klaeui
pp 1288 - 1291; DOI:
10.1021/ic00109a044
PDF
Conformational Flexibility of Metalloporphyrin Skeletons As Studied by Racemization Profiles of Chiral meso-Substituted Metalloporphyrins with Molecular Asymmetry
Katsuaki Konishi, Yoshiki Mori, Takuzo Aida, and Shohei Inoue
pp 1292 - 1294; DOI:
10.1021/ic00109a045
PDF
Reduction of Dinitrogen to Ammonia and Hydrazine in Iron(0) and Molybdenum(0) Complexes Containing the N(CH2CH2PPh2)3 Ligand. Crystal Structures of [FeH(L)(N(CH2CH2PPh2)3)][BPh4] (L = N2, CO)
T. Adrian George, David J. Rose, Yuanda Chang, Qin Chen, and Jon Zubieta
pp 1295 - 1298; DOI:
10.1021/ic00109a046
PDF

Issue 6


Reactions of the Ion Pair [Os(NH3)6]3+.cntdot.[Fe(CN)6]3-
Vassiliki G. Poulopoulou and Henry Taube
pp 1299 - 1301; DOI:
10.1021/ic00110a001
PDF
Spectroscopic Studies on the Average-Valence Copper Site Cu23+
J. A. Farrar, V. McKee, A. H. R Al-Obaidi, J. J. McGarvey, J. Nelson, and A. J. Thomson
pp 1302 - 1303; DOI:
10.1021/ic00110a002
PDF
A Unique Three-Step Cyclic Reaction Sequence of Heterotrimetallic Sulfide Clusters. Structures and Properties of [{Cp*RhP(OEt)3(.mu.-WS4)(CuCl)Cu}2(.mu.-Cl)2] (Cp* = .eta.5-C5Me5) with a Branched Structure and [{Cp*RhP(OEt)3(.mu.-WOS3)(CuCl)Cu}2(.mu.-Cl)2] with a Linked Incomplete Cubane-Type Structure
Seiji Ogo, Takayoshi Suzuki, and Kiyoshi Isobe
pp 1304 - 1305; DOI:
10.1021/ic00110a003
PDF
Phospholylsamarium(III) Complexes
Hans-Juergen Gosink, Francois Nief, Louis Ricard, and Francois Mathey
pp 1306 - 1307; DOI:
10.1021/ic00110a004
PDF
The New Orthosilicate Li4SrCa(SiO4)2: Structure and Eu2+ Luminescence
Annapoorna Akella and Douglas A. Keszler
pp 1308 - 1310; DOI:
10.1021/ic00110a005
PDF
Electrocatalytic Reduction of Dioxygen to Water by Iridium Porphyrins Adsorbed on Edge Plane Graphite Electrodes
James P. Collman, Leng Leng Chng, and David A. Tyvoll
pp 1311 - 1324; DOI:
10.1021/ic00110a006
PDF
Gaseous Fluorodiazonium Ions. Experimental and Theoretical Study on Formation and Structure of FN2+
Fulvio Cacace, Felice Grandinetti, and Federico Pepi
pp 1325 - 1332; DOI:
10.1021/ic00110a007
PDF
Solution Conformations of Dodecasubstituted Cobalt(II) Porphyrins
Craig J. Medforth, J. David Hobbs, Marisol R. Rodriguez, Raymond J. Abraham, Kevin M. Smith, and John A. Shelnutt
pp 1333 - 1341; DOI:
10.1021/ic00110a008
PDF
Ligand Stereochemistry of Metal Carbonyl Clusters: Steric vs Electronic Effects
Angelo Sironi
pp 1342 - 1349; DOI:
10.1021/ic00110a009
PDF
Effect of Conjugation on the Oscillator Strength of the Ruthenium(III)-Cyanamide Chromophore
Christopher E. B. Evans, Dean Ducharme, Mark L. Naklicki, and Robert J. Crutchley
pp 1350 - 1354; DOI:
10.1021/ic00110a010
PDF
Iminosemiquinone Complexes of Copper, Structural, Magnetic, and Electrochemical Characterization of Complexes of the Phenoxazinolate Semiquinone Radical
Gabor Speier, Anne M. Whalen, Jozsef Csihony, and Cortlandt G. Pierpont
pp 1355 - 1360; DOI:
10.1021/ic00110a011
PDF
Chemistry of [Ru(1,3-diaryltriazenide)2(PPh3)2]z (z = 0, +). A Hindered RuII,IIIN2P2 Family with Valence-Independent Geometry
Mahua Menon, Amitava Pramanik, Surajit Chattopadhyay, Nilkamal Bag, and Animesh Chakravorty
pp 1361 - 1367; DOI:
10.1021/ic00110a012
PDF
Electron Transfer from Rieke Cadmium Yielding Cd2+ Coordinated and Ion Associated Anion Radical Systems
Cheryl D. Stevenson, Richard C. Reiter, Richard D. Burton, and Troy D. Halvorsen
pp 1368 - 1372; DOI:
10.1021/ic00110a013
PDF
Magnetic Properties of the Iron Arsenate Phase Fe2As4O12. Short-Range versus Long-Range Order
A. M. Nakua and J. E. Greedan
pp 1373 - 1376; DOI:
10.1021/ic00110a014
PDF
BN Alternants: Boron Nitride Cages and Polymers
H.Y. Zhu, D. J. Klein, W. A. Seitz, and N. H. March
pp 1377 - 1383; DOI:
10.1021/ic00110a015
PDF
Effect of Polyether Ligands on Stabilities and Mass Transport Properties of a Series of Gadolinium(III) .beta.-Diketonate Complexes
Ian Baxter, Simon R. Drake, Michael B. Hursthouse, K. M. Abdul Malik, John McAleese, David J. Otway, and John C. Plakatouras
pp 1384 - 1394; DOI:
10.1021/ic00110a016
PDF
Chemistry of Iron Oxophlorins. 3. Reversible, One-Electron Oxidation of the Iron(III) Octaethyloxophlorin Dimer
Alan L. Balch, Lechoslaw Latos-Grazynski, and Tamara N. St. Claire
pp 1395 - 1401; DOI:
10.1021/ic00110a017
PDF
Catecholate Complexes of Silicon: Synthesis and Molecular and Crystal Structures of [Si(cat)2].cntdot.2THF and Li2[Si(cat)3].cntdot.3.5dme (cat = Catecholate Dianion)
F. Ekkehardt Hahn, Michael Keck, and Kenneth N. Raymond
pp 1402 - 1407; DOI:
10.1021/ic00110a018
PDF
Amide Functional Group Contribution to the Stability of Gadolinium(III) Complexes: DTPA Derivatives
Christine Paul-Roth and Kenneth N. Raymond
pp 1408 - 1412; DOI:
10.1021/ic00110a019
PDF
Polyoxoanion-Supported Catalyst Precursors. Synthesis and Characterization of the Iridium(I) and Rhodium(I) Precatalysts [(n-C4H9)4N]5Na3[(1,5-COD)M.cntdot.P2W15Nb3O62] (M = Ir, Rh)
Matthias Pohl, David K. Lyon, Noritaka Mizuno, Kenji Nomiya, and Richard G. Finke
pp 1413 - 1429; DOI:
10.1021/ic00110a020
PDF
Synthesis, X-ray Crystal Structures, and NMR Spectroscopy of [PPh4]2[M(Te4)2], M = Hg, Cd, Zn
John C. Bollinger, Lisa C. Roof, Donna M. Smith, Jonathan M. McConnachie, and James A. Ibers
pp 1430 - 1434; DOI:
10.1021/ic00110a021
PDF
Analysis of Multiply Charged Oxo-Bridged Complexes by Electrospray Ionization Mass Spectrometry
Ulla N. Andersen, Christine J. McKenzie, and Gustav Bojesen
pp 1435 - 1439; DOI:
10.1021/ic00110a022
PDF
Reactions at a Dimolybdenum(V) Sulfur Bridge: Metallothionitrites and the NO2-, NO, NO+ Connection
Elaine K. Haub, Ana C. Lizano, and Mark E. Noble
pp 1440 - 1444; DOI:
10.1021/ic00110a023
PDF
XAS Investigations on the Iron-Zinc Center of Purple Acid Phosphatase from Red Kidney Beans
S. Priggemeyer, P. Eggers-Borkenstein, F. Ahlers, B. Krebs, G. Henkel, M. Koerner, H. Witzel, H.-F. Nolting, and C. Hermes
pp 1445 - 1454; DOI:
10.1021/ic00110a024
PDF
A Molecular Cavity for Tetrahedral and Y-Shaped Anions. Synthetic and Structural Studies of Macrocyclic Dicopper(I) and Disilver(I) Compounds of 1,6-Bis(diphenylphosphino)hexane
Susumu Kitagawa, Mitsuru Kondo, Satoshi Kawata, Shigetoshi Wada, Masahiko Maekawa, and Megumu Munakata
pp 1455 - 1465; DOI:
10.1021/ic00110a025
PDF
Primary Vinyl- and Alkynylstibines: Preparation and Characterization
S. Legoupy, L. Lassalle, J.-C. Guillemin, V. Metail, A. Senio, and G. Pfister-Guillouzo
pp 1466 - 1471; DOI:
10.1021/ic00110a026
PDF
Synthesis, Characterization, and Electrochemistry of Heteroleptic Double-Decker Complexes of the Type Phthalocyaninato-Porphyrinato-Zirconium(IV) or -Hafnium(IV)
Roger Guilard, Jean-Michel Barbe, Amina Ibnlfassi, Abdallah Zrineh, Victor A. Adamian, and Karl M. Kadish
pp 1472 - 1481; DOI:
10.1021/ic00110a027
PDF
Strong antiferromagnetic coupling in cis-.mu.-1,3-azide-bridged copper(II) dimers: trigonal-bipyramidal vs. quadratic planar coordination with a nearly identical binucleating ligand System
Felix Tuczek and Wolfgang Bensch
pp 1482 - 1486; DOI:
10.1021/ic00110a028
PDF
Moessbauer and EPR Studies of the Binuclear and Trinuclear Antiferromagnetically Coupled Iron(III)-Binding Sites in Ferreascidin
Steven W. Taylor, John D. Cashion, L. Joan Brown, Clifford J. Hawkins, and Graeme R. Hanson
pp 1487 - 1494; DOI:
10.1021/ic00110a029
PDF
Synthesis of a New Layered Sodium Copper(II) Pyrophosphate, Na2CuP2O7, via an Eutectic Halide Flux
Kristen M. S. Etheredge and Shiou-Jyh Hwu
pp 1495 - 1499; DOI:
10.1021/ic00110a030
PDF
Calculation of the Vibronic Intensities in the Emission Spectra of Manganese(V) in Oxide Lattices
David Wexler and Jeffrey I. Zink
pp 1500 - 1506; DOI:
10.1021/ic00110a031
PDF
Rational Design of a Light-Driven Molecular Switch Incorporating an Alizarin-Ru(bpy)2 Fragment
Antonietta DelMedico, Scott S. Fielder, A. B. P. Lever, and William J. Pietro
pp 1507 - 1513; DOI:
10.1021/ic00110a032
PDF
Synthesis of Pyrroloquinolinequinone Analogs. Molecular Structure and Moessbauer and Magnetic Properties of Their Iron Complexes
L. Tommasi, L. Shechter-Barloy, D. Varech, J.-P. Battioni, B. Donnadieu, M. Verelst, A. Bousseksou, D. Mansuy, and J.-P. Tuchagues
pp 1514 - 1523; DOI:
10.1021/ic00110a033
PDF
Convenient Synthesis of Water Soluble, Isomerically Pure Ruthenium Phthalocyanine Complexes
Gerald E. Bossard, Michael J. Abrams, Marilyn C. Darkes, Jean F. Vollano, and Robert C. Brooks
pp 1524 - 1527; DOI:
10.1021/ic00110a034
PDF
Studies on the Iron(II) meso-Oxyporphyrin .pi.-Neutral Radical as a Reaction Intermediate in Heme Catabolism
Isao Morishima, Hiroshi Fujii, Yoshitsugu Shiro, and Seiyo Sano
pp 1528 - 1535; DOI:
10.1021/ic00110a035
PDF
Specific Cation Catalysis in the Thiocyanate Photoanation of Acidopentacyanocobaltate(III) Complexes
A. D. Kirk and Diane M. Kneeland
pp 1536 - 1541; DOI:
10.1021/ic00110a036
PDF
Synthesis and Structure of Carbonyl-Metalated Organobismuth Complexes
Robert E. Bachman and Kenton H. Whitmire
pp 1542 - 1551; DOI:
10.1021/ic00110a037
PDF
Electrochemistry and Infrared Spectroelectrochemistry of the Substituted Phosphine Complexes, XTa(CO)4(dppe) (X = I, Br) and XM(CO)2(dppe)2 (X = H, I, Br ,Cl; M = Nb, Ta)
Christine A. Blaine, John E. Ellis, and Kent R. Mann
pp 1552 - 1561; DOI:
10.1021/ic00110a038
PDF
Synthesis and Characterization of Cyclopentadienyl and Pentamethylcyclopentadienyl Ruthenium Complexes of Oligothiophenes
David D. Graf, Nancy C. Day, and Kent R. Mann
pp 1562 - 1575; DOI:
10.1021/ic00110a039
PDF
Molybdenum(IV) Azamolybdatranes ClMo(R3SiNCH2CH2)3N from an Unexpected Reaction
Zhibang Duan and John G. Verkade
pp 1576 - 1578; DOI:
10.1021/ic00110a040
PDF
Nitrilotripropionic Acid (NTP) and Other Polyamino Carboxylic Acids as Sequestering Agents for Beryllium(II). X-ray Crystal Structure of Sodium (nitrilotripropionato)beryllate(II) Trihydrate, Na[Be(NTP)].cntdot.3H2O
Erasmo Chinea, Sixto Dominguez, Alfredo Mederos, Felipe Brito, Juan Manuel Arrieta, Agustin Sanchez, and Gabriel Germain
pp 1579 - 1587; DOI:
10.1021/ic00110a041
PDF
X-ray Structure of fac-IMn(CO)3(bpy) and Electronic Structures and Transitions of the Complexes fac-XMn(CO)3(bpy) (X = Cl, I) and mer-ClMn(CO)3(bpy)
G. J. Stor, D. J. Stufkens, P. Vernooijs, E. J. Baerends, J. Fraanje, and K. Goubitz
pp 1588 - 1594; DOI:
10.1021/ic00110a042
PDF
Multinuclear NMR Study of Dipotassium Tetracyanometalates of the Group 12 Metals in the Solid State
Gang Wu, Scott Kroeker, and Roderick E. Wasylishen
pp 1595 - 1598; DOI:
10.1021/ic00110a043
PDF
Effects of Imidazoles and pH on the Peroxidase Activity of the Hemin-Hydrogen Peroxide System
Tadayuki Uno, Akiko Takeda, and Saburo Shimabayashi
pp 1599 - 1607; DOI:
10.1021/ic00110a044
PDF
Combination of Metal-Metal Bonding and Antiferromagnetic Exchange Interaction in the d2-d2 Complex [V2O(SPh)4(Me2-bpy)2].cntdot.THF (Me2-bpy = 4,4'-Dimethylbipyridine)
Norman S. Dean, Stuart L. Bartley, William E. Streib, Emil B. Lobkovsky, and George Christou
pp 1608 - 1616; DOI:
10.1021/ic00110a045
PDF
A XANES and EXAFS Investigation of the Speciation of Selenite following Bacterial Metabolization
B. B. Buchanan, J. J. Bucher, D. E. Carlson, N. M. Edelstein, E. A. Hudson, N. Kaltsoyannis, T. Leighton, W. Lukens, H. Nitsche, and et al.
pp 1617 - 1619; DOI:
10.1021/ic00110a046
PDF
Cationic Trinuclear 48-Electron Ruthenium Carbonyl Cluster Complexes Containing No Hydride Ligands
Javier A. Cabeza, Ignacio del Rio, Angela Llamazares, Victor Riera, Santiago Garcia-Granda, and Juan F. Van der Maelen
pp 1620 - 1623; DOI:
10.1021/ic00110a047
PDF
Crystal Structure of a Bis(amido)bis(thiolato)oxorhenium(V) Complex That Forms a Methanol-Solvated Salt with Calcium Extracted from Silica Gel
Dae Yoon Chi, Scott R. Wilson, and John A. Katzenellenbogen
pp 1624 - 1625; DOI:
10.1021/ic00110a048
PDF
Synthesis, Spectroscopic, and Structural Studies of Diarsine Complexes of Nickel(III) Iodide
William Levason and Stephen R. Preece
pp 1626 - 1628; DOI:
10.1021/ic00110a049
PDF

Issue 7


Luminescent Labels for Purine Nucleobases: Electronic Properties of Guanine Bound to Rhenium(I)
Tracy A. Oriskovich, P. S. White, and H. Holden Thorp
pp 1629 - 1631; DOI:
10.1021/ic00111a001
PDF
Mixed Valence, Tricopper(I,II,I) Complexes with Thiolate Bridges. Progress toward Synthetic Models of the Putative {Cu2}3+ Sites in Nitrous Oxide Reductase and Cytochrome c Oxidase
Robert P. Houser and William B. Tolman
pp 1632 - 1633; DOI:
10.1021/ic00111a002
PDF
Efficient and Convenient Method for Axial Nucleotide Removal from Vitamin B12 and Its Derivatives
Xiang Zou, Daniel R. Evans, and Kenneth L. Brown
pp 1634 - 1635; DOI:
10.1021/ic00111a003
PDF
Regiospecific and Nonlinear Substituent Effects on the Electronic and Fluorescence Spectra of Phthalocyanines
Nagao Kobayashi, Natsuko Sasaki, Yasuhiro Higashi, and Tetsuo Osa
pp 1636 - 1637; DOI:
10.1021/ic00111a004
PDF
Isolation of the "Open Form" of Cyclenphosphorane by Deprotonation and Reaction with Electrophilic Reagents
Dilip V. Khasnis, Harold S. Isom, Su Shang, Michael Lattman, Marilyn M. Olmstead, and Philip P. Power
pp 1638 - 1641; DOI:
10.1021/ic00111a005
PDF
Extreme Pressure-Induced Shifts of Emission Energies in M[Au(CN)2] and M2[Pt(CN)4].cntdot.nH2O. Compounds with Low-Dimensional and Metal-Metal Interactions
Hartmut Yersin and Ulrich Riedl
pp 1642 - 1645; DOI:
10.1021/ic00111a006
PDF
Zirconium Bromide Cluster Chemistry. A New Tunnel Structure in A5Zr6Br15Be (A = Rb, Cs)
Ru-Yi Qi and John D. Corbett
pp 1646 - 1651; DOI:
10.1021/ic00111a007
PDF
Cs3Zr7Cl20Mn: A Zirconium Cluster Network Compound with Isolated ZrCl5- Units in a Stuffed Perovskite Structure
Jie Zhang and John D. Corbett
pp 1652 - 1656; DOI:
10.1021/ic00111a008
PDF
Cs3Zr6Br15Z (Z = C, B): A Stuffed Rhombohedral Perovskite Structure of Linked Clusters
Ru-Yi Qi and John D. Corbett
pp 1657 - 1662; DOI:
10.1021/ic00111a009
PDF
Electron Spin Echo Envelope Modulation (ESEEM) Spectroscopy of Cobalt(II) Bis(dimethylglyoximes): Equatorial Co-N Coupling Parameters
Michael D. Wirt, Christopher J. Bender, and Jack Peisach
pp 1663 - 1667; DOI:
10.1021/ic00111a010
PDF
Siloxane and Organosilicon Dimers, Monomers, and Polymers with Amide-Linked Ferrocenyl Moieties. Synthesis, Characterization, and Redox Properties
Carmen M. Casado, Moises Moran, Jose Losada, and Isabel Cuadrado
pp 1668 - 1680; DOI:
10.1021/ic00111a011
PDF
Group 4 Metal Complexes of the Tetradentate (.eta.4-N,N',S,S')Ph4P2N4S22- and Ph4P2N4S2R- Anions. X-ray Structures of {Cp*HfCl2[Ph4P2N3(NH)S2]}2, Cp*ZrCl2[Ph4P2N4S(SMe)], and [Me3PNPPh2NSMeNPPh2NH2]Cl
Tristram Chivers, Xiaoliang Gao, and Masood Parvez
pp 1681 - 1687; DOI:
10.1021/ic00111a012
PDF
Synthesis and Structure of Oxo(2-(1'-methyl-1'-mercaptoethyl)-3-(5''-methyl-5''-mercapto- 3''-(dehydroaza)hexyl)thiazolidinato-N3,N3'',S1',S5'')technetium(V) , TcO(C12H23N2S3): Unusual Formation of a Thiazolidine Ring
Hosen Alarabi, Russell A. Bell, Romolo Faggiani, Helen E. Howard-Lock, Colin J. L. Lock, and Alfred V. Kramer
pp 1688 - 1694; DOI:
10.1021/ic00111a013
PDF
Synthesis of Thorium Amide Complexes via Halide Metathesis and Transamination Procedures: X-ray Structure of Th[N(SiMe3)2]2(NMePh)2
David M. Barnhart, David L. Clark, Steven K. Grumbine, and John G. Watkin
pp 1695 - 1699; DOI:
10.1021/ic00111a014
PDF
CsTi2As3O12: A Cesium Titanium(IV) Arsenate with an Open Framework Structure
Kwang-Hwa Lii
pp 1700 - 1704; DOI:
10.1021/ic00111a015
PDF
Electrochemical Oxidation and Reduction of Cationic Carbonyl Hydride Complexes of Group VI Transition Metals
Frank Marken, Alan M. Bond, and Ray Colton
pp 1705 - 1710; DOI:
10.1021/ic00111a016
PDF
Electrochemistry of Chromium(II) Hexacyanochromate(III) and Electrochemically Induced Isomerization of Solid Iron(II) Hexacyanochromate(III) Mechanically Immobilized on the Surface of a Graphite Electrode
Ales Dostal, Uwe Schroeder, and Fritz Scholz
pp 1711 - 1717; DOI:
10.1021/ic00111a017
PDF
Pyridazine Complexes of Copper(II) Nitrate: Synthesis and Structural and Magnetic Studies
Tom Otieno, Steven J. Rettig, Robert C. Thompson, and James Trotter
pp 1718 - 1725; DOI:
10.1021/ic00111a018
PDF
Cathodic Cleavage of C-S and C-P in Carboranyl Derivatives
Francesc Teixidor, Josefina Pedrajas, and Clara Vinas
pp 1726 - 1729; DOI:
10.1021/ic00111a019
PDF
Autoxidation of Uranium(V). Catalysis and Inhibition by Copper Ions
Andreja Bakac and James H. Espenson
pp 1730 - 1735; DOI:
10.1021/ic00111a020
PDF
NMR and ENDOR Conformational Studies of the Vanadyl Guanosine 5'-Monophosphate Complex in Hydrogen-Bonded Quartet Assemblies
Fa Shun Jiang and Marvin W. Makinen
pp 1736 - 1744; DOI:
10.1021/ic00111a021
PDF
Mono- and Polynuclear Guanine Complexes of Platinum(II). Syntheses and Crystal and Molecular Structures of Bis(9-methylguanine-N(7))bis(trimethylphosphine)platinum(II) Dinitrate and cyclo-Hexakis(9-methylguanine(-H)-N(1),N(7))hexakis(cis-bis(trimethylphosphine)platinum(II)) Hexanitrate
Bruno Longato, Giuliano Bandoli, Guendalina Trovo, Elena Marasciulo, and Giancarlo Valle
pp 1745 - 1750; DOI:
10.1021/ic00111a022
PDF
Electronic Structures of Halogenated Ruthenium Porphyrins. Crystal Structure of RuTFPPCl8(CO)H2O (TFPPCl8 = Octa-.beta.-chlorotetrakis(pentafluorophenyl)porphyrin)
Eva R. Birnbaum, William P. Schaefer, Jay A. Labinger, John E. Bercaw, and Harry B. Gray
pp 1751 - 1755; DOI:
10.1021/ic00111a023
PDF
Lanthanide(III)-Catalyzed Synthesis of 2-(Carboxymethyl)-2,4-(R),5-(R)-tricarboxy- 1,3-dioxolane and Its Coordination to Lanthanide(III) and Calcium(II)
Jurriaan Huskens, Joop A. Peters, Herman Van Bekkum, and Gregory R. Choppin
pp 1756 - 1763; DOI:
10.1021/ic00111a024
PDF
Synthesis, Characterization and Crystal Structures of Technetium(V)-Oxo Complexes Useful in Nuclear Medicine. 1. Complexes of Mercaptoacetylglycylglycylglycine (MAG3) and Its Methyl Ester Derivative (MAG3OMe)
Glenn Grummon, Raghavan Rajagopalan, Gus J. Palenik, Anna E. Koziol, and Dennis L. Nosco
pp 1764 - 1772; DOI:
10.1021/ic00111a025
PDF
6Li and 7Li NMR in the LiNi1-yCoyO2 Solid Solution (0 .ltoreq. y .ltoreq. 1)
Claire Marichal, Jerome Hirschinger, Pierre Granger, Michel Menetrier, Aline Rougier, and Claude Delmas
pp 1773 - 1778; DOI:
10.1021/ic00111a026
PDF
Syntheses and Structural Characterizations of Six-Coordinate Oxo-M(V) Complexes (M = Tc, Re) Containing a Tetradentate P2N2-Phosphino-Amido Ligand
Francesco Tisato, Fiorenzo Refosco, Annarosa Moresco, Giuliano Bandoli, Alessandro Dolmella, and Cristina Bolzati
pp 1779 - 1787; DOI:
10.1021/ic00111a027
PDF
Protonation of Chloride in Os(H)2Cl2(PiPr3)2: Synthesis of [(PiPr3)2H2Os(.mu.-Cl)3OsH2(PiPr3)2]CF3SO3
Roger Kuhlman, William E. Streib, and Kenneth G. Caulton
pp 1788 - 1792; DOI:
10.1021/ic00111a028
PDF
Magnetic Transition and Structural Asymmetrization in the Ferromagnetic Compound [{Ni2(Medpt)2(N3)2}(.mu.-(1,1-N3)2)], an Example of a Dynamic Second-Order Jahn-Teller Effect
Albert Escuer, Ramon Vicente, Joan Ribas, and Xavier Solans
pp 1793 - 1798; DOI:
10.1021/ic00111a029
PDF
Hydridogallium Bis(tetrahydroborate) in the Gas Phase: Vibrational Properties and Structure Determined by Electron Diffraction and ab Initio and Density Functional Theory Computations
Anthony J. Downs, Tim M. Greene, Lisa A. Harman, Philip F. Souter, Paul T. Brain, Colin R. Pulham, David W. H. Rankin, Heather E. Robertson, Matthias Hofmann, and Paul v. R. Schleyer
pp 1799 - 1809; DOI:
10.1021/ic00111a030
PDF
Synthesis, Structure, and Binding of the Open Titanocene-Cagephosphite Complex Ti(2,4-C7H11)2[P(OCH2)3CC2H5]: Further Implications for Phosphite Cone Angles
Lothar Stahl, Wimonrat Trakarnpruk, Jeffrey W. Freeman, Atta M. Arif, and Richard D. Ernst
pp 1810 - 1814; DOI:
10.1021/ic00111a031
PDF
Sterically Encumbered Iron(II) Thiolate Complexes: Synthesis and Structure of Trigonal Planar [Fe(SR)3]- (R = 2,4,6-t-Bu3C6H2) and Moessbauer Spectra of Two- and Three-Coordinate Complexes
Frederick M. MacDonnell, Karin Ruhlandt-Senge, Jeffrey J. Ellison, R. H. Holm, and Philip P. Power
pp 1815 - 1822; DOI:
10.1021/ic00111a032
PDF
Molecular Recognition of Pyrophosphate by 1,13-Dioxa-4,7,10,16,19,22-hexaazacyclotetracosane (OBISDIEN) and by Its Mononuclear and Dinuclear Copper(II) Complexes. A Thermodynamic and Molecular Mechanics Study
Paul E. Jurek, Arthur E. Martell, Ramunas J. Motekaitis, and Robert D. Hancock
pp 1823 - 1829; DOI:
10.1021/ic00111a033
PDF
Comparative Bonding and Photophysical Properties of 2,2'-Bipyridine and 2,2'-Bipyrazine in Tetracyano Complexes Containing Ruthenium and Osmium
Monica E. Garcia Posse, Nestor E. Katz, Luis M. Baraldo, Diego D. Polonuer, Claudio G. Colombano, and Jose A. Olabe
pp 1830 - 1835; DOI:
10.1021/ic00111a034
PDF
Redox Properties and Electrocatalytic Activity of the Oxo/Aqua System [Ru(terpy)(bpz)(O)]2+/[Ru(terpy)(bpz)(H2O)]2+. X-ray Crystal Structure of [Ru(terpy)(bpz)Cl]PF6.cntdot.MeCN (terpy = 2,2',2''-Terpyridine; bpz = 2,2'-Bipyrazine)
Alessandra Gerli, Jan Reedijk, Miles T. Lakin, and Anthony L. Spek
pp 1836 - 1843; DOI:
10.1021/ic00111a035
PDF
Effect of Macrocyclic Ligand Constraints upon the Kinetics of Complex Formation and Dissociation and Metal Ion Exchange. Copper(II) Complexes with Cyclohexanediyl Derivatives of the Cyclic Tetrathiaether [14]aneS4 in 80% Methanol
Luciana Aronne, Qiuyue Yu, L. A. Ochrymowycz, and D. B. Rorabacher
pp 1844 - 1851; DOI:
10.1021/ic00111a036
PDF
Weak Inter- and Intralayer Exchange Coupling between Copper(II) Dimers and a Triplet Density Effect in EPR of Tris(ethylenediamine)cobalt(III) Bis(.mu.-chloro)bis[trichlorocuprate(II)] Dichloride Dihydrate
W. Hilczer, J. Goslar, J. Tritt-Goc, and S. K. Hoffmann
pp 1852 - 1858; DOI:
10.1021/ic00111a037
PDF
Reactions of [M(Se4)2]2- Anions with TePEt3: 77Se and 125Te Spectra of [MTenSe8-n]2- (M = Zn, Cd, Hg; n = 0-4) and Preparation and Crystal Structure of [PPh4]2[Hg(Te2Se2)2]
John C. Bollinger and James A. Ibers
pp 1859 - 1867; DOI:
10.1021/ic00111a038
PDF
On the Structure of the [XeOF5]- Anion and of Heptacoordinated Complex Fluorides Containing One or Two Highly Repulsive Ligands or Sterically Active Free Valence Electron Pairs
Karl O. Christe, David A. Dixon, Jeremy C. P. Sanders, Gary J. Schrobilgen, Scott S. Tsai, and William W. Wilson
pp 1868 - 1874; DOI:
10.1021/ic00111a039
PDF
Metal-Metal Multiply-Bonded Complexes of Technetium. 2. Preparation and Characterization of the Fully Solvated Ditechnetium Cation [Tc2(CH3CN)10]4+
Jeffrey C. Bryan, F. Albert Cotton, Lee M. Daniels, Steven C. Haefner, and Alfred P. Sattelberger
pp 1875 - 1883; DOI:
10.1021/ic00111a040
PDF
Study on an Assembly System Including Tetrathiovanadate. Syntheses and Structural Characterizations of V2Cu2S4 Cubane-Like Clusters and VS4Cu4 Bimetallic Aggregates
Qiutian Liu, Yu Yang, Liangren Huang, Daxu Wu, Beisheng Kang, Changneng Chen, Yuheng Deng, and Jiaxi Lu
pp 1884 - 1893; DOI:
10.1021/ic00111a041
PDF
Three New Polynuclear Bis(.mu.-phosphato) Vanadyl Clusters: [HB(pz)3VO(.mu.-(C6H5O)2PO2)]2, [HB(3,5-Me2pz)3VO(.mu.-(C6H5O)2PO2)].cntdot.C7H8, and H2O.cntnd.[t-Bupz(.mu.-C6H5OPO3)VO]6(H2O)2.cntdot.2CH3CH2OH. Adaptability of the Cyclic (OV)(OPO)2(VO) Bridging Unit
Marcus R. Bond, Ladd M. Mokry, Tom Otieno, Jeffrey Thompson, and Carl J. Carrano
pp 1894 - 1905; DOI:
10.1021/ic00111a042
PDF
Excited State Redox Potentials of Ruthenium Diimine Complexes; Correlations with Ground State Redox Potentials and Ligand Parameters
A. A. Vlcek, Elaine S. Dodsworth, William J. Pietro, and A. B. P. Lever
pp 1906 - 1913; DOI:
10.1021/ic00111a043
PDF
Ab Initio MO Study of the CO2 Insertion into the Cu(I)-R Bond (R = H, CH3, or OH). Comparison between the CO2 Insertion and the C2H4 Insertion
Shigeyoshi Sakaki and Yasuo Musashi
pp 1914 - 1923; DOI:
10.1021/ic00111a044
PDF
When Is an Odd-Electron Dinuclear Complex a Mixed-Valent Species? Tuning of Ligand-to-Metal Spin Shifts in Diruthenium(III,II) Complexes of Noninnocent Bridging Ligands OC(R)NNC(R)O
Volker Kasack, Wolfgang Kaim, Herbert Binder, Jeanne Jordanov, and Eberhard Roth
pp 1924 - 1933; DOI:
10.1021/ic00111a045
PDF
Iron(VI) in Tetrahedral Oxo Coordination: A Single Crystal EPR Study
B. Wagner, D. Reinen, T. C. Brunold, and H. U. Guedel
pp 1934 - 1942; DOI:
10.1021/ic00111a046
PDF
Coordination and Oxidation of N,N'-Bis(o-mercaptophenyl)ethylenediamine (HSNNSH) by VO2+: {V(-SNNS-)}4(.mu.-O)4 and Tetrabenzotetrathiatetraazacycloeicosane
Wenerios Tsagkalidis, Dieter Rodewald, and Dieter Rehder
pp 1943 - 1945; DOI:
10.1021/ic00111a047
PDF
Ten-Membered Rings of Coppers Interconnected by 2,5-Bis(2-pyridyl)pyrazine and Acetate Groups: Synthesis, Crystal Structure, and Magnetic Properties of the Two-Dimensional Polymer catena-(Octakis(.mu.2-acetato)[2,5-bis(2-pyridyl)pyrazine]tetracopper(II))
Antonia Neels, Helen Stoeckli-Evans, Albert Escuer, and Ramon Vicente
pp 1946 - 1949; DOI:
10.1021/ic00111a048
PDF
Has the Affinity of High Spin FeIII for sp3 Nitrogen Donors Been Underestimated?
Kaspar Hegetschweiler, Michele Ghisletta, Lorenza Hausherr-Primo, Thomas Kradolfer, Helmut W. Schmalle, and Volker Gramlich
pp 1950 - 1953; DOI:
10.1021/ic00111a049
PDF
Electron-Transfer Kinetics of the Copper(II/I) Complex with 1,4,8,11-Tetrathiacyclotetradecane in Acetonitrile
Brian C. Dunn, L. A. Ochrymowycz, and D. B. Rorabacher
pp 1954 - 1956; DOI:
10.1021/ic00111a050
PDF
Photoinduced Intercomponent Energy Transfer in a New Heterometallic Dinuclear Complex of Ru(II) and Os(II) with a 3,5-Bis(2-pyridyl)-1,2,4-triazole Cyclohexyl-Bridged Spacer
Gaetano Giuffrida, Giuseppe Calogero, Vittorio Ricevuto, and Sebastiano Campagna
pp 1957 - 1960; DOI:
10.1021/ic00111a051
PDF
Synthesis, Characterization, and X-ray Structure of the Mononuclear Eight-Coordinate Zirconium(IV) 2,2'-Oxydiacetate [Zr{(O(CH2CO2)2)}22H2O].cntdot.4H2O
Ricardo Baggio, Maria Teresa Garland, Mireille Perec, and Daniel Vega
pp 1961 - 1963; DOI:
10.1021/ic00111a052
PDF
Synthesis, Vibrational Spectra, and Single-Crystal X-ray Structure of the Phosphato-Bridged Dinuclear Peroxovanadate (NH4)5[V2O2(O2)4PO4].cntdot.H2O
Peter Schwendt, Jarmila Tyrselova, and Frantisek Pavelcik
pp 1964 - 1966; DOI:
10.1021/ic00111a053
PDF
Energy Transfer between Different Sites in Neat Single-Crystal [Ru(bpy)3](PF6)2
Dieter Braun and Hartmut Yersin
pp 1967 - 1968; DOI:
10.1021/ic00111a054
PDF
AMVMIII(PO4)3: New Mixed-Metal Phosphates Having NASICON and Related Structures
K. Kasthuri Rangan and J. Gopalakrishnan
pp 1969 - 1972; DOI:
10.1021/ic00111a055
PDF

Issue 8


Synthesis and Chemistry of [Hydridotris(3-t-butylpyrazolyl)borato]indium(I)
H. V. Rasika Dias, Liu Huai, Wiechang Jin, and Simon G. Bott
pp 1973 - 1974; DOI:
10.1021/ic00112a001
PDF
Synthesis and Structure of [Hydridotris(3,5-bis(trifluoromethyl)pyrazolyl)borato]potassium
H. V. Rasika Dias, Hui-Ling Lu, Robert E. Ratcliff, and Simon G. Bott
pp 1975 - 1976; DOI:
10.1021/ic00112a002
PDF
Electrospray Mass Spectrometry of Borane Salts: Observation of High Molecular Weight Ion Clusters
Cornelis E. C. A. Hop, Dovas A. Saulys, and Donald F. Gaines
pp 1977 - 1978; DOI:
10.1021/ic00112a003
PDF
A Solid-State Diastereomer, AgLa3GeS7
Shiou-Jyh Hwu, Cordelia K. Bucher, James D. Carpenter, and Stephen P. Taylor
pp 1979 - 1980; DOI:
10.1021/ic00112a004
PDF
Synthesis, Structure, and Properties of a Binuclear Iron-Thiolate Complex with a trans-Disulfur Bridge: A Structural Isomer of the [Fe2S2] Core of 2-Fe Ferredoxins
John D. Franolic, Michelle Millar, and Stephen A. Koch
pp 1981 - 1982; DOI:
10.1021/ic00112a005
PDF
An effective core potential ab initio study of electronic structure and bandwidth-charge transport relationships in low-dimensional, partially oxidized palladium glyoximates
Santo Di Bella, l Giuseppe Lanza, Ignazio Fragalal, Tobin J. Marksl, and Mark A. Ratnerl
pp 1983 - 1987; DOI:
10.1021/ic00112a006
PDF
Molecular Modeling of Dimetal Systems. Dimolybdenum Quadruple Bonds
Jan C. A. Boeyens and Francoise M. M. O'Neill
pp 1988 - 1995; DOI:
10.1021/ic00112a007
PDF
Solid State EXAFS and Luminescence Studies of Neutral, Dinuclear Gold(I) Complexes. Gold(I)-Gold(I) Interactions in the Solid State
William B. Jones, B. Jie Yuan, Ratnavathany Narayanaswamy, Michelle A. Young, R. C. Elder, Alice E. Bruce, and Mitchell R. M. Bruce
pp 1996 - 2001; DOI:
10.1021/ic00112a008
PDF
Dramatic Increase of 3MLCT State Lifetimes of a Ruthenium(II) Polypyridine Complex upon Entrapment within Y-Zeolite Supercages
Krzysztof Maruszewski and James R. Kincaid
pp 2002 - 2006; DOI:
10.1021/ic00112a009
PDF
Luminescent Platinum(II) Complexes of Quinoxaline-2,3-dithiolate
Scott D. Cummings and Richard Eisenberg
pp 2007 - 2014; DOI:
10.1021/ic00112a010
PDF
Luminescence Quenching of Copper(II) Porphyrins with Lewis Bases
Fang Liu, Kurstan L. Cunningham, Wendy Uphues, Gerald W. Fink, Johnathan Schmolt, and David R. McMillin
pp 2015 - 2018; DOI:
10.1021/ic00112a011
PDF
The Cu2(C6H5NNNC6H5)2 Dimer. Theoretical and Spectroscopic Investigations of the First Example of a Fluorescent d10-d10 Complex
Pierre D. Harvey
pp 2019 - 2024; DOI:
10.1021/ic00112a012
PDF
Synthesis and Electrochemical and Spectroscopic Properties of a Series of Binuclear and Trinuclear Ruthenium and Palladium Complexes Based on a New Bridging Ligand Containing Terpyridyl and Catechol Binding Sites
Brenda Whittle, Nicholas S. Everest, Christine Howard, and Michael D. Ward
pp 2025 - 2032; DOI:
10.1021/ic00112a013
PDF
Rhenium(I) Coordination Chemistry: Synthesis, Reactivity, and Electrochemistry of Terpyridyl Complexes
Lisa E. Helberg, Joseph Barrera, Michal Sabat, and W. Dean Harman
pp 2033 - 2041; DOI:
10.1021/ic00112a014
PDF
Variable-Temperature and -Pressure Multinuclear Magnetic Resonance Studies on Solvent Exchange of Cobalt(II), Iron(II), and Manganese(II) Ions in Ethylenediamine. Kinetic Chelate Effect and Chelate Strain Effect
Sen-ichi Aizawa, Kayoko Matsuda, Tomomi Tajima, Machiyo Maeda, Takashi Sugata, and Shigenobu Funahashi
pp 2042 - 2047; DOI:
10.1021/ic00112a015
PDF
Magneto-Structural Effects of the Jahn-Teller Distortions on 2,2'-Bipyrimidine-, (bpm-) Bridged Dinuclear Copper(II) Complexes: Crystal Structures and Magnetic Properties of [Cu2(bpm)(H2O)4(SO4)2].cntdot.3H2O and [Cu2(bpm)(H2O)8](SO4)2.cntdot.2H2O
Giovanni De Munno, Miguel Julve, Francesc Lloret, Juan Cano, and Andrea Caneschi
pp 2048 - 2053; DOI:
10.1021/ic00112a016
PDF
The Unsolvated Pentachloroferrate(III) Ion. X-ray Crystal Structure and Low-Temperature Magnetism of Tetramethylpiperazinium Pentachloroferrate(III)
Bruce D. James, John Liesegang, Margarita Bakalova, William M. Reiff, Brian W. Skelton, and Allan H. White
pp 2054 - 2057; DOI:
10.1021/ic00112a017
PDF
Organotransition-Metal Metallacarboranes. 37. Paramagnetic Iron-Cobalt and Dicobalt Triple-Decker Sandwich Complexes
Martin Stephan, Peter Mueller, Ulrich Zenneck, Hans Pritzkow, Walter Siebert, and Russell N. Grimes
pp 2058 - 2067; DOI:
10.1021/ic00112a018
PDF
Synthetic, Structural, and Spectroscopic Studies on Solids Containing Tris(dipicolinato) Rare Earth Anions and Transition or Main Group Metal Cations
Philippa A. Brayshaw, Jean-Claude G. Buenzli, Pascal Froidevaux, Jack M. Harrowfield, Yang Kim, and Alexander N. Sobolev
pp 2068 - 2076; DOI:
10.1021/ic00112a019
PDF
High Pressure Synthesis of NdCuO3-.delta. Perovskites (0 .ltoreq. .delta. .ltoreq. 0.5)
Bai-Hao Chen, Dave Walker, Emmanuelle Suard, Bruce A. Scott, Bernard Mercey, Maryvonne Hervieu, and Bernard Raveau
pp 2077 - 2083; DOI:
10.1021/ic00112a020
PDF
Stoichiometry of Potassium- and Carbonate-Containing Apatites Synthesized by Solid State Reactions
Ronald M. H. Verbeeck, Erna A. P. De Maeyer, and Ferdinand C. M. Driessens
pp 2084 - 2088; DOI:
10.1021/ic00112a021
PDF
The Equilibrium between cis- and trans-Fluoroformyl Hypofluorite, FC(O)OF. Thermodynamic Properties, Molecular Structures, and Vibrational Spectra
Gustavo A. Arguello, Bernd Juelicher, Sonia E. Ulic, Helge Willner, Bernd Casper, Hans-Georg Mack, and Heinz Oberhammer
pp 2089 - 2094; DOI:
10.1021/ic00112a022
PDF
Facile Electrophilic Iodination of Icosahedral Carboranes. Synthesis of Carborane Derivatives with Boron-Carbon Bonds via the Palladium-Catalyzed Reaction of Diiodocarboranes with Grignard Reagents
Zhiping Zheng, Wei Jiang, Alfred A. Zinn, Carolyn B. Knobler, and M. Frederick Hawthorne
pp 2095 - 2100; DOI:
10.1021/ic00112a023
PDF
Preparation and Characterization of Cobaltaboranes Containing Cobalt Carbonyl Fragments
Chang-Soo Jun, Jean-Francois Halet, Arnold L. Rheingold, and Thomas P. Fehlner
pp 2101 - 2107; DOI:
10.1021/ic00112a024
PDF
B-N Bond Formation by the Reaction of (N-(3-Methoxysalicylidene)-N'-(imidazol-4-ylmethylene)-1,3-propanediamino)copper(II) Perchlorate and Sodium Tetraphenylborate
Takeshi Nozaki, Naohide Matsumoto, Hisashi Okawa, Hitoshi Miyasaka, and Genjin Mago
pp 2108 - 2112; DOI:
10.1021/ic00112a025
PDF
Reactivity of a Tetrakis(pyrazolyl)borate Oxorhenium Complex
Antonio Paulo, Angela Domingos, Joaquim Marcalo, Antonio Pires de Matos, and Isabel Santos
pp 2113 - 2120; DOI:
10.1021/ic00112a026
PDF
Cluster Growth: Some Representative Reactions. Crystal Structures of [Pt(H)(AgNO3)(AuPPh3)8](NO3) and [Pt(H)(AgNO3)2(AuPPh3)8](NO3)
T. G. M. M. Kappen, P. P. J. Schlebos, J. J. Bour, W. P. Bosman, G. Beurskens, J. M. M. Smits, P. T. Beurskens, and J. J. Steggerda
pp 2121 - 2132; DOI:
10.1021/ic00112a027
PDF
New Hydride-Containing Mixed Metal-Gold Phosphine Clusters. Crystal Structures of [Pt(H)(CuCl)(AuPPh3)8](NO3) and [Pt(H)(CuCl)2(AuPPh3)8](NO3)
T. G. M. M. Kappen, P. P. J. Schlebos, J. J. Bour, W. P. Bosman, J. M. M. Smits, P. T. Beurskens, and J. J. Steggerda
pp 2133 - 2142; DOI:
10.1021/ic00112a028
PDF
Lipophilic Hexadentate Aluminum Complexes of New Phenolate-Derivatized Cyclohexanetriamine Ligands and Their Effect on the Peptide Transport System (PTS-1)
James E. Bollinger, Joel T. Mague, William A. Banks, Abba J. Kastin, and D. Max Roundhill
pp 2143 - 2152; DOI:
10.1021/ic00112a029
PDF
Synthesis and Reactivity of Mononuclear Anionic Pentafluorophenyl Compounds of Rhodium(I) and Iridium(I). X-ray Structure of [{P(OPh)3}2(C6F5)2RhAg(PPh3)]
Maria P. Garcia, M. Victoria Jimenez, Fernando J. Lahoz, and Luis A. Oro
pp 2153 - 2159; DOI:
10.1021/ic00112a030
PDF
Polyoxometalate-Diphosphate Complexes. 3. Possible Intermediates in the Molybdate-Catalyzed Hydrolysis of Pyrophosphate. The Structure of Hexamolybdomethylenediphosphonate, [(O3PCH2PO3)Mo6O18(H2O)4]4-
Uli Kortz and Michael T. Pope
pp 2160 - 2163; DOI:
10.1021/ic00112a031
PDF
Complexes of Trivalent Metal Ions with Potentially Heptadentate N4O3 Schiff Base and Amine Phenol Ligands of Varying Rigidity
Li-Wei Yang, Shuang Liu, Ernest Wong, Steven J. Rettig, and Chris Orvig
pp 2164 - 2178; DOI:
10.1021/ic00112a032
PDF
Syntheses and Structures of Lithiated Tetramines: [Li3(Me3SiNCH2CH2)3N(THF)2] and {(.mu.3-Cl)Li3H4[(Me3SiNCH2CH2)3N]2}
Zhibang Duan, Victor G. Young, and John G. Verkade
pp 2179 - 2185; DOI:
10.1021/ic00112a033
PDF
Intramolecularly Base-Stabilized Group 13 Aryloxide Complexes
David A. Atwood, Alan H. Cowley, Rodney D. Schluter, Marcus R. Bond, and Carl J. Carrano
pp 2186 - 2189; DOI:
10.1021/ic00112a034
PDF
Synthesis and Molecular Structures of the Redox Pair (Octaethylporphinato)bis(pentamethylene sulfide)osmium(II) and (Octaethylporphinato)bis(pentamethylene sulfide)osmium(III) Hexafluorophosphate
W. Robert Scheidt and Habib Nasri
pp 2190 - 2193; DOI:
10.1021/ic00112a035
PDF
Production of Oxaporphyrin and Biliverdin Derivatives by Coupled Oxidation of Cobalt(II) Octaethylporphyrin
Alan L. Balch, Marinella Mazzanti, Tamara N. St. Claire, and Marilyn M. Olmstead
pp 2194 - 2200; DOI:
10.1021/ic00112a036
PDF
Oxidation of Nickel(II) Tetraphenylporphyrin Revisited. Characterization of Stable Nickel(III) Complexes at Room Temperature
Jyoti Seth, Vaithianathan Palaniappan, and David F. Bocian
pp 2201 - 2206; DOI:
10.1021/ic00112a037
PDF
Zinc Complexes of the Ligand Dipicolylglycine
Ahmed Abufarag and Heinrich Vahrenkamp
pp 2207 - 2216; DOI:
10.1021/ic00112a038
PDF
Modeling Dinuclear Copper Sites of Biological Relevance: Synthesis, Molecular Structure, Magnetic Properties, and 1H NMR Spectroscopy of a Nonsymmetric Dinuclear Copper(II) Complex. Microcalorimetric Determination of Stepwise Complexation of Copper(II) by a Nonsymmetric Dinucleating Ligand
Marcel Lubben, Ronald Hage, Auke Meetsma, and Ben L. Feringa
pp 2217 - 2224; DOI:
10.1021/ic00112a039
PDF
Synthesis, Crystal Structure, and Potentiometry of Pyridine-Containing Tetraaza Macrocyclic Ligands with Acetate Pendant Arms
Won D. Kim, Duane C. Hrncir, Garry E. Kiefer, and A. Dean Sherry
pp 2225 - 2232; DOI:
10.1021/ic00112a040
PDF
Relaxometry, Luminescence Measurement, Electrophoresis, and Animal Biodistribution of Lanthanide(III) Complexes of Some Polyaza Macrocyclic Acetates Containing Pyridine
Won D. Kim, Garry E. Kiefer, Frederic Maton, Kenneth McMillan, Robert N. Muller, and A. Dean Sherry
pp 2233 - 2243; DOI:
10.1021/ic00112a041
PDF
Influence of Side Chains on Electronic Coupling between Metal Centers in Simple Model Systems
Nita A. Lewis and Wei Pan
pp 2244 - 2250; DOI:
10.1021/ic00112a042
PDF
Facile Syntheses and Transformations of a Series of Tellurium-Iron Carbonyl Clusters: Crystal Structures of [PhCH2NMe3]2[Te6Fe8(CO)24], Fe2(CO)6(.mu.-TeCHCl2)2, and Fe2(CO)6(.mu.-TeCHPhTe)
Minghuey Shieh, Pao-Fei Chen, Yi-Chou Tsai, Mei-Huey Shieh, Shie-Ming Peng, and Gene-Hsiang Lee
pp 2251 - 2254; DOI:
10.1021/ic00112a043
PDF
Crystal Structure and Magnetic Properties of a 2D Sheetlike .mu.-Cyanido- and .mu.-Oxamidato-Bridged Fe(III)-Cu(II) Bimetallic Complex
Zhong Ning Chen, Jing Ling Wang, Jun Qiu, Fang Ming Miao, and Wen Xia Tang
pp 2255 - 2257; DOI:
10.1021/ic00112a044
PDF
Reaction of Cp*3Co3(.mu.3-CCH3)(.mu.3-H) with (Trimethylsilyl)diazomethane and Ethyl Diazoacetate: Facile Hydrogen Transfer Forms the Diazenide Clusters Cp*3Co3(.mu.3-CCH3)(.mu.3-.eta.1-NNCH2SiMe3) and Cp*3Co3(.mu.3-CCH3)(.mu.3-.eta.1-NNCH2CO2Et)
Charles P. Casey, Ross A. Widenhoefer, and Randy K. Hayashi
pp 2258 - 2262; DOI:
10.1021/ic00112a045
PDF
New Three-Dimensional Ferrimagnetic Materials: K2Mn[Mn(CN)6], Mn3[Mn(CN)6]2.cntdot.12H2O, and CsMn[Mn(CN)6.cntdot. 1/2H2O. [Erratum to document cited in CA121:270418]
William R. Entley and Gregory S. Girolami
pp 2262 - 2262; DOI:
10.1021/ic00112a046
PDF

Issue 9


The First Metal Complex Involving an .alpha.-H-Containing Nitroxide
Victor I. Ovcharenko, Fabrice Lanfranc de Panthou, Natalie V. Pervukhina, Vladimir A. Reznikov, Paul Rey, and Renad Z. Sagdeev
pp 2263 - 2264; DOI:
10.1021/ic00113a001
PDF
Modeling the Reactivity of .alpha.-Ketoglutarate-Dependent Non-Heme Iron(II)-Containing Enzymes
Edward H. Ha, Raymond Y. N. Ho, James F. Kisiel, and Joan Selverstone Valentine
pp 2265 - 2266; DOI:
10.1021/ic00113a002
PDF
Synthesis and Structural Characterization of the [Nb(O)(S2)2SH]2-, [Nb(S)3SH]2-, and {[Nb(S)3]2O}4- anions. New elementary Thio- and Oxothioniobates
B. S. Mandimutsira, S.-J. Chen, K. D. Demadis, and D. Coucouvanis
pp 2267 - 2268; DOI:
10.1021/ic00113a003
PDF
Synthesis and Crystal and Molecular Structure of Cesium Hexakis(fluorosulfato)antimonate(V) and Its Role in the HSO3F-Sb(SO3F)5 Conjugate Superacid System
Dingliang Zhang, Steven J. Rettig, James Trotter, and Friedhelm Aubke
pp 2269 - 2270; DOI:
10.1021/ic00113a004
PDF
Synthesis and Crystal Structure of the First Inverse 12-Metallacrown-4
Ann J. Stemmler, Jeff W. Kampf, and Vincent L. Pecoraro
pp 2271 - 2272; DOI:
10.1021/ic00113a005
PDF
Synthesis and Crystal Structures of (Phosphine)technetium(V) Complexes with Phenylimido and Phenyldiazenido Ligands Using the Precursor PhNHNHCO3
Fernande D. Rochon, Robert Melanson, and Pi-Chang Kong
pp 2273 - 2277; DOI:
10.1021/ic00113a006
PDF
Kinetic and Mechanistic Aspects of Sulfur Abstraction from Pd2X2(.mu.-S)(.mu.-dpm)2 Using dpm or dpmMe [X = Halide, dpm = Bis(diphenylphosphino)methane, dpmMe = 1,1'-Bis(diphenylphosphino)ethane]
Terrance Y. H. Wong, A. Freddy Barnabas, Dominique Sallin, and Brian R. James
pp 2278 - 2286; DOI:
10.1021/ic00113a007
PDF
Rhenium(V) and Technetium(V) Complexes of Phosphinidenediphenolate (PO22-) and Phosphinophenolate (PO-) Ligands
Hongyan Luo, Ika Setyawati, Steven J. Rettig, and Chris Orvig
pp 2287 - 2299; DOI:
10.1021/ic00113a008
PDF
Heavy Metal Complexes of Oxa-Crowned Derivatives of Dithiomaleonitrile
John W. Sibert, Steven J. Lange, Brian M. Hoffman, David J. Williams, and A. G. M. Barrett
pp 2300 - 2305; DOI:
10.1021/ic00113a009
PDF
Synthesis and Characterization of Two New Schiff-Bases and Their Soluble Linear Cerium(IV) Polymers
Huiyong Chen, Jon A. Cronin, and Ronald D. Archer
pp 2306 - 2315; DOI:
10.1021/ic00113a010
PDF
Bis[platinum(II)] and Bis[palladium(II)] Complexes of .alpha.,.omega.-Dicarboxylic Acid Bis(1,2,4-triaminobutane-N4) Amides
Elfriede Schumann, Janina Altman, Konstantin Karaghiosoff, and Wolfgang Beck
pp 2316 - 2322; DOI:
10.1021/ic00113a011
PDF
Dinuclear Metal Carbonyls Bridged by Pyridyl Ligands Incorporating an Alkyne Entity
Jiann T. Lin, Shih-Sheng Sun, Jiann Jung Wu, Liangshiu Lee, Kuan-Jiuh Lin, and Yi Fong Huang
pp 2323 - 2333; DOI:
10.1021/ic00113a012
PDF
Synthesis, Structure, and Spectroscopic Properties of Ortho-Metalated Platinum(II) Complexes
Millan M. Mdleleni, Jon S. Bridgewater, Richard J. Watts, and Peter C. Ford
pp 2334 - 2342; DOI:
10.1021/ic00113a013
PDF
Cyclopentadienylniobium(V) Phosphine Chemistry: Adduct Formation vs Reduction. X-ray Structure of CpNbCl4(PMePh2)
James C. Fettinger, D. Webster Keogh, and Rinaldo Poli
pp 2343 - 2347; DOI:
10.1021/ic00113a014
PDF
Bonding and Structure of Heavily .pi.-Loaded Complexes
Michael T. Benson, Jeffrey C. Bryan, Anthony K. Burrell, and Thomas R. Cundari
pp 2348 - 2355; DOI:
10.1021/ic00113a015
PDF
Magneto-structural correlations in .mu.2-1,1-azide-bridged dicopper(II) complexes. 2. Dominant antiferromagnetic coupling with azide bridge angles exceeding 108.degree.. X-ray Structures of [Cu2(PAP)(.mu.2-N3)Br3].cntdot.CH2Cl2, [Cu2(PAP6Me)(.mu.2-N3)(.mu.2-Br)Br2].cntdot.1.68H2O, [Cu2(PAP6Me)(.mu.2-N3)(.mu.2-H2O)(NO3)2](NO3).cntdot.0.75CH3OH, [Cu2(PAN)(.mu.2-N3)(.mu.2-NO3)(NO3)2].cntdot.CH3OH.cntdot.CH3CN, and [Cu2(PPD35Me)(.mu.2-N3)Br3(CH3OH)]
Laurence K. Thompson, Santokh. S. Tandon, and Mike E. Manuel
pp 2356 - 2366; DOI:
10.1021/ic00113a016
PDF
Preparation and Structure of a Manganese Antimony .mu.5-Oxo Ethoxide, Mn8Sb4(.mu.5-O)4(.mu.3-OEt)4(.mu.-OEt)16
U. Bemm, R. Norrestam, M. Nygren, and G. Westin
pp 2367 - 2370; DOI:
10.1021/ic00113a017
PDF
Investigation of Lithium Chloride/Ambient-Temperature 1-Methyl-3-ethylimidazolium Chloride-Aluminum Chloride Ionic Liquids. 1. Ion Interactions in a Neutral Tetrachloroaluminate Melt
Y. S. Fung and S. M. Chau
pp 2371 - 2376; DOI:
10.1021/ic00113a018
PDF
Investigation of Solid and Solution Structures of N-Substituted Cu(II) Salicyldimines by X-Ray Absorption Spectroscopy
Michael D. Wirt, Luigi Bubacco, and Jack Peisach
pp 2377 - 2381; DOI:
10.1021/ic00113a019
PDF
Synthesis, Crystal Structure, and Properties of a Polyimidazole Diiron(III) Complex. A New Model of the Active Site of Purple Acid Phosphatase
Hanlin Nie, Sheila Aubin, Mark S. Mashuta, Jimmy Wu, John F. Richardson, David N. Hendrickson, and Robert M. Buchanan
pp 2382 - 2388; DOI:
10.1021/ic00113a020
PDF
A More Intimate Examination of the Role of Copper(I) in the Decarboxylation of Derivatives of Malonic Acid. Comparisons with Zinc(II) Analogs
Donald J. Darensbourg, Matthew W. Holtcamp, Bandana Khandelwal, Kevin K. Klausmeyer, and Joseph H. Reibenspies
pp 2389 - 2398; DOI:
10.1021/ic00113a021
PDF
Structural Variations in Layered Alkali Metal Naphthalenesulfonates
Brian J. Gunderman and Philip J. Squattrito
pp 2399 - 2406; DOI:
10.1021/ic00113a022
PDF
Core Distortions and Geometries of the Difluorides and Dihydrides of Ca, Sr, and Ba
Ian Bytheway, Ronald J. Gillespie, Ting-Hua Tang, and Richard F. W. Bader
pp 2407 - 2414; DOI:
10.1021/ic00113a023
PDF
Molecular Orbital Calculations of Octahedral Molybdenum Cluster Complexes with the DV-X.alpha. Method
Hideo Imoto, Taro Saito, and Hirohiko Adachi
pp 2415 - 2422; DOI:
10.1021/ic00113a024
PDF
Slow Proton Exchange Kinetics in Aqueous Solutions of Hexaaquarhodium(III): Influence of the Second Hydration Sphere
Istvan Banyai, Julius Glaser, Michael C. Read, and Magnus Sandstroem
pp 2423 - 2429; DOI:
10.1021/ic00113a025
PDF
Vitamin B1: Chemical Interaction with CdCl2 and in vivo Effects on Cadmium Toxicity in Rats. Crystal Structure of [Cd(thiamine)Cl3]2.cntdot.2H2O, a Complex Containing Pyrimidine and Cadmium-Hydroxyethyl Bonds
Jose S. Casas, Eduardo E. Castellano, Maria D. Couce, Agustin Sanchez, Jose Sordo, Jose M. Varela, and Julio Zukerman-Schpector
pp 2430 - 2437; DOI:
10.1021/ic00113a026
PDF
Synthesis, Electrochemical Behavior, and Spectroscopic and Luminescence Properties of Dinuclear Species Containing [Ru(diimine)3]2+ and [Re(diimine)Cl(CO)3] Chromophores Bridged by a Nonsymmetric Quaterpyridine Ligand
David A. Bardwell, Francesco Barigelletti, Rosemary L. Cleary, Lucia Flamigni, Massimo Guardigli, John C. Jeffery, and Michael D. Ward
pp 2438 - 2446; DOI:
10.1021/ic00113a027
PDF
Synthesis, Structure, and Spectroscopic Properties of Bismuth Citrate Compounds and the Bismuth-Containing Ulcer-Healing Agent Colloidal Bismuth Subcitrate (CBS). 4. Crystal Structure and Solution Behavior of a Unique Dodecanuclear Cluster (NH4)12[Bi12O8(cit)8](H2O)10
Eiji Asato, Kosho Katsura, Masahiro Mikuriya, Urho Turpeinen, Ilpo Mutikainen, and Jan Reedijk
pp 2447 - 2454; DOI:
10.1021/ic00113a028
PDF
Potentiometric and Spectroscopic Study of Nickel(II) and Cobalt(II) Complexes of Histamine-Containing Dipeptides
Tamas Gajda, Bernard Henry, and Jean-Jacques Delpuech
pp 2455 - 2460; DOI:
10.1021/ic00113a029
PDF
The First Arsenido-Substituted Niobocene Derivative
Georgii I. Nikonov, Jorg Lorberth, Klaus Harms, and Dmitry A. Lemenovskii
pp 2461 - 2463; DOI:
10.1021/ic00113a030
PDF
Analysis of Multiply Charged Ions of Ruthenium(II) Tetranuclear Complexes by Electrospray Ionization Mass Spectrometry
Ryuichi Arakawa, Takekiyo Matsuo, Koichi Nozaki, Takeshi Ohno, and Masa-aki Haga
pp 2464 - 2467; DOI:
10.1021/ic00113a031
PDF
Photoredox Decomposition of (PPh3)3CuI(.mu.-Cl)FeIIICl3 Induced by Metal-to-Metal Charge Transfer Excitation
Horst Kunkely and Arnd Vogler
pp 2468 - 2469; DOI:
10.1021/ic00113a032
PDF
RuHX(H2)(PiPr3)2 (X = Cl, I): 16 Electron Dihydrogen-Hydride or Trihydride Complexes?
Timothy Burrow, Sylviane Sabo-Etienne, and Bruno Chaudret
pp 2470 - 2472; DOI:
10.1021/ic00113a033
PDF
Syntheses of Palladium(II) Chalcogenide Complexes. Solid State Structure of [(CH3)2NCS2]Pd(PEt3)SCH3
Daniel L. Reger and James E. Collins
pp 2473 - 2475; DOI:
10.1021/ic00113a034
PDF
Synthesis, Characterization, and X-ray Study of a Heteroleptic Samarium(III) Porphyrin Double Decker Complex
G. A. Spyroulias, A. G. Coutsolelos, C. P. Raptopoulou, and A. Terzis
pp 2476 - 2479; DOI:
10.1021/ic00113a035
PDF
Synthesis and Characterization of cis-[Mo6Cl8(Cl4)(P(C2H5)3)2].cntdot.2THF
Grant M. Ehrlich, Haibin Deng, Laurie I. Hill, M. L. Steigerwald, Philip J. Squattrito, and Francis J. DiSalvo
pp 2480 - 2482; DOI:
10.1021/ic00113a036
PDF
Synthesis and Crystal Structure of an Organoimido Molybdenum(V) Porphyrin Salt, [Mo(NMe)(TPP)(H2O)][I3] (TPP = Tetraphenylporphyrin)
Ju Chang Kim, William S. Rees, and Virgil L. Goedken
pp 2483 - 2486; DOI:
10.1021/ic00113a037
PDF
Characterization of (Trimethyltriazacyclononane)triaquozinc(II) Nitrate. A Nonbridged Isomer
Gail C. Silver, Peter Gantzel, and William C. Trogler
pp 2487 - 2489; DOI:
10.1021/ic00113a038
PDF
Syntheses, Structures, and Spectroscopic Properties of Gold(I) Complexes of 1,3,5-Triaza-7-phosphaadamantane (TPA). Correlation of the Supramolecular Au.cntdot. .cntdot. .cntdot.Au Interaction and Photoluminescence for the Species (TPA)AuCl and [(TPA-HCl)AuCl] [Erratum to document cited in CA122:44906]
Zerihun Assefa, Brian G. McBurnett, Richard J. Staples, John P. Jr. Fackler, Bernd Assmann, Klaus Angermaier, and Hubert Schmidbaur
pp 2490 - 2490; DOI:
10.1021/ic00113a039
PDF

Issue 10


Influence of Lead(II) Lone Pairs on the Serpentine Structures for Heterometallic Alkoxides
Daniel J. Teff, John C. Huffman, and Kenneth G. Caulton
pp 2491 - 2492; DOI:
10.1021/ic00114a001
PDF
First Example of a Mixed Valence MnIIIMnIIMnIII Schiff-Base Polymeric Complex having a Trimeric Repeat Unit. Crystal Structure of [Mn3(HL)2(acetato)2(5-Cl-salicylato)2]n
Dora A. Malamatari, Panagiota Hitou, Antonis G. Hatzidimitriou, Frank E. Inscore, Andre Gourdon, Martin L. Kirk, and Dimitris P. Kessissoglou
pp 2493 - 2494; DOI:
10.1021/ic00114a002
PDF
Linear Titanoxanes via the Assembling of Bridging and Terminal Oxo-Titanium(IV) Fragments
Emma Gallo, Euro Solari, Federico Franceschi, Carlo Floriani, Angiola Chiesi-Villa, and Corrado Rizzoli
pp 2495 - 2496; DOI:
10.1021/ic00114a003
PDF
The 199Hg Chemical Shift as a Probe of Coordination Environments in Blue Copper Proteins
Lisa M. Utschig, Jeffery G. Wright, Gregg Dieckmann, Vincent Pecoraro, and Thomas V. O'Halloran
pp 2497 - 2498; DOI:
10.1021/ic00114a004
PDF
Permethyltitanocene Tellurides and Ditellurides. X-ray Structures of [(C5Me5)2Ti]2(.mu.-Te) and (C5Me5)2Ti(.eta.2-Te2)
Jason M. Fischer, Warren E. Piers, Leonard R. MacGillivray, and Michael J. Zaworotko
pp 2499 - 2500; DOI:
10.1021/ic00114a005
PDF
Nickel L-Edge X-ray Absorption Spectroscopy of Pyrococcus furiosus Hydrogenase
J. van Elp, G. Peng, Z. H. Zhou, M. W. W. Adams, N. Baidya, P. K. Mascharak, and S. P. Cramer
pp 2501 - 2504; DOI:
10.1021/ic00114a006
PDF
X-ray Absorption Spectroscopic Studies of the Diiron Center in Methane Monooxygenase in the Presence of Substrate and the Coupling Protein of the Enzyme System
Jane G. DeWitt, Amy C. Rosenzweig, Athanasios Salifoglou, Britt Hedman, Stephen J. Lippard, and Keith O. Hodgson
pp 2505 - 2515; DOI:
10.1021/ic00114a007
PDF
Sequence-Specific Assignment of Ligand Cysteine Protons of Oxidized, Recombinant HiPIP I from Ectothiorhodospira halophila
Ivano Bertini, Francesco Capozzi, Lindsay D. Eltis, Isabella Caterina Felli, Claudio Luchinat, and Mario Piccioli
pp 2516 - 2523; DOI:
10.1021/ic00114a008
PDF
A Slow Exchanging Vanadium(V) Peptide Complex: Vanadium(V)-Glycine-Tyrosine
Debbie C. Crans, Hartmut Holst, Anastasios D. Keramidas, and Dieter Rehder
pp 2524 - 2534; DOI:
10.1021/ic00114a009
PDF
(.mu.-Nitrido)((tetraphenylporphyrinato)iron)((phthalocyaninato)iron) and Its Fe-Ru Analog: Redox Behavior and Characterization of New Fe(IV)-Containing Species. X-ray Crystal Structure of [(THF)(TPP)Fe-N-FePc(H2O)](I5).cntdot.2THF
C. Ercolani, J. Jubb, G. Pennesi, U. Russo, and G. Trigiante
pp 2535 - 2541; DOI:
10.1021/ic00114a010
PDF
Pentamethylcyclopentadienyl and Cyclopentadienyl Tantalum and Niobium Calixarene Compounds and Their Water and Acetonitrile Inclusion Complexes
Jacqueline A. Acho, Linda H. Doerrer, and Stephen J. Lippard
pp 2542 - 2556; DOI:
10.1021/ic00114a011
PDF
Net Amine Dealkylation at a Diruthenium Center: Dehydrogenation of a Secondary Amine and Hydrolysis of a Coordinated Imine
Deryn E. Fogg and Brian R. James
pp 2557 - 2561; DOI:
10.1021/ic00114a012
PDF
Synthesis, Cyclic Voltammetry, and x-ray Crystal Structures of Copper(I) and Copper(II) Complexes of Tris((6-phenyl-2-pyridyl)methyl)amine (TPPA)
Chang-lin Chuang, Kitae Lim, Qiu Chen, Jon Zubieta, and James W. Canary
pp 2562 - 2568; DOI:
10.1021/ic00114a013
PDF
Coordination Chemistry of the Pseudochalcogen Nitrite Analog Nitrosodicyanomethanide
D. Scott Bohle, Brenda J. Conklin, and Chen-Hsiung Hung
pp 2569 - 2581; DOI:
10.1021/ic00114a014
PDF
Synthesis and Characterization of [(C5Me5)2OsH]2[Os2Br8]. The Eclipsed Rotamer of the Triply-Bonded Os2Br82- Anion
Christopher L. Gross, Scott R. Wilson, and Gregory S. Girolami
pp 2582 - 2586; DOI:
10.1021/ic00114a015
PDF
Synthesis and Characterization of the Strontium Thiolate Sr(SMes*)2(THF)4.cntdot.2THF (Mes* = 2,4,6-tBu3C6H2) and Selenolate Sr(SeMes*)2(THF)4.cntdot.2THF. Structural Investigation of SrI2(THF)5
Karin Ruhlandt-Senge, Kelly Davis, Sona Dalal, Ulrich Englich, and Mathias O. Senge
pp 2587 - 2592; DOI:
10.1021/ic00114a016
PDF
Synthesis and Structure of Unassociated Mono-, Di- and Trithiolate Derivatives of Aluminum and Gallium: Investigation of Al-S and Ga-S .pi.-Bonding
Rudolf J. Wehmschulte, Karin Ruhlandt-Senge, and Philip P. Power
pp 2593 - 2599; DOI:
10.1021/ic00114a017
PDF
Copper(II) Complexes Immobilized on a Polymeric Matrix. Thermodynamics, Spectroscopy, and Molecular Modeling
E. Chiessi, M. Branca, A. Palleschi, and B. Pispisa
pp 2600 - 2609; DOI:
10.1021/ic00114a018
PDF
Multiple Imido Complexes of Molybdenum: Synthesis and Reactivity of the d0 Mo(:NR)3 Functional Group
Donald L. Morrison and David E. Wigley
pp 2610 - 2616; DOI:
10.1021/ic00114a019
PDF
Synthesis, Characterization, and Photochemistry of Bis(arene) and Bis(acetonitrile) Complexes of Osmium(II)
Daniel A. Freedman, David J. Magneson, and Kent R. Mann
pp 2617 - 2624; DOI:
10.1021/ic00114a020
PDF
Synthesis and Properties of (Aminomethyl)nickel Complexes. [{Li(OEt2)}2Ni(CH2NC5H10)4]: The First Structurally Characterized Homoleptic Aminomethyl Complex of a Transition Metal
Dirk Steinborn, Frank Becke, and Roland Boese
pp 2625 - 2628; DOI:
10.1021/ic00114a021
PDF
Phosphatovanadium Chemistry: New Compounds, Including An Example of "Tenne's Prospect," and Oxidation of Cyclohexadiene
D. L. Thorn, R. L. Harlow, and N. Herron
pp 2629 - 2638; DOI:
10.1021/ic00114a022
PDF
EPR and Crystallographic Studies of Some Reaction Products of VCl4, NbCl4, and TaCl4 with Trialkyl- and Triarylphosphines
F. Albert Cotton and Jian Lu
pp 2639 - 2644; DOI:
10.1021/ic00114a023
PDF
Structures and Magnetic Properties of Iron(III) Dinuclear Complexes with Alkoxo and Carboxylato Bridges
Masako Kato, Yasuko Yamada, Tomoko Inagaki, Wasuke Mori, Ken Sakai, Taro Tsubomura, Mitsunobu Sato, and Shigenobu Yano
pp 2645 - 2651; DOI:
10.1021/ic00114a024
PDF
Exchange Interactions in the Bimetallic Chain Compound Cu(ethylenediamine)2MnCl4
B. Chiari, A. Cinti, O. Piovesana, and P. F. Zanazzi
pp 2652 - 2657; DOI:
10.1021/ic00114a025
PDF
Anion-Anion Interactions Involving the [Mo3Se13]2- Cluster. Syntheses and Characterization of (Me4N)2Mo3Se13, K2Mo3Se12.5O0.5, and K6Mo6Se27.cntdot.6H2O
Ju-Hsiou Liao, Jing Li, and Mercouri G. Kanatzidis
pp 2658 - 2670; DOI:
10.1021/ic00114a026
PDF
Interstitially-Stabilized Praseodymium(III) Compounds Na2Pr4Br9NO and Pr8Br13N3O: Structures on the Border Between Salts and Clusters
Michael Lulei, Sharon J. Steinwand, and John D. Corbett
pp 2671 - 2677; DOI:
10.1021/ic00114a027
PDF
High-Yield Synthesis of the W6S8 Cluster Unit as the Pyridine Complex (W6S8)(py)6 and Attempts To Prepare Tungsten Analogs of the Chevrel Phases
Xiang Zhang and Robert E. McCarley
pp 2678 - 2683; DOI:
10.1021/ic00114a028
PDF
Synthesis, Crystal Structure and Physical Properties of KNa2[NiO2] and K3[NiO2] Containing "Linear" [NiO2]3- Anions
Angela Moeller, Michael A. Hitchman, Elmars Krausz, and Rudolf Hoppe
pp 2684 - 2691; DOI:
10.1021/ic00114a029
PDF
Preparation and Structural and Magnetic Properties of AgF+MF6- (M = Ir, Ru, Sb, Bi) and Ag2+(BiF6-)2
G. Lucier, J. Muenzenberg, W. J. Casteel, and N. Bartlett
pp 2692 - 2698; DOI:
10.1021/ic00114a030
PDF
Exchange Alternation and Single-ion Anisotropy in The Antiferromagnetic Heisenberg Chain S = 1. Magnetic and Thermal Properties of the Compound Ni2(EDTA).cntdot.6H2O
J. J. Borras-Almenar, E. Coronado, J. Curely, and R. Georges
pp 2699 - 2704; DOI:
10.1021/ic00114a031
PDF
Building of 2D Sheet of Tetrakis(methylthio)tetrathiafulvalenes Coordinating to Copper(I) Halides with Zigzag and Helical Frames and the 3D Network through the S.cntdot. .cntdot. .cntdot.S Contacts
Megumu Munakata, Takayoshi Kuroda-Sowa, Masahiko Maekawa, Akihiro Hirota, and Susumu Kitagawa
pp 2705 - 2710; DOI:
10.1021/ic00114a032
PDF
Structure Maps for Intermetallic Phases Using Second Moment Scaling Theory
Laura M. Hoistad
pp 2711 - 2717; DOI:
10.1021/ic00114a033
PDF
Molecular Mechanics Model of Ligand Effects 7. Binding of .eta.2 Ligands to Cr(CO)5 and CpRh(CO): ER Values for Olefins
David P. White and Theodore L. Brown
pp 2718 - 2724; DOI:
10.1021/ic00114a034
PDF
Long Distance, Bridge-Mediated Electron Transfer in a Ligand-Bridged ReI-ReI Complex
Geoffrey F. Strouse, Jon R. Schoonover, Richard Duesing, and Thomas J. Meyer
pp 2725 - 2734; DOI:
10.1021/ic00114a035
PDF
Electronic Structure of f1 Actinide Complexes. 1. Nonrelativistic and Relativistic Calculations of the Optical Transition Energies of AnX6q- Complexes
Nikolas Kaltsoyannis and Bruce E. Bursten
pp 2735 - 2744; DOI:
10.1021/ic00114a036
PDF
Upconversion Luminescence in Er3+-Doped RbGd2Cl7 and RbGd2Br7
Toni Riedener, Karl Kraemer, and Hans U. Guedel
pp 2745 - 2752; DOI:
10.1021/ic00114a037
PDF
Calorimetric and Laser Induced Fluorescence Investigation of the Complexation Geometry of Selected Europium-gem-Diphosphonate Complexes in Acidic Solutions
K. L. Nash, L.-F. Rao, and G. R. Choppin
pp 2753 - 2758; DOI:
10.1021/ic00114a038
PDF
Complexes of the Ruthenium(II)-2,2':6',2''-terpyridine Family. Effect of Electron-Accepting and -Donating Substituents on the Photophysical and Electrochemical Properties
Mauro Maestri, Nicola Armaroli, Vincenzo Balzani, Edwin C. Constable, and Alexander M. W. Cargill Thompson
pp 2759 - 2767; DOI:
10.1021/ic00114a039
PDF
The Pentaamminemethylcobalt(III) Cation: Synthesis and Spectroscopic Characterization
Pauli Kofod
pp 2768 - 2770; DOI:
10.1021/ic00114a040
PDF
Effects of Coordination to a Macrocyclic Cobalt Complex on the Electrochemistry of Dioxygen, Superoxide, and Hydroperoxide
Chan Kang and Fred C. Anson
pp 2771 - 2780; DOI:
10.1021/ic00114a041
PDF
Electrochemistry of the Nickel(II) Tris(2-diphenylphosphinoethyl)phosphine Halide Cations and an X-ray Crystallographic Structure of [Ni(.eta.4-P3P')Br][PF6].cntdot.1/2MeCN.cntdot.H2O
Tania Whyte, Allan T. Casey, and Geoffrey A. Williams
pp 2781 - 2787; DOI:
10.1021/ic00114a042
PDF
Five-Coordinate Platinum Olefin Complexes: Synthesis, 1H NMR Investigations, and Crystal Structure of a Platinum .eta.2-Ethylene Crown Ether Complex
Andreas Gund, Bernhard K. Keppler, and Bernhard Nuber
pp 2788 - 2790; DOI:
10.1021/ic00114a043
PDF

Issue 11


Photochemistry of a Structurally Uncomplicated Phenylcarbyne Complex
Scott Trammell, B. Patrick Sullivan, L. Mark Hodges, W. Dean Harman, Sheila R. Smith, and H. Holden Thorp
pp 2791 - 2792; DOI:
10.1021/ic00115a001
PDF
Facile Interconversion of Polyphosphides and Formation of a New Polyphosphide Anion
Frederic Guerin and Darrin Richeson
pp 2793 - 2794; DOI:
10.1021/ic00115a002
PDF
Synthesis and Structure of [Co(tepa)O2COH](ClO4)2.cntdot.3H2O, a Chelated Bicarbonate Species Prepared in Aqueous Solution
Kay E. Baxter, Lyall R. Hanton, Jim Simpson, Beverly R. Vincent, and Allan G. Blackman
pp 2795 - 2796; DOI:
10.1021/ic00115a003
PDF
Effects of Main-Group and Transition Elements on Bond Formation and Cleavage in Transition-Metal Chalcogenide Clusters: Reactions of E2Fe3(CO)9 (E = Te, Se) with [Co(CO)4]-, [Mn(CO)5]-, and [Fe(CO)4]2-
Minghuey Shieh, Tse-Fang Tang, Shie-Ming Peng, and Gene-Hsiang Lee
pp 2797 - 2803; DOI:
10.1021/ic00115a004
PDF
Chemical, Computational, and Structural Studies of Dimeric (Pentamethylcyclopentadienyl)zirconium Thiolate and Alkoxide Complexes
Richard H. Heyn and Douglas W. Stephan
pp 2804 - 2812; DOI:
10.1021/ic00115a005
PDF
Polymer Pendant Ligand Chemistry. 3. A Biomimetic Approach to Selective Metal Ion Removal and Recovery from Aqueous Solution with Polymer-Supported Sulfonated Catechol and Linear Catechol Amide Ligands
Song-Ping Huang, Wei Li, Katherine J. Franz, Robert L. Albright, and Richard H. Fish
pp 2813 - 2819; DOI:
10.1021/ic00115a006
PDF
Synthetic and Structural Studies of a Linear Bis-Catechol Amide, N,N'-Bis(2,3-dihydroxybenzoyl)-1,7-diazaheptane (5-LICAM), and Its Complexes with Ni2+ and Co2+: Utilization of a Polymer-Supported, Sulfonated Analog, 5-LICAMS, as a Biomimetic Ligand for Divalent Metal Ion Removal from Aqueous Solution
Song-Ping Huang, Katherine J. Franz, Marilyn M. Olmstead, and Richard H. Fish
pp 2820 - 2825; DOI:
10.1021/ic00115a007
PDF
Outer-Sphere Macrochelation in [Pd(en)(5'-GMP-N7)2].cntdot.9H2O and [Pt(en)(5'-GMP-N7)2].cntdot.9H2O: X-ray Crystallography and NMR Spectroscopy in Solution
Kevin J. Barnham, Christopher J. Bauer, Milos I. Djuran, Muhammed A. Mazid, Tobias Rau, and Peter J. Sadler
pp 2826 - 2832; DOI:
10.1021/ic00115a008
PDF
Synthesis and Characterization of Some Copper(I) Phenanthroline Complexes
Alexander J. Pallenberg, Kristina S. Koenig, and David M. Barnhart
pp 2833 - 2840; DOI:
10.1021/ic00115a009
PDF
2,4-Ethanotetraborane Derivatives. 2. Synthesis, Characterization, and Gas-Phase Structures of 2,4-(MeCHCH2)B4H8, 2,4-(trans-MeCHCHMe)B4H8, and 2- and 4-Pr-2,4-(MeCHCH2)B4H7
Paul T. Brain, Michael Buehl, Mark A. Fox, Robert Greatrex, Ellen Leuschner, Matthew J. Picton, David W. H. Rankin, and Heather E. Robertson
pp 2841 - 2849; DOI:
10.1021/ic00115a010
PDF
Chain and Large-Ring Polymeric Transition Metal and Lanthanide Complexes Formed by N,N'-Ethylenebis(pyrrolidin-2-one)
Garry A. Doyle, David M. L. Goodgame, Stuart P. W. Hill, Stephan Menzer, Alistair Sinden, and David J. Williams
pp 2850 - 2860; DOI:
10.1021/ic00115a011
PDF
Macrocyclic Mononuclear VIV and VV, Heterodinuclear VIVNiII, and Heterotrinuclear VIVNiIIVV Complexes: Synthesis, Structure, Electrochemistry, and Magnetochemistry
Kausik K. Nanda, Sasankasekhar Mohanta, Soma Ghosh, Monika Mukherjee, Madeleine Helliwell, and Kamalaksha Nag
pp 2861 - 2869; DOI:
10.1021/ic00115a012
PDF
Crystal Structure of (Et2Me2N)3Cu4Cl11: An Antiferromagnetic Chain of Ferromagnetically Coupled Tetramers
Y. Fujii, Z. Wang, R. D. Willett, W. Zhang, and C. P. Landee
pp 2870 - 2874; DOI:
10.1021/ic00115a013
PDF
Structure and Luminescence Properties of [Re(4,7-dimethyl-1,10-phenanthroline)(CO)3py]+ in a Solid Matrix
Lynne Wallace, Clifton Woods, and D. Paul Rillema
pp 2875 - 2882; DOI:
10.1021/ic00115a014
PDF
Binuclear Copper(II) Complexes of Bis(1,4,7-triazacyclononane) Ligands Containing Tri- and Tetramethylene Bridging Groups. An Equilibrium and Structural Study
Xiaoping Zhang, Wen-Yuan Hsieh, T. N. Margulis, and Leverett J. Zompa
pp 2883 - 2888; DOI:
10.1021/ic00115a015
PDF
Synthesis, Crystal Structure, and Properties of a New Imidazolate-Bridged Copper-Zinc Heterobinuclear Complex with Triethylenetetramine Ligands
Zong-Wan Mao, Ming-Qin Chen, Xiang-Shi Tan, Jie Liu, and Wen-Xia Tang
pp 2889 - 2893; DOI:
10.1021/ic00115a016
PDF
Low Temperature Multinuclear NMR Study of the Mechanism of Protonation of W(H)2Cl2(PMe2Ph)4
Helmut Rothfuss, Dmitry G. Gusev, and Kenneth G. Caulton
pp 2894 - 2901; DOI:
10.1021/ic00115a017
PDF
Addition of Metallic Mercury to Platinum- and Palladium-Gold Cluster Compounds. X-ray Crystal and Molecular Structures of [(Hg)2Pd(AuPPh3)8](NO3)2 and [(Hg)Pt(AuPPh3)8](NO3)2
Rachael A. T. Gould, Kathryn L. Craighead, Jack S. Wiley, and Louis H. Pignolet
pp 2902 - 2913; DOI:
10.1021/ic00115a018
PDF
Multiple Bonds between Transition Metals and Main-Group Elements. 142. Lewis-Base Adducts of Organorhenium(VII) Oxides: Structures and Dynamic Behavior in Solution
Wolfgang A. Herrmann, Fritz E. Kuehn, Monika U. Rauch, Joao D. G. Correia, and Georg Artus
pp 2914 - 2920; DOI:
10.1021/ic00115a019
PDF
Oxazoline Early Transition Metal Complexes: Functionalizable Achiral Titanium(IV), Titanium(III), Zirconium(IV), Vanadium(III), and Chiral Zirconium(IV) Bis(oxazoline) Complexes
Pier Giorgio Cozzi, Carlo Floriani, Angiola Chiesi-Villa, and Corrado Rizzoli
pp 2921 - 2930; DOI:
10.1021/ic00115a020
PDF
Reactions of [Ru(bpy)(CO)2Cl2] in Acidic Media: Formation and Structural Characterization of [Ru(bpy)Cl3(NO)], [Ru2N(bpy)2Cl5(H2O)], and (H5O2)[Ru2N(bpy)2Cl6]
Matti Haukka, Tapani Venalainen, Markku Ahlgren, and Tapani A. Pakkanen
pp 2931 - 2936; DOI:
10.1021/ic00115a021
PDF
Seven-Coordinate Iridium(V) Polyhydrides with Chelating Bis(silyl) Ligands
Maria Loza, J. W. Faller, and Robert H. Crabtree
pp 2937 - 2941; DOI:
10.1021/ic00115a022
PDF
Luminescence from the 2T2g(H) state of cobalt(II)-doped KCdBr3
Robbie G. McDonald, Aamer A. Al-Waili, and W. Ewen Smith
pp 2942 - 2951; DOI:
10.1021/ic00115a023
PDF
Infrared Spectra of Beryllium Carbonyls from Reactions of Beryllium Atoms with Carbon Monoxide in Solid Argon
Lester Andrews, Thomas J. Tague, Gary P. Kushto, and Randall D. Davy
pp 2952 - 2961; DOI:
10.1021/ic00115a024
PDF
Ternary Metal-Rich Phosphides: Structure, Bonding, and Site Preferences in ZrNbP and Hf1+xMo1-xP
Gordon J. Miller and Jun Cheng
pp 2962 - 2968; DOI:
10.1021/ic00115a025
PDF
Calculated Structures and Electronic Absorption Spectroscopy for Magnesium Phthalocyanine and Its Anion Radical
Marshall G. Cory, Hiroaki Hirose, and Michael C. Zerner
pp 2969 - 2979; DOI:
10.1021/ic00115a026
PDF
Structure of Magnesium Cluster Grignard Reagents
Alexandr V. Nemukhin, Igor A. Topol, and Frank Weinhold
pp 2980 - 2983; DOI:
10.1021/ic00115a027
PDF
Electrochemistry and Spectroelectrochemistry of .sigma.-Bonded Iron(III) Porphyrins with Nonplanar Porphyrin Rings. Reactions of (OETPP)Fe(R) and (OETPP)FeCl, Where R = C6H5, C6F4H, or C6F5 and OETPP Is the Dianion of 2,3,7,8,12,13,17,18-Octaethyl-5,10,15,20- tetraphenylporphyrin
Karl M. Kadish, Eric Van Caemelbecke, Francis D'Souza, Craig J. Medforth, Kevin M. Smith, Alain Tabard, and Roger Guilard
pp 2984 - 2989; DOI:
10.1021/ic00115a028
PDF
Molecular Orbital Calculations and Raman Measurements for 1-Ethyl-3-methylimidazolium Chloroaluminates
S. Takahashi, L. A. Curtiss, D. Gosztola, N. Koura, and Marie-Louise Saboungi
pp 2990 - 2993; DOI:
10.1021/ic00115a029
PDF
Synthesis, Characterization, and Interaction with DNA of the Novel Metallointercalator Cationic Complex (2,2':6',2''-terpyridine)methylplatinum(II)
G. Arena, L. Monsu Scolaro, R. F. Pasternack, and R. Romeo
pp 2994 - 3002; DOI:
10.1021/ic00115a030
PDF
4,7,10,23-Tetramethyl-17-oxa-1,4,7,10,13,23-hexaazabicyclo[11.7.5]pentacosane (L), a Two-Binding-Site Ligand for the Assembly of the [Zn2(.mu.-OH)2]2+ Cluster
Carla Bazzicalupi, Andrea Bencini, Antonio Bianchi, Vieri Fusi, Laura Mazzanti, Piero Paoletti, and Barbara Valtancoli
pp 3003 - 3010; DOI:
10.1021/ic00115a031
PDF
Ferromagnetic versus Antiferromagnetic Exchange in Five Structurally Analogous Carboxylate-Bridged Trinuclear Ferrous Complexes
David P. Goldberg, Joshua Telser, Cecilia M. Bastos, and Stephen J. Lippard
pp 3011 - 3024; DOI:
10.1021/ic00115a032
PDF
Fingerprinting Petroporphyrin Structures with Vibrational Spectroscopy. 3. Resonance Raman Characterization of Regioisomers of Nickel(II) Tetrahydrobenzoporphyrin
J. Graham Rankin, Roman S. Czernuszewicz, and Timothy D. Lash
pp 3025 - 3037; DOI:
10.1021/ic00115a033
PDF
Side Chain Entropy and the Activation of Organocobalamins for Carbon-Cobalt Bond Homolysis: Thermolysis of Neopentylcobalamin-c-monocarboxylate, -c-N-methylamide, -c-N,N-dimethylamide, and -c-N-isopropylamide
Kenneth L. Brown, Shifa Cheng, and Helder M. Marques
pp 3038 - 3049; DOI:
10.1021/ic00115a034
PDF
Mononuclear Copper(II)-Acylperoxo Complexes
Indrajit Sanyal, Phalguni Ghosh, and Kenneth D. Karlin
pp 3050 - 3056; DOI:
10.1021/ic00115a035
PDF
Gallium and Indium Complexes of Hexadentate Ligands Containing Pendant Pyridyl and Phenolate Groups
Ernest Wong, Shuang Liu, Steve Rettig, and Chris Orvig
pp 3057 - 3064; DOI:
10.1021/ic00115a036
PDF
Iodide Complexes of Decaborane(14) and 2,4-Diiododecaborane(14). The X-ray Crystal Structure of [P(C6H5)3CH3][2,4-I2B10H12I]
Joseph R. Wermer, Orin Hollander, John C. Huffman, Jeanette A. Krause Bauer, Danan Dou, Leh-Yeh Hsu, Daniel L. Leussing, and Sheldon G. Shore
pp 3065 - 3071; DOI:
10.1021/ic00115a037
PDF
Donor Solvent Mediated Reactions of Elemental Zinc and Sulfur, sans Explosion
Atul K. Verma, Thomas B. Rauchfuss, and Scott R. Wilson
pp 3072 - 3078; DOI:
10.1021/ic00115a038
PDF
Utility of Mixed-Ligand Alkylaluminum Reagents in the Formation of Mixed-Metal Yttrium and Lanthanide Aluminum Compounds
William J. Evans, Mohammad A. Ansari, and Joseph W. Ziller
pp 3079 - 3082; DOI:
10.1021/ic00115a039
PDF
Calorimetric Studies of Metal Binding to Tetracycline. Role of Solvent Structure in Defining the Selectivity of Metal Ion-Drug Interactions
T. Ohyama and J. A. Cowan
pp 3083 - 3086; DOI:
10.1021/ic00115a040
PDF
Ammonia and Carbon Dioxide from Urea. Multinuclear NMR Study of the Activation of Urea by Platinum(II)
Andrew A. Watson and David P. Fairlie
pp 3087 - 3092; DOI:
10.1021/ic00115a041
PDF
EPR Evidence for Low-Lying MLCT States in Tetracyanoiron and -ruthenium Complexes with Strongly .pi.-Accepting Chelate Ligands. Comparison with Isoelectronic Tetracarbonylmetal Species
Eberhard Waldhoer, Juergen Poppe, Wolfgang Kaim, Edgardo H. Cutin, Monica E. Garcia Posse, and Nestor E. Katz
pp 3093 - 3096; DOI:
10.1021/ic00115a042
PDF
Preparation and Magnetic Properties of Al(PF3)2
J. A. Howard, R. Jones, M. Tomietto, and H. A. Joly
pp 3097 - 3098; DOI:
10.1021/ic00115a043
PDF
A Diiron(III) Complex Containing N-N Bridges. Synthesis, Structure, and Properties
Jagadam Saroja, Vadivelu Manivannan, Partha Chakraborty, and Samudranil Pal
pp 3099 - 3101; DOI:
10.1021/ic00115a044
PDF
Assembling Processes in a System Comprising Four Constituents: Two Metal Ions (Na, Ni) and Two Anionic Ligands (Perchlorate and 3-(2-Methoxyethoxy)salicylaldiminato(1-))
Jean-Pierre Costes, Francoise Dahan, and Jean-Pierre Laurent
pp 3102 - 3104; DOI:
10.1021/ic00115a045
PDF
From Methyl to Acetyl Complexes. An Example of Alkyl Migration in Heterotrinuclear Systems. Crystal and Molecular Structure of [{Rh(.mu.-pz)(.mu.-StBu)I(COMe)P(OMe)3}2Pd]
M. Teresa Pinillos, Anabel Elduque, Eduardo Martin, Nuria Navarro, Luis A. Oro, Antonio Tiripicchio, and Franco Ugozzoli
pp 3105 - 3109; DOI:
10.1021/ic00115a046
PDF
13C and 1H NMR Line Broadening in Desferrioxamine B Spectra. Kinetics and Mechanism of Siderophore Chemistry
Mladen Birus, Mario Gabricevic, Olga Kronja, and Branimir Klaic
pp 3110 - 3113; DOI:
10.1021/ic00115a047
PDF
Synthesis and Properties of New Perfluorinated Aliphatic Isocyanides
Burkhard Krumm, Robert L. Kirchmeier, and Jean'ne M. Shreeve
pp 3114 - 3116; DOI:
10.1021/ic00115a048
PDF
[Cp''Co(P4){(Cp''Co)2(.mu.-CO)}] (Cp'' = .eta.5-C5H3tBu2): A Complex with a P4 Unit on the Way to a P1 and a P3 Ligand
Manfred Scheer, Uta Becker, Malcolm H. Chisholm, John C. Huffman, Frederic Lemoigno, and Odile Eisenstein
pp 3117 - 3119; DOI:
10.1021/ic00115a049
PDF
Further Gold Aggregation at a Pentanuclear Gold Cluster with Hypercoordinate Interstitial Nitrogen
Klaus Angermaier and Hubert Schmidbaur
pp 3120 - 3122; DOI:
10.1021/ic00115a050
PDF
A Novel Honeycomb-like Copper(II) Phosphate Framework, [BaCl][CuPO4]
Kristen M. S. Etheredge and Shiou-Jyh Hwu
pp 3123 - 3125; DOI:
10.1021/ic00115a051
PDF
Ge93- and Pb93-: Two Novel, Naked, Homopolyatomic Zintl Ions with Paramagnetic Properties. [Erratum to document cited in CA121:270419]
Thomas F. Faessler and Markus Hunziker
pp 3126 - 3126; DOI:
10.1021/ic00115a052
PDF
Early Metal Mediated P-P Bond Formation in Cp2M((PR)2) and Cp2M((PR)3) Complexes. [Erratum to document cited in CA120:245375]
Jianwei Ho, Tricia L. Breen, Andrzej Ozarowski, and Douglas W. Stephan
pp 3126 - 3126; DOI:
10.1021/ic00115a053
PDF

Issue 12


Cage Fragmentation of P4S10 by t-Bu3Ga. Formation and Interconversions of a Novel Phosphorus-Sulfur-Gallium Ring System
Alan H. Cowley, Dieter Hellert, Francois P. Gabbai, and Falk Olbrich
pp 3127 - 3129; DOI:
10.1021/ic00116a001
PDF
Thermal Phase Transition of Cesium Formate
Yoshio Masuda, Akihiko Yahata, and Hiroshi Ogawa
pp 3130 - 3133; DOI:
10.1021/ic00116a002
PDF
Structures and Magnetic Susceptibility Studies of Four New High-Nuclearity Copper(II) Halide Oligomers
M. R. Bond, H. Place, Z. Wang, R. D. Willett, Ying Liu, Todd E. Grigereit, John E. Drumheller, and George F. Tuthill
pp 3134 - 3141; DOI:
10.1021/ic00116a003
PDF
Polarized X-ray Absorption Spectroscopy of Cupric Chloride Dihydrate
Ingrid J. Pickering and Graham N. George
pp 3142 - 3152; DOI:
10.1021/ic00116a004
PDF
Antimony(III) Fluoride Fluorosulfates: Syntheses and Molecular Structures of Antimony(III) Difluoride Fluorosulfate [SbF2(SO3F)]x, Antimony(III) Fluoride Bis(fluorosulfate) [SbF(SO3F)2]x, and Antimony(III) Tris(fluorosulfate) [Sb(SO3F)3]x
Dingliang Zhang, Steven J. Rettig, James Trotter, and F. Aubke
pp 3153 - 3164; DOI:
10.1021/ic00116a005
PDF
Uranium Tellurides: New One- and Two-Dimensional Compounds CsUTe6, CsTiUTe5, Cs8Hf5UTe30.6, and CsCuUTe3
Jason A. Cody and James A. Ibers
pp 3165 - 3172; DOI:
10.1021/ic00116a006
PDF
Spectroscopy and Photochemistry of Nickel(II), Palladium(II), and Platinum(II) .beta.-Diketonates
Frederick D. Lewis, Alan M. Miller, and Gwen D. Salvi
pp 3173 - 3181; DOI:
10.1021/ic00116a007
PDF
Platinum(II) Bis(.beta.-diketonates) as Photoactivated Hydrosilation Catalysts
Frederick D. Lewis and Gwen D. Salvi
pp 3182 - 3189; DOI:
10.1021/ic00116a008
PDF
Preparation and Properties of Ru2(DtolF)4Cl: A Surprising Electronic Structure Change Compared to Ru2(DtolF)4 (DtolF = [(p-tol)NCHN(p-tol)]-)
F. Albert Cotton and Tong Ren
pp 3190 - 3193; DOI:
10.1021/ic00116a009
PDF
Halide and Tertiary Phosphine Derivatives of the Tungsten (IV) .eta.2-Acetyl Complex CpW(NCMe)3(.eta.2-COMe)2+. Reversible Ag+-Assisted Opening of an .eta.2-Acetyl Group?
Vidar Skagestad, Christian Romming, and Mats Tilset
pp 3194 - 3202; DOI:
10.1021/ic00116a010
PDF
Isolation and Structural Characterization of cis- and trans-Forms of [(.eta.5-C5Me5)TiCl2]2[.mu.-.eta.5:.eta.5-(C5H3)2(SiMe2)2]
Joyce Y. Corey, Jean L. Huhmann, and Nigam P. Rath
pp 3203 - 3209; DOI:
10.1021/ic00116a011
PDF
Detailed Structural Characterization of the Polyvalent Iminoiodinanes ArINTs (Ar = C6H5 or 2,4,6-Me3C6H2; Ts = SO2C6H4-4-Me) and the Aryldichloroiodinane 2,4,6-i-Pr3C6H2ICl2
Anil K. Mishra, Marilyn M. Olmstead, Jeffrey J. Ellison, and Philip P. Power
pp 3210 - 3214; DOI:
10.1021/ic00116a012
PDF
Trivalent Lanthanide Chalcogenolates: Synthesis, Structure, and Thermolysis Chemistry
Jongseong Lee, Meggan Brewer, M. Berardini, and J. G. Brennan
pp 3215 - 3219; DOI:
10.1021/ic00116a013
PDF
Low-Temperature FTIR Study of the Photochemistry of CpMo(CO)3-Co(CO)4 and Related Heterodinuclear Complexes
Xiaoqing Song and Theodore L. Brown
pp 3220 - 3231; DOI:
10.1021/ic00116a014
PDF
MLCT Excited-State Properties of the Ru(L)2(CN)2 (L = 2-(N-Methylformimidoyl)pyridine) Complex. A Theoretical Approach by Means of DV-X.alpha. Molecular Orbital Calculations
Mutsuhiro Maruyama, Hideyo Matsuzawa, and Youkoh Kaizu
pp 3232 - 3240; DOI:
10.1021/ic00116a015
PDF
Directional Effects of CO .pi. Bonding in Group VIB Pentacarbonyl Amines
K. S. Wang, D. Wang, K. Yang, M. G. Richmond, and M. Schwartz
pp 3241 - 3244; DOI:
10.1021/ic00116a016
PDF
Relativistic Effects on Metal-Ligand Bond Strengths in .pi.-Complexes: Quasi-Relativistic Density Functional Study of M(PH3)2X2 (M = Ni, Pd, Pt; X2 = O2, C2H2, C2H4) and M(CO)4(C2H4) (M = Fe, Ru, Os)
Jian Li, Georg Schreckenbach, and Tom Ziegler
pp 3245 - 3252; DOI:
10.1021/ic00116a017
PDF
A New Analysis of the Ligand Field Stabilization Energy
David A. Johnson and Peter G. Nelson
pp 3253 - 3259; DOI:
10.1021/ic00116a018
PDF
Host.cntdot..cntdot..cntdot.Guest Interactions in the Pyrrole and Aniline Hofmann Clathrates. A Theoretical Study
Eliseo Ruiz and Santiago Alvarez
pp 3260 - 3269; DOI:
10.1021/ic00116a019
PDF
Model Studies of .alpha.-Keto Acid-Dependent Nonheme Iron Enzymes: Nitric Oxide Adducts of [FeII(L)(O2CCOPh)](ClO4) Complexes
Yu-Min Chiou and Lawrence Que
pp 3270 - 3278; DOI:
10.1021/ic00116a020
PDF
A Tripod Ligand with Three Different "Legs" and Some Chiral Zinc Complexes Thereof
Ahmed Abufarag and Heinrich Vahrenkamp
pp 3279 - 3284; DOI:
10.1021/ic00116a021
PDF
A New Tridentate N,N,S Ligand and Its Zinc Complexes
Udo Brand and Heinrich Vahrenkamp
pp 3285 - 3293; DOI:
10.1021/ic00116a022
PDF
Laser-Induced Luminescence Studies and Crystal Structure of the Europium(III) Complex of 1,4,7,10-Tetrakis(carbamoylmethyl)-1,4,7,10-tetraazacyclododecane. The Link between Phosphate Diester Binding and Catalysis by Lanthanide(III) Macrocyclic Complexes
Shahid Amin, David A. Voss, William DeW. Horrocks, Charles H. Lake, Melvyn Rowen Churchill, and Janet R. Morrow
pp 3294 - 3300; DOI:
10.1021/ic00116a023
PDF
Substituted tetraammineruthenium cytochrome c derivatives: Chemistry and electron-transfer reactions
Ji Sun, James F. Wishart, Mary B. Gardineer, Myung-ok P. Cho, and Stephan S. Isied
pp 3301 - 3309; DOI:
10.1021/ic00116a024
PDF
Amide Formation from Aldimine and Water Promoted by Coordinated Metal Redox. Chemistry of a Family of Isomeric RuII(diimine)2Cl2, RuIII(diimine)2Cl2+, and RuIII(diimine)(amide-imine)Cl2 Complexes
Mahua Menon, Amitava Pramanik, and Animesh Chakravorty
pp 3310 - 3316; DOI:
10.1021/ic00116a025
PDF
Use of Ligand Design to Provide Coordination Asymmetry in a Binuclear Metalloprotein Model System: Ligand Synthesis, Coordination Chemistry with Copper, and Demonstration of Site-Directed Reactivity
Joe H. Satcher, Michael W. Droege, Timothy J. R. Weakley, and Robert T. Taylor
pp 3317 - 3328; DOI:
10.1021/ic00116a026
PDF
Mixed-Ligand Chelate Complexes of Thallium(III), Characterized by Equilibrium Measurements, NMR and Raman Spectroscopy, and X-ray Crystallography
Stefano Musso, Giorgio Anderegg, Heinz Ruegger, Carl Wilhelm Schlaepfer, and Volker Gramlich
pp 3329 - 3338; DOI:
10.1021/ic00116a027
PDF
Electrocatalysis of CO2 Reduction in Aqueous Media at Electrodes Modified with Electropolymerized Films of Vinylterpyridine Complexes of Transition Metals
J. A. Ramos Sende, C. R. Arana, L. Hernandez, K. T. Potts, M. Keshevarz-K, and H. D. Abruna
pp 3339 - 3348; DOI:
10.1021/ic00116a028
PDF
Stereochemistry at the Chiral Ruthenium Atom in Half-Sandwich Compounds of the Type [(.eta.6-Ar)Ru(LL*)L']X and [(.eta.6-Ar)Ru(LL*)-Hal]. X-ray Structure Analysis of [(.eta.6-cymene)Ru(LL*)(4-Mepy)]PF6 and Appeal to the Proper Use of Stereochemical Terminology
Henri Brunner, Ralf Oeschey, and Bernd Nuber
pp 3349 - 3351; DOI:
10.1021/ic00116a029
PDF
Crystal and Molecular Structure of Tetramethyldithioimidodiphosphinic acid, (SPMe2)2NH, and Its Cobalt(II) Complex, Co[(SPMe2)2N]2, Containing a Tetrahedral CoS4 Core
Cristian Silvestru, Roland Roesler, Ionel Haiduc, Raymundo Cea-Olivares, and Georgina Espinosa-Perez
pp 3352 - 3354; DOI:
10.1021/ic00116a030
PDF
Evidence of the Importance of Back-Bonding in Determining the Behavior of Ruthenated Cyanophenyl Cobalt Porphyrins as Electrocatalysts for the Reduction of Dioxygen
Beat Steiger and Fred C. Anson
pp 3355 - 3357; DOI:
10.1021/ic00116a031
PDF
Synthesis and UV-Vis, Electrochemical, Spectroelectrochemical and Intervalence Characterization of Bis-bipyridyl Osmium(II) Complexes Bound to Dipyrido[2,3-a;2',3'-h]phenazine (dpop)
Ronald R. Ruminski, Donna Serveiss, and Martin Jaquez
pp 3358 - 3362; DOI:
10.1021/ic00116a032
PDF
A Novel Microporous Mixed-Transition-Metal Phosphate: Hydrothermal Synthesis, Characterization, and Structure of Zn2Co4(PO4)4(H2O)5.cntdot.2H2O
Dongmok Whang, Nam Hwi Hur, and Kimoon Kim
pp 3363 - 3366; DOI:
10.1021/ic00116a033
PDF
Metal-Pteridine Complexes Having Three-Dimensional Hydrogen-Bonded Networks
Minoru Mitsumi, Jiro Toyoda, and Kazuhiro Nakasuji
pp 3367 - 3370; DOI:
10.1021/ic00116a034
PDF

Issue 13


Magnetic Coupling and 1H NMR Spectroscopy of Binuclear Copper(II) Complexes
Joseph H. Satcher and Alan L. Balch
pp 3371 - 3373; DOI:
10.1021/ic00117a001
PDF
Synthesis and Characterization of TpMoOX2 (X = F, Cl, Br; Tp = Hydrotris(3,5-dimethylpyrazol-1-yl)borate)
Norriel S. Nipales and T. David Westmoreland
pp 3374 - 3377; DOI:
10.1021/ic00117a002
PDF
Quantitative and Qualitative Photoelectrochemical Studies on the 18-Molybdodisulfate Anion [S2Mo18O62]4-
A. M. Bond, D. M. Way, A. G. Wedd, R. G. Compton, J. Booth, and J. C. Eklund
pp 3378 - 3384; DOI:
10.1021/ic00117a003
PDF
Synthesis and Photophysical Properties of Mono(2,2',2''-terpyridine) Complexes of Ruthenium(II)
Benjamin J. Coe, David W. Thompson, Christopher T. Culbertson, Jon R. Schoonover, and Thomas J. Meyer
pp 3385 - 3395; DOI:
10.1021/ic00117a004
PDF
Acid-Base Behavior of the Ground and Excited States of Platinum(II) Complexes of Quinoxaline-2,3-dithiolate
Scott D. Cummings and Richard Eisenberg
pp 3396 - 3403; DOI:
10.1021/ic00117a005
PDF
Synthesis, Structure, and Molecular Orbital Calculation of the Bicapped Triangular Molybdenum Cluster Complex [Mo3S5(PMe3)6]
Kiyoshi Tsuge, Hideo Imoto, and Taro Saito
pp 3404 - 3409; DOI:
10.1021/ic00117a006
PDF
Theoretical Study of Dinitrogen Activation in Dinuclear V(II) and V(III) Hexacoordinated Complexes: Ab Initio Calculations on Various Model Compounds
Nazzareno Re, Marzio Rosi, Antonio Sgamellotti, and Carlo Floriani
pp 3410 - 3417; DOI:
10.1021/ic00117a007
PDF
Theoretical Aspects of the Heterobimetallic Dimers with the T Over Square Structural Motif. Synthesis and Structure of a Heteronuclear Platinum and Palladium Complex with 1-Methylcytosinato Bridging Ligands
Carlo Mealli, Fabio Pichierri, Lucio Randaccio, Ennio Zangrando, Michael Krumm, Dagmar Holtenrich, and Bernhard Lippert
pp 3418 - 3424; DOI:
10.1021/ic00117a008
PDF
Density Functional Study of Ground and Excited States of Mn2(CO)10
Angela Rosa, Giampaolo Ricciardi, Evert Jan Baerends, and Derk J. Stufkens
pp 3425 - 3432; DOI:
10.1021/ic00117a009
PDF
Formation of 1:1, 2:1, and 2:2 Complexes between Carbonyl Compounds and Titanium Tetrachloride. An ab Initio Study
Vicenc Branchadell and Antonio Oliva
pp 3433 - 3439; DOI:
10.1021/ic00117a010
PDF
Dinuclear Titanium(III) Complexes. Exchange Coupling in (Cp2Ti)2(.mu.-O)
Wayne W. Lukens and Richard A. Andersen
pp 3440 - 3443; DOI:
10.1021/ic00117a011
PDF
Autoxidation of an Electron-Rich Organometallic. Mechanism of the Reaction of a Substituted Niobocene Compound with Dioxygen
B. Thiyagarajan, Margaret E. Kerr, and Joseph W. Bruno
pp 3444 - 3452; DOI:
10.1021/ic00117a012
PDF
Weakly Coordinating Anions M(OTeF5)6- (M = Nb, Sb) and M(OTeF5)62- (M = Ti, Zr, Hf): Two-Step Synthesis, Characterization, Stability, and Use in the Isolation of the Dihaloalkane Complex Cations Ag(CH2Cl2)3+, Ag(CH2Br2)3+, and catena-poly[Ag(1,2-C2H4Br2)2-.mu.-(1,2-C2H4Br2)-Br:Br']+
Dawn M. Van Seggen, Paul K. Hurlburt, Oren P. Anderson, and Steven H. Strauss
pp 3453 - 3464; DOI:
10.1021/ic00117a013
PDF
New Iron(II)- and Gold(I)-Containing Metallocenes. X-ray Structure of a Three-Coordinate Gold(I) Ferrocenophane-Type Representative
Manuella Viotte, Bernard Gautheron, Marek M. Kubicki, Yves Mugnier, and Richard V. Parish
pp 3465 - 3473; DOI:
10.1021/ic00117a014
PDF
A Three-Center Hydrogen Bond in 2,6-Diphenylpyridinium Tetrachloroaurate
Glenn P. A. Yap, Arnold L. Rheingold, Pampa Das, and Robert H. Crabtree
pp 3474 - 3476; DOI:
10.1021/ic00117a015
PDF
Synthesis and Characterization of (Octaethylporphyrinato)ruthenium(II) and -ruthenium(III) Complexes with Thioether, Sulfoxide, and Benzoate Axial Ligands
Andrew Pacheco, Brian R. James, and Steven J. Rettig
pp 3477 - 3484; DOI:
10.1021/ic00117a016
PDF
Synthesis, Characterization, and Reactivity of Sulfido- and Selenidomolybdenum(IV) Porphyrin Complexes. X-ray Structure of Sulfido(5,10,15,20-tetratolylporphyrinato)molybdenum(IV)
Lisa M. Berreau, Victor G. Young, and L. Keith Woo
pp 3485 - 3490; DOI:
10.1021/ic00117a017
PDF
Iodination Reactions of Icosahedral para-Carborane and the Synthesis of Carborane Derivatives with Boron-Carbon Bonds
Wei Jiang, Carolyn B. Knobler, Carol E. Curtis, Mark D. Mortimer, and M. Frederick Hawthorne
pp 3491 - 3498; DOI:
10.1021/ic00117a018
PDF
Synthesis and Characterization of the First Three-Coordinate Donor-Free Magnesium Thiolates, [Mg(STriph)2]2 (Triph = 2,4,6-Ph3C6H2) and [Mg(SMes*)2]2 (Mes* = 2,4,6-t-Bu3C6H2), and the Four-Coordinate Magnesium Thiolate Mg(SMes*)2(OEt2)2 and Selenolate Mg(SeMes*)2(THF)2
Karin Ruhlandt-Senge
pp 3499 - 3504; DOI:
10.1021/ic00117a019
PDF
Synthesis, Crystal Structure and Magnetic Properties of Indium(III) Diphthalocyanine
Jan Janczak, Ryszard Kubiak, and Adam Jezierski
pp 3505 - 3508; DOI:
10.1021/ic00117a020
PDF
Hydrothermal Syntheses and Structural Characterization of Layered Oxovanadium Phosphate Solids Incorporating Organic Cations: [H2N(C4H8)NH2][(VO)4(OH)4(PO4)2], [(NH3C3H6)NH(C2H4)2NH(C3H6NH3)][(VO)5(OH)2(PO4)4].cntdot.2H2O, [HN(C2H4)3NH]2[(VO)8(HPO4)3(PO4)4(OH)2].cntdot.2H2O, and [HN(C2H4)3NH][(VO)3(OH)2(PO4)2]
Victoria Soghomonian, Qin Chen, Robert C. Haushalter, Charles J. O'Connor, Cuihong Tao, and Jon Zubieta
pp 3509 - 3519; DOI:
10.1021/ic00117a021
PDF
X-ray and Multinuclear Magnetic Resonance Study of the Complexes of Lanthanum(III) with 2,2':6',2''-Terpyridine
Monique Frechette and Corinne Bensimon
pp 3520 - 3527; DOI:
10.1021/ic00117a022
PDF
Transition Metal Complexes of 12- and 13-Membered Functionalized Macrocycles, Dioxotetraazacycloalkanediacetates
Michiko B. Inoue, Paul Oram, Gabriel Andreu-de-Riquer, Motomichi Inoue, Peter Borbat, Arnold Raitsimring, and Quintus Fernando
pp 3528 - 3535; DOI:
10.1021/ic00117a023
PDF
Non-Metal Redox Kinetics: Oxidation of Bromide Ion by Nitrogen Trichloride
Michael Gazda, Krishan Kumar, and Dale W. Margerum
pp 3536 - 3542; DOI:
10.1021/ic00117a024
PDF
Applications of Dual Parameter E- and C-Based Substituent Constants to Inorganic Systems
Russell S. Drago
pp 3543 - 3548; DOI:
10.1021/ic00117a025
PDF
An Organometal Hydroxide Route to {[(C8H12)Rh]2[Ti(OPrn)6]}
Victor W. Day, Todd A. Eberspacher, Jinling Hao, Walter G. Klemperer, and Bianxiao Zhong
pp 3549 - 3552; DOI:
10.1021/ic00117a026
PDF
Synthesis of (Hexafluoro-tert-butyl)amine and Molybdenum(VI) (Hexafluoro-tert-butyl)imido Complexes
Michael Buchmeiser and Richard R. Schrock
pp 3553 - 3554; DOI:
10.1021/ic00117a027
PDF
Behavior of [Ir6(CO)16] in Solution: Isomerization and Cluster Breakdown to [Ir4(CO)12]
Dominique Roberto, Luigi Garlaschelli, and Maddalena Pizzotti
pp 3555 - 3556; DOI:
10.1021/ic00117a028
PDF
1H MAS NMR Spectra of Transition Metal Carbonyl Hydrides
Silvio Aime, Patrick J. Barrie, Dermot F. Brougham, Roberto Gobetto, and Geoffrey E. Hawkes
pp 3557 - 3559; DOI:
10.1021/ic00117a029
PDF
Self-Assembly of a Complex Fluorinated Metallacycle from Hexafluoroacetone and Acetonitrile on Aerobic Photolysis of (HB(pz)3)ReO(C2O4)
Seth N. Brown and James M. Mayer
pp 3560 - 3562; DOI:
10.1021/ic00117a030
PDF
Nonsolvated Li-Amide Clusters. Preparation and Crystal Structure of the Adduct {(meso-octaethylcalix-[4]-pyrrole)Li4}(t-BuLi)2 and of the Tetrameric [(cyclohexyl)2NLi]4
Jayne Jubb, Pietro Berno, Shoukang Hao, and Sandro Gambarotta
pp 3563 - 3566; DOI:
10.1021/ic00117a031
PDF
Synthesis and x-ray Structure of Selenasapphyrin
Jerzy Lisowski, Jonathan L. Sessler, and Vincent Lynch
pp 3567 - 3572; DOI:
10.1021/ic00117a032
PDF
Synthesis and Chemical Properties of a Heterodinuclear (Pt,Ru) DNA-DNA and DNA-Protein Crosslinking Agent
Yun Qu and Nicholas Farrell
pp 3573 - 3576; DOI:
10.1021/ic00117a033
PDF
Catecholate Complexes of Silicon: Synthesis and Molecular and Crystal Structures of [Si(cat)2].cntdot.2THF and Li2[Si(cat)3].cntdot.3.5dme (cat = Catecholate Dianion). [Erratum to document cited in CA122:176945]
F. Ekkehardt Hahn, Michael Keck, and Kenneth N. Raymond
pp 3576 - 3576; DOI:
10.1021/ic00117a034
PDF

Issue 14


Structure of a Mononuclear Iron(II)-Catecholate Complex and Its Relevance to the Extradiol-Cleaving Catechol Dioxygenases
Yu-Min Chiou and Lawrence Que
pp 3577 - 3578; DOI:
10.1021/ic00118a001
PDF
A New and Unexpected Arrangement for a ReV:O(N2S2) Complex. The Donor Set in the Basal Plane Is NOS2
Lory Hansen, Malgorzata Lipowska, Andrew Taylor, and Luigi G. Marzilli
pp 3579 - 3580; DOI:
10.1021/ic00118a002
PDF
Redox Switching of Anthracene Fluorescence through the CuII/CuI Couple
Giancarlo De Santis, Luigi Fabbrizzi, Maurizio Licchelli, Carlo Mangano, and Donatella Sacchi
pp 3581 - 3582; DOI:
10.1021/ic00118a003
PDF
Synthesis and Structure of Lanthanide Complexes Derived from the O,N-Chelating, Bis(methylpyridine)-Substituted Alcohol HOC(CMe3)(2-CH2NC5H3Me-6)2
William J. Evans, Reiner Anwander, Uwe H. Berlekamp, and Joseph W. Ziller
pp 3583 - 3588; DOI:
10.1021/ic00118a004
PDF
Copper(II) Complexes of Substituted Macrobicyclic Hexaamines: Combined Trigonal and Tetragonal Distortions
Paul V. Bernhardt, Richard Bramley, Lutz M. Engelhardt, Jack M. Harrowfield, David C. R. Hockless, Bohdan R. Korybut-Daszkiewicz, Elmars R. Krausz, Tammy Morgan, Alan M. Sargeson, and et al.
pp 3589 - 3599; DOI:
10.1021/ic00118a005
PDF
Cyano-Bridged Complexes of trans-Tetrakis(pyridine)ruthenium(II)
Benjamin J. Coe, Thomas J. Meyer, and Peter S. White
pp 3600 - 3609; DOI:
10.1021/ic00118a006
PDF
Insertion of One and Two Arsenic Atoms into Calix[4]arenes
Su Shang, Dilip V. Khasnis, Hongming Zhang, Aaron C. Small, Maomian Fan, and Michael Lattman
pp 3610 - 3615; DOI:
10.1021/ic00118a007
PDF
Novel Reactivity of the Dioxygen Molecule in the Presence of a Manganese(II) Complex and Reducing Agents
Yuzo Nishida, Noriko Tanaka, Akira Yamazaki, Tadashi Tokii, Noriyuki Hashimoto, Koji Ide, and Kaku Iwasawa
pp 3616 - 3620; DOI:
10.1021/ic00118a008
PDF
Reaction of Cyanogen with Cobalt Phthalocyanines
Michael Hanack, Rainer Polley, Siegfried Knecht, and Uwe Schlick
pp 3621 - 3624; DOI:
10.1021/ic00118a009
PDF
19F NMR Spectra and Structures of Halogenated Porphyrins
Eva R. Birnbaum, Julia A. Hodge, Mark W. Grinstaff, William P. Schaefer, Lawrence Henling, Jay A. Labinger, John E. Bercaw, and Harry B. Gray
pp 3625 - 3632; DOI:
10.1021/ic00118a010
PDF
Modeling the Multinuclear Redox-Active Manganese Enzymes. Synthesis, Structure, and Properties of a Bis(dinuclear Mn(III)-.mu.-oxo-bis(.mu.-acetato)) Complex
Yilma Gultneh, Bijan Ahvazi, A. Raza Khan, Ray J. Butcher, and J. P. Tuchagues
pp 3633 - 3645; DOI:
10.1021/ic00118a011
PDF
Synthesis and Structures of Five [Co(Mecyclen)(S-AlaO)]2+ Isomers: Use of nOe and COSY 1H NMR Spectroscopy for Structural Assignment in Solution
David A. Buckingham, Charles R. Clark, Andrew J. Rogers, and Jim Simpson
pp 3646 - 3657; DOI:
10.1021/ic00118a012
PDF
Structural Characterization and Reactivity Properties of a New Class of Fe/Mo/S Double Cubanes with Mo-Bound S-.mu.2-.eta.1,O-.eta.1 Mercapto Carboxylate Ligands. New Catalysts for the Reduction of Hydrazine to Ammonia and Implications Regarding the Function of Nitrogenase
Konstantinos D. Demadis and Dimitri Coucouvanis
pp 3658 - 3666; DOI:
10.1021/ic00118a013
PDF
Thiolato-Activated Oxo-Metal Bond Features in Molybdenum and Tungsten Oxidoreductase Models As Revealed by Raman Spectroscopy
Hiroyuki Oku, Norikazu Ueyama, and kira Nakamura
pp 3667 - 3676; DOI:
10.1021/ic00118a014
PDF
DNA-tentacle porphyrin interactions: AT over GC selectivity exhibited by an outside binding self-stacking porphyrin
Nancy E. Mukundan, Gabor Petho, Dabney W. Dixon, and Luigi G. Marzilli
pp 3677 - 3687; DOI:
10.1021/ic00118a015
PDF
Preparation and Electronic Structure of Substituted Aromatic Dithiolene Complexes of Gold(III)
N. C. Schiodt, P. Sommer-Larsen, T. Bjornholm, M. Folmer Nielsen, J. Larsen, and K. Bechgaard
pp 3688 - 3694; DOI:
10.1021/ic00118a016
PDF
New Charge Transfer Luminescent Polymetallic Complexes of Rhodium(III), Iridium(III), and Ruthenium(II) with the Bridging Ligand 1,4,5,8,9,12-Hexaazatriphenylene
I. Ortmans, P. Didier, and A. Kirsch-De Mesmaeker
pp 3695 - 3704; DOI:
10.1021/ic00118a017
PDF
Analyzing Lanthanide-Induced Shifts in the NMR Spectra of Lanthanide(III) Complexes Derived from 1,4,7,10-Tetrakis(N,N-diethylacetamido)-1,4,7,10-tetraazacyclododecane
John H. Forsberg, Robert M. Delaney, Qian Zhao, George Harakas, and Rubin Chandran
pp 3705 - 3715; DOI:
10.1021/ic00118a018
PDF
Comprehensive high resolution photoelectron spectra of metal carbonyls using synchrotron radiation
Yong-Feng Hu, G. Michael Bancroft, Zhifeng Liu, and Kim H. Tan
pp 3716 - 3723; DOI:
10.1021/ic00118a019
PDF
Kinetics of Complex Formation by Macrocyclic Polyaza Polycarboxylate Ligands: Detection and Characterization of an Intermediate in the Eu3+-dota System by Laser-Excited Luminescence
Shu Ling Wu and William DeW. Horrocks
pp 3724 - 3732; DOI:
10.1021/ic00118a020
PDF
Molecular Mechanics of Cobalt Corrinoids. 2. Structure of Alkylcobalamins and Thermolysis of the Cobalt-Carbon Bond
Helder M. Marques and Kenneth L. Brown
pp 3733 - 3740; DOI:
10.1021/ic00118a021
PDF
Electronic Structures of Peroxonickel(II) Bis(isocyanide) Complexes
Ian Bytheway and Michael B. Hall
pp 3741 - 3746; DOI:
10.1021/ic00118a022
PDF
Oxidative Addition of Diorganyl Ditellurides to [Mn(CO)5]-: Crystal Structures of cis-[Na-18-crown-6-ether.cntdot.2THF][Mn(CO)4(TePh)2], [PPN][(CO)3Mn(.mu.-TePh)3Mn(CO)3], (CO)3Mn(.mu.-TePh)3Co(CO)(.mu.-TePh)2Mn(CO)4, and (CO)4Mn(.mu.-TePh)2Mn(CO)4
Wen-Feng Liaw, Der-Shiaw Ou, Yu-Shiou Li, Way-Zen Lee, Chih-Yuan Chuang, Yi-Pei Lee, Gene-Hsiang Lee, and Shie-Ming Peng
pp 3747 - 3754; DOI:
10.1021/ic00118a023
PDF
Synthesis and Characterization of Polymeric Ag(I)-Telluroether and Cu(I)-Diorganyl Ditelluride Complexes: Crystal Structures of [Ag(MeTe(CH2)3TeMe)2]n[BF4]n, [(.mu.2-MeTeTeMe)Cu(.mu.-Cl)]n, and [Ag2(NCCH3)4(.mu.2-(p-C6H4F)TeTe(p-C6H4F))2][BF4]2
Wen-Feng Liaw, Chia-Huei Lai, Show-Jen Chiou, Yih-Chern Horng, Chin-Cheng Chou, Ming-Chi Liaw, Gene-Hsiang Lee, and Shie-Ming Peng
pp 3755 - 3759; DOI:
10.1021/ic00118a024
PDF
Synthesis of Rutile-Related Oxides, LiMMoO6 (M = Nb, Ta), and Their Proton Derivatives. Intercalation Chemistry of Novel Broensted Acids, HMMoO6.cntdot.H2O
N. S. P. Bhuvanesh and J. Gopalakrishnan
pp 3760 - 3764; DOI:
10.1021/ic00118a025
PDF
Aggregation of Metalated Organics by Hydrogen Bonding: Synthesis and Crystal Structures of 2-Aminophenoxy-Aluminum and Salen-Aluminum Ligand-Separated Ion Pairs
Matthew G. Davidson, Christoph Lambert, Isabel Lopez-Solera, Paul R. Raithby, and Ronald Snaith
pp 3765 - 3779; DOI:
10.1021/ic00118a026
PDF
Crystal Structure of (3-chloroanilinium)8NiCl10 and a Temperature-Dependent X-ray Diffraction Study of the Jahn-Teller Distortion in (3-chloroanilinium)8CuCl10
Mingyi Wei and Roger D. Willett
pp 3780 - 3784; DOI:
10.1021/ic00118a027
PDF
Kinetic Behavior of Carbonate Ligands with Different Coordination Modes: Equilibrium Dynamics for Uranyl(2+) Carbonato Complexes in Aqueous Solution. A 13C and 17O NMR Study
Istvan Banyai, Julius Glaser, Karoly Micskei, Imre Toth, and Laszlo Zekany
pp 3785 - 3796; DOI:
10.1021/ic00118a028
PDF
Organometallic Macrocycle Chemistry. 4. Synthesis and Reactions of [RuX(CS)(PPh3)([9]aneS3)]ClO4 (X = H, Cl, SCN, SC6H4Me-4; [9]aneS3 = 1,4,7-Trithiacyclononane)
Andrew L. Hector and Anthony F. Hill
pp 3797 - 3800; DOI:
10.1021/ic00118a029
PDF
Mononuclear and Binuclear Molybdenum Complexes of the Tris(3,5-dimethyl-1-pyrazolyl)methane Ligand
Ish K. Dhawan, Michael A. Bruck, Brooke Schilling, Carina Grittini, and John H. Enemark
pp 3801 - 3808; DOI:
10.1021/ic00118a030
PDF
Two New Ditungsten Species Containing Chloride and Trimethylphosphine Ligands
F. Albert Cotton and Evgeny V. Dikarev
pp 3809 - 3812; DOI:
10.1021/ic00118a031
PDF
An Unsymmetric Trinuclear Chromium(III) Oxo Carboxylate Assembly: Structure and Characterization of Cr3O(O2CPh)4(8-hqn)3.cntdot.1.25CH2Cl2
Maysa K. Nagi, Anthony Harton, Scott Donald, Young-Sook Lee, Michal Sabat, Charles J. O'Connor, and John B. Vincent
pp 3813 - 3820; DOI:
10.1021/ic00118a032
PDF
Tris(pentafluorophenyl)alane: A Novel Aluminum Organyl
Thomas Belgardt, Jens Storre, Herbert W. Roesky, Mathias Noltemeyer, and Hans-Georg Schmidt
pp 3821 - 3822; DOI:
10.1021/ic00118a033
PDF
NbNi2.38Te3, a New Metal-Rich Niobium Telluride with a "Stuffed" TaFe1+xTe3 Structure
Joerg Neuhausen, E. Wolfgang Finckh, and Wolfgang Tremel
pp 3823 - 3825; DOI:
10.1021/ic00118a034
PDF
Convenient Approach to the Direct Syntheses of Chromium Complexes from Chromium(III) Chloride
Wancydora Kharmawphlang, Subrata Choudhury, Alok K. Deb, and Sreebrata Goswami
pp 3826 - 3828; DOI:
10.1021/ic00118a035
PDF
A Configuration Mixing Approach to the Reactivity of Carbene and Carbene Analogs
Ming-Der Su
pp 3829 - 3832; DOI:
10.1021/ic00118a036
PDF
Tetrathiolate Ligation of Cd2+-Desulforedoxin
Frank Rusnak, Christopher Czaja, Lazaros T. Kakalis, and Ian M. Armitage
pp 3833 - 3834; DOI:
10.1021/ic00118a037
PDF
Spectroelectrochemical Characterization of Solvent-Related Changes in Axial Ligation of Manganese(II) and -(III) Tetraphenylporphyrins
Xi Hai Mu and Franklin A. Schultz
pp 3835 - 3837; DOI:
10.1021/ic00118a038
PDF
Synthesis and Structure of a Hydride- and Sulfide-Bridged Tetranuclear Ruthenium(II,III) Cluster Complex
Kazuko Matsumoto, Hiroshi Ohnuki, and Masaki Kawano
pp 3838 - 3840; DOI:
10.1021/ic00118a039
PDF
Contrasting Reactivity of [NO]BF4 with CpRu(PPh3)(L)SR, L = PPh3 or CO
Alan Shaver, Mohammad El-khateeb, and Anne-Marie Lebuis
pp 3841 - 3843; DOI:
10.1021/ic00118a040
PDF
Dimethoxyethane as a Solvent for the Synthesis of C-Monosubstituted o-Carborane Derivatives
Clara Vinas, Rajae Benakki, Francesc Teixidor, and Jaume Casabo
pp 3844 - 3845; DOI:
10.1021/ic00118a041
PDF
ROESY NMR of Basic Ambient-Temperature Chloroaluminate Ionic Liquids
Robert A. Mantz, Paul C. Trulove, Richard T. Carlin, and Robert A. Osteryoung
pp 3846 - 3847; DOI:
10.1021/ic00118a042
PDF
Polyoxometalate-Diphosphate Complexes. 4. Structure of Na4[(O3PCHN(CH3)2PO3)W2O6].cntdot.11H2O
Uli Kortz and Michael T. Pope
pp 3848 - 3850; DOI:
10.1021/ic00118a043
PDF
1H NMR studies of the imidazole complex of cytochrome c: Resonance assignment and structural characterization of the heme cavity. [Erratum to document cited in CA122:74955]
Weiping Shao
pp 3850 - 3850; DOI:
10.1021/ic00118a044
PDF

Issue 15


Spectroscopic observation of coupled metal-ligand vibrational modes in the luminescence spectrum of trans-[ReO2(1-methylimidazole)4]I
Carole Savoie, Christian Reber, Suzanne Belanger, and Andre L. Beauchamp
pp 3851 - 3852; DOI:
10.1021/ic00119a001
PDF
The Benzannelation Approach to Novel Gallium and Indium Heterocycles
Andreas Decken, Francois P. Gabbaie, and Alan H. Cowley
pp 3853 - 3854; DOI:
10.1021/ic00119a002
PDF
Different Pathways of the Reaction of InCl with Ph3PAuCl: Isolation of the First Mixed-Valent Mixed-Metal Gold/Indium Cluster
Francois P. Gabbai, Annette Schier, Juergen Riede, and Hubert Schmidbaur
pp 3855 - 3856; DOI:
10.1021/ic00119a003
PDF
Chiral [Ru(pp)2(CO)2]2+ Species (pp = Bidentate Polypyridyl Ligand) and Their Use in the Stereoselective Synthesis of Ligand-Bridge Dinuclear Complexes
Todd J. Rutherford, Michael G. Quagliotto, and F. Richard Keene
pp 3857 - 3858; DOI:
10.1021/ic00119a004
PDF
Distribution of Halogen Atoms in Mixed-Valence Linear-Chain Complexes of Platinum: A Solid-State 15N NMR Study
Elliot J. W. Austin, Patrick J. Barrie, and Robin J. H. Clark
pp 3859 - 3863; DOI:
10.1021/ic00119a005
PDF
95Mo NMR Spectroscopic Evidence for the Weak .pi.-Acceptor Ability of PCl3
Elmer C. Alyea and Shuquan Song
pp 3864 - 3873; DOI:
10.1021/ic00119a006
PDF
Online Mass Analysis of Reaction Products by Electrospray Ionization. Photosubstitution of Ruthenium(II) Diimine Complexes
Ryuichi Arakawa, Jian Lu, Akio Yoshimura, Koichi Nozaki, Takeshi Ohno, Hidekazu Doe, and Takekiyo Matsuo
pp 3874 - 3878; DOI:
10.1021/ic00119a007
PDF
Influence of X and R on the Emission of [Ru(X)(R)(CO)2(.alpha.-diimine)] (X = Halide, Mn(CO)5; R = alkyl): Change of Character of the Lowest-Excited State from MLCT (X = Cl) to XLCT (X = I) and .sigma.b.pi. (X = Mn(CO)5)
Heleen A. Nieuwenhuis, Derk J. Stufkens, and Antonin Vlcek
pp 3879 - 3886; DOI:
10.1021/ic00119a008
PDF
Resonance Raman Spectroelectrochemical Study of (.mu.-3,3',4,4'-Tetraimino-3,3',4,4'-tetrahydrobiphenyl)bis[bis(bipyridine)ruthenium(II)](4+) and Its One-, Two-, and Four-Electron-Reduction Products
F. Hartl, T. L. Snoeck, D. J. Stufkens, and A. B. P. Lever
pp 3887 - 3894; DOI:
10.1021/ic00119a009
PDF
Spectroscopic Studies of the Active Site of Galactose Oxidase
Peter F. Knowles, Rodney D. Brown, Seymour H. Koenig, Shengke Wang, Robert A. Scott, Michele A. McGuirl, Doreen E. Brown, and David M. Dooley
pp 3895 - 3902; DOI:
10.1021/ic00119a010
PDF
Interpretation of Electronic and EPR Spectra of Copper(II) Amine Complexes: A Test of the MM-AOM Method
Peter Comba, Trevor W. Hambley, Michael A. Hitchman, and Horst Stratemeier
pp 3903 - 3911; DOI:
10.1021/ic00119a011
PDF
Synthesis and Structure of Sr2VN3 and Ba2VN3, Two New Nitridovanadates
D. H. Gregory, M. G. Barker, P. P Edwards, and D. J. Siddons
pp 3912 - 3916; DOI:
10.1021/ic00119a012
PDF
Crystal and Magnetic Structures of Layer Transition Metal Phosphate Hydrates
Simon G. Carling, Peter Day, and Dirk Vissen
pp 3917 - 3927; DOI:
10.1021/ic00119a013
PDF
Control of Ligand Field Strength through Intra- and Interligand Contact. Octahedral Iron(II) Poly(pyrazolyl)borate Complexes
Yoshiki Sohrin, Hisao Kokusen, and Masakazu Matsui
pp 3928 - 3934; DOI:
10.1021/ic00119a014
PDF
Reactivity of Decaborane(14) with Pyridine: Synthesis and Characterization of the First 6,6-Substituted Isomer of nido-B10H14, 6,6-(C5H5N)2B10H12, and Application of 11B-11B Double-Quantum NMR Spectroscopy
Sophie M. Cendrowski-Guillaume, Jennifer L. O'Loughlin, Istvan Pelczer, and James T. Spencer
pp 3935 - 3941; DOI:
10.1021/ic00119a015
PDF
Sequence-specific 1H, 13C, and 15N NMR assignments for oxidized ferredoxin from Clostridium pasteurianum
Sergio D. B. Scrofani, Robert T. C. Brownlee, Maruse Sadek, and Anthony G. Wedd
pp 3942 - 3952; DOI:
10.1021/ic00119a016
PDF
Resonance Raman Spectroscopic Core-Size Correlations for the Crystallographically Defined Complexes FeII(OEP), FeII(OEC), FeIII(OEP)(NCS), [FeIII(OEP)(N-MeIm)2]+, and [FeIII(OEP)(DMSO)2]+
Muthusamy Mylrajan, Laura A. Andersson, Jie Sun, Thomas M. Loehr, Carol S. Thomas, Eric P. Sullivan, Mark A. Thomson, Kim M. Long, Oren P. Anderson, and Steven H. Strauss
pp 3953 - 3963; DOI:
10.1021/ic00119a017
PDF
Complexation of Na+ in Redox-Active Ferrocene Crown Ethers, a Structural Investigation, and an Unexpected Case of Li+ Selectivity
Herbert Plenio and Ralph Diodone
pp 3964 - 3972; DOI:
10.1021/ic00119a018
PDF
Synthesis and Characterization of Gallium and Indium Thiolate Complexes. Crystal and Molecular Structures of [M(SC5H4N)3] (M = Ga, In), [In(SC5H3N-3-SiMe3)3], and [M2(OC2H5)2(SC5H4N)4] (M = Ga, In)
David J. Rose, Yuan Da Chang, Qin Chen, Peter B. Kettler, and Jon Zubieta
pp 3973 - 3979; DOI:
10.1021/ic00119a019
PDF
Synthesis and Characterization of Volatile Sodium Yttrium Fluoroalkoxides. Structure of Na3Y(OCH(CF3)2)6(THF)3 and Na2Y(OCMe(CF3)2)5(THF)3
Francois Laurent, John C. Huffman, Kirsten Folting, and Kenneth G. Caulton
pp 3980 - 3985; DOI:
10.1021/ic00119a020
PDF
Co(tacn)(NCS)3 Synthesis and Thiocyanate Photosubstitution. Yield Enhancement by Added Thiocyanate
A. D. Kirk and L.-Z. Cai
pp 3986 - 3992; DOI:
10.1021/ic00119a021
PDF
Electron Transfer. 126. Reductions of Oxime-Bound Nickel(IV)
Subrata Mandal and E. S. Gould
pp 3993 - 3997; DOI:
10.1021/ic00119a022
PDF
Uphill electron transfer in pentaammineruthenium(III)-modified ferrocytochrome c: Rates, thermodynamics, and the mediating role of the ruthenium moiety
Ji Sun, James F. Wishart, and Stephan S. Isied
pp 3998 - 4000; DOI:
10.1021/ic00119a023
PDF
Control of Photosubstitution in Dinuclear Ruthenium Polypyridyl Complexes by Choice of Bridging Ligand
Helen P. Hughes and Johannes G. Vos
pp 4001 - 4003; DOI:
10.1021/ic00119a024
PDF
Electrostatic, Covalent, and Transfer Interpretation of Bond Strengths
Russell S. Drago and Ngai M. Wong
pp 4004 - 4007; DOI:
10.1021/ic00119a025
PDF
Synthesis and Structural Characterization of [(SalpanAl)Li(THF)2]2 and [(SalomphanAl)Li(THF)2]2: A New Class of Aluminum Anion
David A. Atwood and Drew Rutherford
pp 4008 - 4010; DOI:
10.1021/ic00119a026
PDF

Issue 16


Extensively Conjugated Bimetallic (.mu.-Tetrathiooxalato)copper(II) Complex (Bu4N)2[(C3S5)CuC2S4Cu(C3S5)] for Electrically Conducting Charge Transfer Complexes
Jens Piotraschke, Anthony E. Pullen, Khalil A. Abboud, and John R. Reynolds
pp 4011 - 4012; DOI:
10.1021/ic00120a001
PDF
Synthesis and Crystal Structure of a Novel Copper(I) Crown Complex: A Spectrochemical Metal Ion Probe for Alkali Metal and Alkaline Earth Metal Cations
Vivian Wing-Wah Yam, Kenneth Kam-Wing Lo, and Kung-Kai Cheung
pp 4013 - 4014; DOI:
10.1021/ic00120a002
PDF
Synthesis, Structure, and Flash Photolysis Kinetic Studies of Borylated Bis(dioximato)iron(II) Carbonyl Complexes
D. G. A. Harshani de Silva, Daniel B. Leznoff, Gary Impey, Isak Vernik, Zhe Jin, and Dennis V. Stynes
pp 4015 - 4025; DOI:
10.1021/ic00120a003
PDF
Effects of solvent, pressure, and temperature on the spectroscopy, photophysics, and photochemistry of the hexaamminechromium(III) ion, [Cr(NH3)6]3+
Duane A. Friesen, Sang H. Lee, Rodney E. Nashiem, Stephen P. Mezyk, and William L. Waltz
pp 4026 - 4031; DOI:
10.1021/ic00120a004
PDF
Configurational Isomerism in Bis(N-alkylsalicylaldiminato)nickel(II) Complexes: The Equilibrium Planar .dblharw. Tetrahedral and Its Effect on the Kinetics and Mechanism of Ligand Substitution
Rainer Knoch, Horst Elias, and Helmut Paulus
pp 4032 - 4040; DOI:
10.1021/ic00120a005
PDF
Direct and Indirect Oxidations by Peroxynitrite
Sara Goldstein and Gidon Czapski
pp 4041 - 4048; DOI:
10.1021/ic00120a006
PDF
Oxidation and Reduction Reactions of Hydroperoxo Cobalt Macrocycles
Wei-Dong Wang, Andreja Bakac, and James H. Espenson
pp 4049 - 4056; DOI:
10.1021/ic00120a007
PDF
Electron Transfer. 125. Intermediate Oxidation States in the Reduction of Chromium(VI) with Hypophosphite
Swapan K. Chandra, E. Gelerinter, and E. S. Gould
pp 4057 - 4061; DOI:
10.1021/ic00120a008
PDF
Tripodal Amido Ligands Containing an "Active" Ligand Periphery
Harald Memmler, Kevin Walsh, Lutz H. Gade, and Joseph W. Lauher
pp 4062 - 4068; DOI:
10.1021/ic00120a009
PDF
Tripodal Triamidostannates and -plumbates
Konrad W. Hellmann, Lutz H. Gade, Olaf Gevert, Paul Steinert, and Joseph W. Lauher
pp 4069 - 4078; DOI:
10.1021/ic00120a010
PDF
Synthesis of Neutral and Anionic Uranyl Aryloxide Complexes from Uranyl Amide Precursors: X-ray Crystal Structures of UO2(O-2,6-i-Pr2C6H3)2(py)3 and [Na(THF)3]2[UO2(O-2,6-Me2C6H3)4]
David M. Barnhart, Carol J. Burns, Nancy N. Sauer, and John G. Watkin
pp 4079 - 4084; DOI:
10.1021/ic00120a011
PDF
Bis(trifluoromethanesulfonato)(tetra-p-tolylporphyrinato)silicon(IV), (TTP)Si(OTf)2: The First Structurally Characterized (Porphyrinato)silicon(IV) Complex
Kevin M. Kane, Frederick R. Lemke, and Jeffrey L. Petersen
pp 4085 - 4091; DOI:
10.1021/ic00120a012
PDF
Selective Formation of Four-Membered Metallacyclic Pt-N-P-C Compounds from Reactions of Bis((N-arylimino)phosphoranyl)methanes with Halide-Bridged Platinum(II) Phosphine Dimers. X-ray Crystal Structures of [PtCl(PMe2Ph){CH(PPh2:NC6H4-4-CH3)(PPh2N'HC6H4-4-CH3)}]+Cl- and [PtCl(PEt3){CH(PPh2:NC6H4-4-CH3)(PPh2N'HC6H4-4-CH3)}]+[PtCl3(PEt3)]-
Mandy W. Avis, Kees Vrieze, Huub Kooijman, Nora Veldman, Anthony L. Spek, and Cornelis J. Elsevier
pp 4092 - 4105; DOI:
10.1021/ic00120a013
PDF
Lindqvist-Type Oxo-Nitrosyl Complexes. Syntheses, Vibrational, Multinuclear Magnetic Resonance (14N, 17O, 95Mo, and 183W), and Electrochemical Studies of [M5O18{M'(NO)}]3- anions (M, M' = Mo, W)
Anna Proust, Rene Thouvenot, Soo-Gyun Roh, Jeong-Kun Yoo, and Pierre Gouzerh
pp 4106 - 4112; DOI:
10.1021/ic00120a014
PDF
Infrared Absorption Spectra of Sodium Pentacyanonitrosylosmate(II) Dihydrate in Two Excited Electronic Metastable States
J. A. Gueida, O. E. Piro, and P. J. Aymonino
pp 4113 - 4116; DOI:
10.1021/ic00120a015
PDF
Comparative Chemical-Ionization and Electron-Ionization Mass Spectra of Salen Complexes with Metals of the First Transition Series
Steven M. Schildcrout, Somu SriHari, and John Masnovi
pp 4117 - 4122; DOI:
10.1021/ic00120a016
PDF
Synthesis and Magnetic Exchange Properties of Linear Trinuclear Oxo-Bridged MIIIORuIVOMIII Complexes (M = Fe, Cr, Mn) Formed by Two-Electron Redox Reactions
Kevin J. Berry, Boujemaa Moubaraki, Keith S. Murray, Peter J. Nichols, Lewis D. Schulz, and Bruce O. West
pp 4123 - 4133; DOI:
10.1021/ic00120a017
PDF
Ab Initio Interpretation of the Closed-Shell Intermolecular E.cntdot..cntdot..cntdot.E Attraction in Dipnicogen (H2E-EH2)2 and Dichalcogen (HE-EH)2 Hydride Model Dimers
Karl Wilhelm Klinkhammer and Pekka Pyykko
pp 4134 - 4138; DOI:
10.1021/ic00120a018
PDF
Coexistence of Magnetic and Delocalized Electrons in Hybrid Molecular Materials. The Series of Organic-Inorganic Radical Salts (BEDT-TTF)8[XW12O40](solv)n (X = 2(H+), BIII, SiIV, CuII, CoII, and FeIII; solv = H2O, CH3CN)
Carlos J. Gomez-Garcia, Carlos Gimenez-Saiz, Smail Triki, Eugenio Coronado, Pierre Le Magueres, Lahcene Ouahab, Laurent Ducasse, Claude Sourisseau, and Pierre Delhaes
pp 4139 - 4151; DOI:
10.1021/ic00120a019
PDF
Polymorphism and Related Magnetic Behavior in Decamethylferrocenium Salts of Transition-Metal Maleonitriledithiolates
Mohammed Fettouhi, Lahcene Ouahab, Massa Hagiwara, Epiphane Codjovi, Olivier Kahn, H. Constant-Machado, and Francois Varret
pp 4152 - 4159; DOI:
10.1021/ic00120a020
PDF
The [Co4O4]4+ Cubane as a Quadruply-Bridging Unit: The Mixed-Valence Cluster [Co8O4(O2CPh)12(solv)4] (solv = DMF, MeCN, H2O)
Katerina Dimitrou, Jui-Sui Sun, Kirsten Folting, and George Christou
pp 4160 - 4166; DOI:
10.1021/ic00120a021
PDF
Structural and Magnetic Properties of [Ni4(.mu.3-OMe)4(dbm)4(MeOH)4] and [Ni4(.eta.1,.mu.3-N3)4(dbm)4(EtOH)4]. Magnetostructural Correlations for [Ni4X4]4+ Cubane Complexes
Malcolm A. Halcrow, Jui-Sui Sun, John C. Huffman, and George Christou
pp 4167 - 4177; DOI:
10.1021/ic00120a022
PDF
A New Layered Mixed-Valent Potassium Vanadium Selenite, KV2SeO7
Kyu-Seok Lee, Young-Uk Kwon, Hae Namgung, and Sei-Hwan Kim
pp 4178 - 4181; DOI:
10.1021/ic00120a023
PDF
Measurements of Microwave Spectra and Structural Parameters for Cyclopentadienylchromium Dicarbonyl Nitrosyl
S. G. Kukolich, R. T. McKay, S. M. Breckenridge, L. D. Flores, G. E. Morris, S. M. Sickafoose, and D. L. Morrison
pp 4182 - 4186; DOI:
10.1021/ic00120a024
PDF
Lattice oxygen mobility and structural stability of Ni and Cu octahedral molecular sieves having the cryptomelane structure
Yuan-Gen Yin, Wen-Qing Xu, Steven L. Suib, and C. L. O'Young
pp 4187 - 4193; DOI:
10.1021/ic00120a025
PDF
A Unique Coordination Mode for Citrate and a Transition Metal: K2[V(O)2(C6H6O7)]2.cntdot.4H2O
David W. Wright, Patricia A. Humiston, William H. Orme-Johnson, and William M. Davis
pp 4194 - 4197; DOI:
10.1021/ic00120a026
PDF
Synthesis, Characterization, and Reactivity of an Oxoruthenium(IV) Complex Containing a Bis(oxazoline) Ligand. Crystal Structure of [Ru((S)-bpop)(Cl)(trpy)](BF4)
Lisa F. Szczepura, Stephen M. Maricich, Ronald F. See, Melvyn Rowen Churchill, and Kenneth J. Takeuchi
pp 4198 - 4205; DOI:
10.1021/ic00120a027
PDF
Carbolithiations of N,N'-Di-tert-butyl-1,4-diazabuta-1,3-diene
Michael G. Gardiner and Colin L. Raston
pp 4206 - 4212; DOI:
10.1021/ic00120a028
PDF
Structural and EPR Studies of Vanadium Complexes of Deprotonated Amide Ligands: Effects on the 51V Hyperfine Coupling Constant
Charles R. Cornman, Edward P. Zovinka, Yvette D. Boyajian, Katherine M. Geiser-Bush, Paul D. Boyle, and Phirtu Singh
pp 4213 - 4219; DOI:
10.1021/ic00120a029
PDF
Mono- and Dinuclear Zinc Complexes of XDK, H2XDK = m-Xylenediamine Bis(Kemp's triacid imide), and Their Reaction with Phosphate Esters
Tomoaki Tanase, Joanne W. Yun, and Stephen J. Lippard
pp 4220 - 4229; DOI:
10.1021/ic00120a030
PDF
Untwisting a Helically Coordinated Hexaazamacrocycle: Divalent Mg, Ca, Sr, Cd, Hg, and Pb Complexes of (pyo)2[18]dieneN6 and the X-ray Crystal Structure of the Cd Complex
L. Henry Bryant, Abdessadek Lachgar, and Susan C. Jackels
pp 4230 - 4238; DOI:
10.1021/ic00120a031
PDF
A New Form of Fluxional Process in the Sterically Hindered Oxo Cluster [Ru3(.mu.3-O)(.mu.3-CO)(CO)3(.mu.-Ph2PCH2PPh2)3]
Hameed A. Mirza, Jagadese J. Vittal, and Richard J. Puddephatt
pp 4239 - 4243; DOI:
10.1021/ic00120a032
PDF
X-Ray Diffraction Study of the Correlation between Electrostatic Potential and K-Absorption Edge Energy in a Bis(.mu.-oxo) Mn(III)-Mn(IV) Dimer
Anette Frost Jensen, Zhengwei Su, Niels K. Hansen, and Finn Krebs Larsen
pp 4244 - 4252; DOI:
10.1021/ic00120a033
PDF
Structure of Crystalline (C5Me5)ReO3 and Implied Nonexistence of "(C5Me5)Tc2O3"
Anthony K. Burrell, F. Albert Cotton, Lee M. Daniels, and Vaclav Petricek
pp 4253 - 4255; DOI:
10.1021/ic00120a034
PDF
[PhP(S)(NMeNH2)2]ZnCl2: A Reagent for the Synthesis of Polymetallic Complexes. X-ray Structure of the Electroactive Compound [PhP(S)(NMeN:CHC5H4FeCp)2]ZnCl2
Beatrice Delavaux-Nicot, Benedicte Douziech, Rene Mathieu, and Guy Lavigne
pp 4256 - 4261; DOI:
10.1021/ic00120a035
PDF
Development of Redox-Active Optical Mesostructures at Chemically Modified Electrode Interfaces
Ying Wu, Brian W. Pfennig, Andrew B. Bocarsly, and Edward P. Vicenzi
pp 4262 - 4267; DOI:
10.1021/ic00120a036
PDF
Hydrotris(3,4-diphenyl-5-methylpyrazol-1-yl)borate: Control of Coordination Number via an Equatorial Substituent
Jiong Huang, Lily Lee, Brian S. Haggerty, Arnold L. Rheingold, and Marc A. Walters
pp 4268 - 4270; DOI:
10.1021/ic00120a037
PDF
Chromium-Centered Imido Group Transfer
Wa-Hung Leung, Man-Ching Wu, Tai-Chu Lau, and Wing-Tak Wong
pp 4271 - 4274; DOI:
10.1021/ic00120a038
PDF
Synthesis and Structural Characterization of a Novel Cyclodithiatriazine Containing Sulfur and Molybdenum in High Oxidation States
Thomas Luebben, Michael Witt, Herbert W. Roesky, Mathias Noltemeyer, and Hans-Georg Schmidt
pp 4275 - 4277; DOI:
10.1021/ic00120a039
PDF
Synthesis of Polycrystalline Bismuth Telluride by a Metal-Organo Complex Method
Joseph J. Ritter and Pichai Maruthamuthu
pp 4278 - 4280; DOI:
10.1021/ic00120a040
PDF
Thermodynamic Parameters for Cobalt-Quinone Electron Transfer and Spin Transition Steps of the CoIII(bpy)(3,5-DBSQ)(3,5-DBCat)/CoII(bpy)(3,5-DBSQ)2 Valence Tautomeric Equilibrium
Cortlandt G. Pierpont and Ok-Sang Jung
pp 4281 - 4283; DOI:
10.1021/ic00120a041
PDF
Preparation and Structure of [Mo6Cl8(CH3CN)6](SbCl6)4.cntdot.2EtOH
Grant M. Ehrlich, Christopher J. Warren, Robert C. Haushalter, and Francis J. DiSalvo
pp 4284 - 4286; DOI:
10.1021/ic00120a042
PDF

Issue 17


Evidence of Ordering of Cobaltocenium Ions in SnSe2{Co(.eta.-C5D5)2}0.3 Using Single-Crystal Solid State 2H NMR Spectroscopy
S. J. Mason, S. J. Heyes, H. V. Wong, and D. O'Hare
pp 4287 - 4289; DOI:
10.1021/ic00121a001
PDF
Lewis Base Adducts of Diboron Compounds: Molecular Structures of [B2(cat)2(4-picoline)] and [B2(cat)2(4-picoline)2] (cat = 1,2-O2C6H4)
Paul Nguyen, Chaoyang Dai, Nicholas J. Taylor, William P. Power, Todd B. Marder, Nigel L. Pickett, and Nicholas C. Norman
pp 4290 - 4291; DOI:
10.1021/ic00121a002
PDF
Discrete Complexes Incorporating Heteropolychalcogenide Ligands: Ring and Cage Structures in [Au2(TeS3)2]2-, [Ag2Te(TeS3)2]2-, and [Ag2Te(TeSe3)2]2-
Duck-Young Chung, Song-Ping Huang, Kang-Woo Kim, and Mercouri G. Kanatzidis
pp 4292 - 4293; DOI:
10.1021/ic00121a003
PDF
Metallohelices: Effects of Weak Interactions on Helical Morphology
Tatsuya Kawamoto, Om Prakash, Robert Ostrander, Arnold L. Rheingold, and A. S. Borovik
pp 4294 - 4295; DOI:
10.1021/ic00121a004
PDF
Sterically Hindered Aluminum-Magnesium Bridged Complex: {Me2Al[.mu.-N(iC3H7)2]2Mg[O-2,6-(tC4H9)2-4-MeC6H2]}
Chung-Cheng Chang, Tzong-Yih Her, Mung-Dar Li, Rodney Williamson, Gene-Hsiung Lee, Shie-Ming Peng, and Yu Wang
pp 4296 - 4298; DOI:
10.1021/ic00121a005
PDF
77Se Solid-State NMR Spectroscopy and Structures of Tetramethylammonium Pentaselenide and Hexaselenide Complexes
Patrick J. Barrie, Robin J. H. Clark, Duck-Young Chung, Debojit Chakrabarty, and Mercouri G. Kanatzidis
pp 4299 - 4304; DOI:
10.1021/ic00121a006
PDF
Synthesis and Structural Characterization of Niobium(IV) Amido Complexes and a Niobium(V) Bisimido Complex
Simon G. Bott, David M. Hoffman, and Sri Prakash Rangarajan
pp 4305 - 4310; DOI:
10.1021/ic00121a007
PDF
Synthesis and Characterization of a Novel Azatitanatrane
Zhibang Duan and John G. Verkade
pp 4311 - 4316; DOI:
10.1021/ic00121a008
PDF
Analysis of the absorption and magnetic circular dichroism spectra of low spin (S = 1/2) iron(III) phthalocyanine
Edward A. Ough and Martin J. Stillman
pp 4317 - 4325; DOI:
10.1021/ic00121a009
PDF
Tetranuclear Pentaammineruthenium Complexes Bridged by .pi.-Conjugated Tetracyano Ligands Related to TCNE: Syntheses and Spectroscopy of Different Oxidation States
Michael Moscherosch, Eberhard Waldhoer, Herbert Binder, Wolfgang Kaim, and Jan Fiedler
pp 4326 - 4335; DOI:
10.1021/ic00121a010
PDF
13C and 31P NMR Study of Paramagnetic Lanthanide(III) Texaphyrins
Jerzy Lisowski, Jonathan L. Sessler, and Tarak D. Mody
pp 4336 - 4342; DOI:
10.1021/ic00121a011
PDF
Experimental and Theoretical Vibrational Studies of Covalent X-N3 Azides (X = H, F, Cl, Br, I). Application of the Density Functional Theory and Comparison with ab Initio Results
Axel Schulz, Inis C. Tornieporth-Oetting, and Thomas M. Klapoetke
pp 4343 - 4346; DOI:
10.1021/ic00121a012
PDF
Spin Densities and Spin Coupling in Iron-Sulfur Clusters: A New Analysis of Hyperfine Coupling Constants
J.-M. Mouesca, L. Noodleman, D. A. Case, and B. Lamotte
pp 4347 - 4359; DOI:
10.1021/ic00121a013
PDF
Raman Spectroscopic and ab initio Quantum Chemical Investigations of Molecules and Complex Ions in the Molten System CsCl-NbCl5-NbOCl3
Christian Rosenkilde, George Voyiatzis, Vidar R. Jensen, Martin Ystenes, and Terje Oestvold
pp 4360 - 4369; DOI:
10.1021/ic00121a014
PDF
Static and vibronic contributions to the spectral intensities of tetrahalocopper(II), -platinum(II), and -palladium(II) chromophores
Adam J. Bridgeman and Malcolm Gerloch
pp 4370 - 4378; DOI:
10.1021/ic00121a015
PDF
Infrared Spectroscopic Study of the Cryogenic Thin Film and Matrix-Isolated Complexes of TiCl4 with NH3 and (CH3)3N
Jennifer B. Everhart and Bruce S. Ault
pp 4379 - 4384; DOI:
10.1021/ic00121a016
PDF
New Metal Carbonyl Complexes of Mixed Group 15/16 Anions: Structural Characterization of [Fe(As3Se3)2(CO)]2-, [Mn(As3Se5)(CO)3]2-, and [Fe2(AsTe4)2(CO)4]2-
Thomas M. Martin, Paul T. Wood, George L. Schimek, William T. Pennington, and Joseph W. Kolis
pp 4385 - 4391; DOI:
10.1021/ic00121a017
PDF
The Chemistry of Iron Carbonyl Sulfide and Selenide Anions
Russell L. Holliday, Lisa C. Roof, Beverly Hargus, Donna M. Smith, Paul T. Wood, William T. Pennington, and Joseph W. Kolis
pp 4392 - 4401; DOI:
10.1021/ic00121a018
PDF
(Arene)cyclopentadienylchromium Chemistry. Synthesis, EPR, NMR, and Cyclic Voltammetry of Neutral Compounds and Their Monocations
Frank H. Koehler, Bernhard Metz, and Werner Strauss
pp 4402 - 4413; DOI:
10.1021/ic00121a019
PDF
Synthesis, Photochemistry, and Molecular Structures of Peripherally-Molybdenated Tetraphenylporphyrins and -metalloporphyrins
Natalie M. Rowley, Stefan S. Kurek, Jean-Dominique Foulon, Tom A. Hamor, Christopher J. Jones, Jon A. McCleverty, Stephan M. Hubig, Eric J. L. McInnes, Nicholas N. Payne, and Lesley J. Yellowlees
pp 4414 - 4426; DOI:
10.1021/ic00121a020
PDF
Potential for Redox Isomerism by Quinone Complexes of Iron(III). Studies on Complexes of the FeIII(N-N)(DBSQ)(DBCat) Series with 2,2'-Bipyridine and N,N,N',N'-Tetramethylethylenediamine Coligands
Attia S. Attia, Samaresh Bhattacharya, and Cortlandt G. Pierpont
pp 4427 - 4433; DOI:
10.1021/ic00121a021
PDF
Structures and Stabilities of Tungstate Complexes of .alpha.-Hydroxy Acids. 183W NMR Study of the Influence of Ligand Substitution
Miloudi Hlaibi, Stella Chapelle, Mohammed Benaissa, and Jean-Francois Verchere
pp 4434 - 4440; DOI:
10.1021/ic00121a022
PDF
Synthesis, Characterization, and Reactivity of Platinum Cysteinato and Related Thiolato Complexes: Molecular Structure of Pt2(.mu.-N-acetyl-L-cysteine-S)2(bpy)2
Kathryn A. Mitchell and Craig M. Jensen
pp 4441 - 4446; DOI:
10.1021/ic00121a023
PDF
Unexpectedly Large Change of Water Exchange Rate and Mechanism on [Ln(DTPA-BMA)(H2O)] Complexes along the Lanthanide(III) Series
Dirk Pubanz, Gabriel Gonzalez, D. Hugh Powell, and Andre E. Merbach
pp 4447 - 4453; DOI:
10.1021/ic00121a024
PDF
Synthesis, Structure, and Characterization of N-Ligated W6S8L6 Cluster Complexes
Grant M. Ehrlich, Christopher J. Warren, Deborah A. Vennos, Douglas M. Ho, Robert C. Haushalter, and Francis J. DiSalvo
pp 4454 - 4459; DOI:
10.1021/ic00121a025
PDF
Hydrothermal Syntheses and Crystal Structures of Two Oxovanadium-Organodiphosphonate Phases: [H2N(C2H4)2NH2][(VO)2(O3PCH2CH2CH2PO3H)2], a "Stair-Step" Structure Incorporating an Organic Cationic Template, and [(VO)(H2O){O3PCH2NH(C2H4)2NHCH2PO3}], a Layered Structure "Pillared" by a Piperazinium-Tethered Diphosphonate
Victoria Soghomonian, Roberto Diaz, Robert C. Haushalter, Charles J. O'Connor, and Jon Zubieta
pp 4460 - 4466; DOI:
10.1021/ic00121a026
PDF
Changes in Geometries and Spin States of Thiolato-Schiff Base NiN2S2 Complexes Containing N,N'-Biphenyl Backbones
Henrik Frydendahl, Hans Toftlund, Jan Becher, Jennifer C. Dutton, Keith S. Murray, Lucille F. Taylor, Oren P. Anderson, and Edward R. T. Tiekink
pp 4467 - 4476; DOI:
10.1021/ic00121a027
PDF
Electrostatic Influences on the Kinetics of the Reactions of Lobster Metallothioneins with the Electrophilic Disulfides 2,2'-Dithiodipyridine (PySSPy) and 5,5'-Dithiobis(2-nitrobenzoic acid) (ESSE)
Zhiwu Zhu, David H. Petering, and C. Frank Shaw
pp 4477 - 4483; DOI:
10.1021/ic00121a028
PDF
DNA-Binding Studies of a Bifunctional Platinum Complex That Is a Luminescent Intercalator
Claire S. Peyratout, Toni K. Aldridge, Denise K. Crites, and David R. McMillin
pp 4484 - 4489; DOI:
10.1021/ic00121a029
PDF
Reversible Multi-Step and Multielectron Redox Behavior of the Oxo-Centered Trinuclear Ruthenium Complex with Redox-Active Ligand, [Ru3(.mu.3-O)(.mu.-CH3CO2)6(mbpy+)3]4+ (mbpy+ = N-Methyl-4,4'-bipyridinium Ion) and Its Trirhodium and Diruthenium-Rhodium Derivatives
Masaaki Abe, Yoichi Sasaki, Yasuko Yamada, Keiichi Tsukahara, Shigenobu Yano, and Tasuku Ito
pp 4490 - 4498; DOI:
10.1021/ic00121a030
PDF
Two Crystal Structures Featuring the Tetraperoxovanadate(V) Anion and a Brief Reinvestigation of Peroxovanadate Equilibria in Neutral and Basic Solutions
Tae-Jin Won, Charles L. Barnes, Elmer O. Schlemper, and Richard C. Thompson
pp 4499 - 4503; DOI:
10.1021/ic00121a031
PDF
Chiral Recognition Among Tris(diimine)-Metal Complexes. 4. Atomistic Computer Modeling of a Monolayer of [Ru(bpy)3]2+ Intercalated into a Smectite Clay
Josef Breu and C. Richard A. Catlow
pp 4504 - 4510; DOI:
10.1021/ic00121a032
PDF
Thermochromic Properties of Diphenyl Diselenide in Solution
H. Kunkely, A. Vogler, and J. K. Nagle
pp 4511 - 4512; DOI:
10.1021/ic00121a033
PDF
Nucleophilic Reactions with Tetramethoxysilane and Tetraethoxysilane under Negative Ion Chemical Ionization Conditions
Vemisetty S. Murthy and Jack M. Miller
pp 4513 - 4515; DOI:
10.1021/ic00121a034
PDF
Solid state and solution behavior of triorganotin(IV) derivatives containing the 2,4,6-tris(trifluoromethyl)benzene and 1,4-bis(perfluoroisopropoxy)tetrafluorobenzene ligands: crystal and molecular structures of 2,4,6-(CF3)3C6H2Sn(C6H5)3 and 1,4-[(CH3)3SnOC(CF3)2]2C6F4. [Erratum to document cited in CA122:10143]
Ashwani Vij, Robert L. Kirchmeier, Roger D. Willett, Jean'ne M. Shreeve, and Mingyi Wei
pp 4516 - 4516; DOI:
10.1021/ic00121a035
PDF

Issue 18


A Model for the Low-Spin, Non-Heme, Thiolate-Ligated Iron Site of Nitrile Hydratase
Steven C. Shoner, David Barnhart, and Julie A. Kovacs
pp 4517 - 4518; DOI:
10.1021/ic00122a001
PDF
Uncharged Mixed-Ligand Clusters with the [Fe4S4]+ and [Fe4S4]2+ Cores. Synthesis, Structural Characterization, and Properties of the Fe4S4X(tBu3P)3 (X = Cl, Br, I) and Fe4S4(SPh)2(tBu3P)2 Cubanes
Marni A. Tyson, Konstantinos D. Demadis, and Dimitri Coucouvanis
pp 4519 - 4520; DOI:
10.1021/ic00122a002
PDF
Divalent Lanthanide Chemistry: Three Synthetic Routes to Samarium(II) and Ytterbium(II) Bis(phosphido) Species Including the Structural Characterization of Yb[PPh2]2(thf)4 and Sm[PPh2]2(N-MeIm)4
Gerd W. Rabe, Glenn P. A. Yap, and Arnold L. Rheingold
pp 4521 - 4522; DOI:
10.1021/ic00122a003
PDF
The Dianion of nido-Decaborane(14), nido-Dodecahydrodecaborate(2-), [B10H122-], and Its Solution Behavior
Adam N. Bridges and Donald F. Gaines
pp 4523 - 4524; DOI:
10.1021/ic00122a004
PDF
Pentacoordinated Molecules. 107. Axial Preference of a Phenyl Group in a Trigonal Bipyramidal Tetraoxyphosphorane. A Unique Five-Coordinated Geometry
Natalya V. Timosheva, T. K. Prakasha, A. Chandrasekaran, Roberta O. Day, and Robert R. Holmes
pp 4525 - 4526; DOI:
10.1021/ic00122a005
PDF
In-situ FT-IR Spectroelectrochemical Study of the Trinuclear Complex [Ru3(.mu.3-O)(.mu.-CH3COO)6(CO)(pyridine)2] in Acetonitrile
Shen Ye, Hironobu Akutagawa, Kohei Uosaki, and Yoichi Sasaki
pp 4527 - 4528; DOI:
10.1021/ic00122a006
PDF
{CuII[N,N'-bis(2-aminoethyl)-2-(2-(4-pyridyl)ethyl)malondiamido(2-)]}: A Convenient Building Block for the Construction of Supramolecular Coordination Compounds Containing Exchangeable Peripheral CuII Cations
Giancarlo De Santis, Luigi Fabbrizzi, Anna Maria Manotti Lanfredi, Piersandro Pallavicini, Angelo Perotti, Franco Ugozzoli, and Michele Zema
pp 4529 - 4535; DOI:
10.1021/ic00122a007
PDF
Synthesis, Cyclic Voltammetric and Electrospray Mass Spectrometric Studies of a Series of Tris-Substituted 1,2-Dithiolene Complexes of Tungsten and Molybdenum
Polycarpos Falaras, Christine-Anne Mitsopoulou, Dimitris Argyropoulos, Emmanuel Lyris, Nikos Psaroudakis, Ersi Vrachnou, and Dimitris Katakis
pp 4536 - 4542; DOI:
10.1021/ic00122a008
PDF
Kinetics and Mechanism of the Oxidation of HSO3- by O2. 1. The Uncatalyzed Reaction
Robert E. Connick, Yi-Xue Zhang, Shaoyung Lee, Raymond Adamic, and Paul Chieng
pp 4543 - 4553; DOI:
10.1021/ic00122a009
PDF
Comparison of the catalytic reduction of oxygen by [5,10,15,20-tetrakis((pentaammineruthenio(II)-4-pyridyl)porphyrinato]cobalt(II) in solution and on graphite electrode surfaces
Chunnian Shi and Fred C. Anson
pp 4554 - 4561; DOI:
10.1021/ic00122a010
PDF
Kinetics and Mechanism of the Photooxidation of Bis(bipyridine)dichlororuthenium(II) and the Photoreduction of Bis(bipyridine)dichlororuthenium(III) in Chloroform
Sivasorubi Sathiyabalan and Patrick E. Hoggard
pp 4562 - 4571; DOI:
10.1021/ic00122a011
PDF
Inner-Sphere Self-Exchange Electron Transfer in Low-Spin Co(III)-Co(II) Couples. Rate Determinations from 1H-NMR Line Broadening and a Simple Vibronic Model of the Reaction Coordinate
Carolyn L. Schwarz and John F. Endicott
pp 4572 - 4580; DOI:
10.1021/ic00122a012
PDF
Synthesis and Characterization of Tetraethylammonium and 1,4-Dimethylpyridinium Antimony(III) Bis-dmit Complexes
Solange M. S. V. Doidge-Harrison, John T. S. Irvine, Gavin M. Spencer, James L. Wardell, Ma Wei, Paolo Ganis, and Giovanni Valle
pp 4581 - 4584; DOI:
10.1021/ic00122a013
PDF
Near-Infrared Luminescence Spectroscopy of Cobaltocene Doped into Single Crystals of Ruthenocene
Martin J. Davis and Christian Reber
pp 4585 - 4590; DOI:
10.1021/ic00122a014
PDF
Electronic Spectroscopy of Chloro(terpyridine)platinum(II)
James A. Bailey, Michael G. Hill, Richard E. Marsh, Vincent M. Miskowski, William P. Schaefer, and Harry B. Gray
pp 4591 - 4599; DOI:
10.1021/ic00122a015
PDF
Strong Metal-Metal Coupling in a Dinuclear Terpyridinebipyridineruthenium Mixed-Valence Complex Incorporating the Bridging Ligand 1,4-Dicyanamidobenzene Dianion
Ali R. Rezvani, Christopher E. B. Evans, and Robert J. Crutchley
pp 4600 - 4604; DOI:
10.1021/ic00122a016
PDF
Spin Distribution and Bonding in [Mo(OD2)6]3+
Stephen P. Best, Brian N. Figgis, J. Bruce Forsyth, Philip A. Reynolds, and Philip L. W. Tregenna-Piggott
pp 4605 - 4610; DOI:
10.1021/ic00122a017
PDF
Chromia Pillaring in .alpha.-Zirconium Phosphate: A Structural Investigation Using X-Ray Absorption Spectroscopy
Deborah J. Jones, Jacques Roziere, Pedro Maireles-Torres, Antonio Jimenez-Lopez, Pascual Olivera-Pastor, Enrique Rodriguez-Castellon, and Anthony A. G. Tomlinson
pp 4611 - 4617; DOI:
10.1021/ic00122a018
PDF
Chiral Discrimination of Complexes with D3 Symmetry. Synthesis and Characterization of Tris{O,O'-bis[(+)(S)-2-methylbutyl] dithiophosphato}chromium(III) Complexes (.LAMBDA..DELTA.){Cr[(+)(S)(S)Mebdtp]3} and .LAMBDA.-(-)589-, and .DELTA.-(+)589{Cr[(+)(S)(S)Mebdtp]3} and Crystal Packing of Racemic Tris{O,O'-diethyl dithiophosphato}chromium(III), Cr[ddtp]3
Paolo Biscarini, Roberto Franca, and Reiko Kuroda
pp 4618 - 4626; DOI:
10.1021/ic00122a019
PDF
A Novel Dimanganese(III) Complex with a Single Hydroxo Bridge. Syntheses, Structures, and Magnetic Susceptibilities of (.mu.-Hydroxo)bis((octaethylporphinato)manganese(III)) Perchlorate and a Monomeric Precursor, Aquo(octaethylporphinato)manganese(III) Perchlorate
Beisong Cheng, Fabio Cukiernik, Pascal H. Fries, Jean-Claude Marchon, and W. Robert Scheidt
pp 4627 - 4639; DOI:
10.1021/ic00122a020
PDF
Early-Time Dynamics and Reactivity of Polyoxometalate Excited States. Identification of a Short-Lived LMCT Excited State and a Reactive Long-Lived Charge-Transfer Intermediate following Picosecond Flash Excitation of [W10O32]4- in Acetonitrile
Dean C. Duncan, Thomas L. Netzel, and Craig L. Hill
pp 4640 - 4646; DOI:
10.1021/ic00122a021
PDF
A New Family of Quaternary, Early Rare-Earth Chalcogenides: Ca4(RE)2In4Q13 (RE = La, Nd, Sm, Gd; Q = S, Se)
James D. Carpenter and Shiou-Jyh Hwu
pp 4647 - 4651; DOI:
10.1021/ic00122a022
PDF
Hydroalumination of 1,4-Diazabut-1-enes and 4-Lithio-1,4-diazabut-1-enes: Synthesis of Amidoaluminum Hydride, Lithium Aluminum Hydride, and Lithium Diamidoaluminum Hydride Complexes
Michael G. Gardiner, Stacey M. Lawrence, and Colin L. Raston
pp 4652 - 4659; DOI:
10.1021/ic00122a023
PDF
Polyiron(III)-Alkoxo Clusters: a Novel Trinuclear Complex and Its Relevance to the Extended Lattices of Iron Oxides and Hydroxides
A. Caneschi, A. Cornia, A. C. Fabretti, D. Gatteschi, and W. Malavasi
pp 4660 - 4668; DOI:
10.1021/ic00122a024
PDF
Saturation Magnetization Magnetic Circular Dichroism Spectroscopy of Systems with Positive Zero-Field Splittings: Application to FeSiF6.cntdot.6H2O
Cecelia Campochiaro, Elizabeth G. Pavel, and Edward I. Solomon
pp 4669 - 4675; DOI:
10.1021/ic00122a025
PDF
Chromium Tricarbonyl Catecholate Derivatives. Structural and Reactivity Studies of "16-Electron" Complexes
Donald J. Darensbourg, Kevin K. Klausmeyer, and Joseph H. Reibenspies
pp 4676 - 4681; DOI:
10.1021/ic00122a026
PDF
Dinuclear Manganese(II) Complexes with the {Mn2(.mu.-carboxylato)2}2+ Core and Their Transformation to (.mu.-Oxo)bis(.mu.-carboxylato)dimanganese(III) Complexes
Tomoaki Tanase and Stephen J. Lippard
pp 4682 - 4690; DOI:
10.1021/ic00122a027
PDF
Enantioselective Oxidation of Racemic Phosphines with Chiral Oxoruthenium Porphyrins and Crystal Structure of [5,10,15,20-Tetrakis[o-((2-methoxy-2-phenyl-3,3,3- trifluoropropanoyl)amino)phenyl]porphyrinato](carbonyl)(tetrahydrofuran) ruthenium(II) (.alpha.,.beta.,.alpha.,.beta. Isomer)
Paul Le Maux, Hassan Bahri, Gerard Simonneaux, and Loic Toupet
pp 4691 - 4697; DOI:
10.1021/ic00122a028
PDF
Hydrazide Derivatives of Gallium
Deborah A. Neumayer, Alan H. Cowley, Andreas Decken, Richard A. Jones, Vikas Lakhotia, and John G. Ekerdt
pp 4698 - 4700; DOI:
10.1021/ic00122a029
PDF

Issue 19


Multiple Bonds between Transition Metals and Main-Group Elements. 145. Coordination Chemistry of Dirhenium Heptaoxide: Covalent Adducts and "Ionic Perrhenyl-Perrhenates"
Wolfgang A. Herrmann, Peter W. Roesky, Fritz E. Kuehn, Martina Elison, Georg Artus, Wolfgang Scherer, Carlos C. Romao, Andre Lopes, and Jean-Marie Basset
pp 4701 - 4707; DOI:
10.1021/ic00123a001
PDF
Syntheses, Structures, and Properties of [Mn2(.mu.-O)2(.mu.-O2CCH3)(fac-bpea)2](ClO4)2 and Two Halide-Ligated Dioxo-Bridged Dimers Derived Therefrom: [Mn2(.mu.-O)2X2(mer-bpea)2](ClO4)2 (X = F, Cl)
Samudranil Pal, Marilyn M. Olmstead, and William H. Armstrong
pp 4708 - 4715; DOI:
10.1021/ic00123a002
PDF
Carbonyl Derivatives of Chloride-Dimethyl Sulfoxide-Ruthenium(III) Complexes: Synthesis, Crystal Structure, and Reactivity of [(DMSO)2H][trans-RuCl4(DMSO-O)(CO)] and mer,cis-RuCl3(DMSO-O)2(CO)
E. Alessio, M. Bolle, B. Milani, G. Mestroni, P. Faleschini, S. Geremia, and M. Calligaris
pp 4716 - 4721; DOI:
10.1021/ic00123a003
PDF
Carbonyl Derivatives of Chloride-Dimethyl Sulfoxide-Ruthenium(II) Complexes: Synthesis, Structural Characterization, and Reactivity of Ru(CO)x(DMSO)4-xCl2 Complexes (x = 1-3)
E. Alessio, B. Milani, M. Bolle, G. Mestroni, P. Faleschini, F. Todone, S. Geremia, and M. Calligaris
pp 4722 - 4734; DOI:
10.1021/ic00123a004
PDF
X-ray Structures and Redox Properties of Copper(II) Bis(pyrazole) Complexes
Constantinus F. Martens, Albertus P. H. J. Schenning, Martinus C. Feiters, Harry W. Berens, Johannes G. M. van der Linden, Gert Admiraal, Paul T. Beurskens, Huub Kooijman, Anthony L. Spek, and Roeland J. M. Nolte
pp 4735 - 4744; DOI:
10.1021/ic00123a005
PDF
Transition-Metal Complexes with Sulfur Ligands. 112. Synthesis and Characterization of Ruthenium Complexes with [RuPS2N2] Cores. Substitution, Redox and Acid-Base Reactions of [RuII(L)(PR3)('S2N2H2')], (L = CO, PPr3, R = Pr or Cy) and Five-Coordinate [RuIV(PCy3)('S2N2')]
Dieter Sellmann, Richard Ruf, Falk Knoch, and Matthias Moll
pp 4745 - 4755; DOI:
10.1021/ic00123a006
PDF
Synthesis and Characterization of New Dinuclear Complexes (CO)5MnRe(CO)3(L) (L = 2,2'-Bipyrimidine, 2,3-Bis(2-pyridyl)pyrazine) and Trinuclear Compounds (CO)5MnRe(CO)3(L)R (R = Re(Br)(CO)3, W(CO)4). Evidence for Asymmetric Distortion of the Bridging 2,2'-Bipyrimidine Ligand (L) in (CO)5MnRe(CO)3(L)Re(Br)(CO)3 from the Crystal Structure and 1H-NMR and Resonance Raman Spectra
J. W. M. van Outersterp, D. J. Stufkens, J. Fraanje, K. Goubitz, and A. Vlcek
pp 4756 - 4766; DOI:
10.1021/ic00123a007
PDF
Synthesis and Structure Determination of (hfac)Ag(SEt2), Pd(hfac-C)(hfac-O,O)(SEt2), and [(hfac)Ag]4(SEt2): Ligand Exchange Reactions Relevant to Aerosol-Assisted Chemical Vapor Deposition (AACVD) of Ag1-xPdx Films
Chongying Xu, Mark J. Hampden-Smith, Toivo T. Kodas, Eileen N. Duesler, Arnold L. Rheingold, and Glenn Yap
pp 4767 - 4773; DOI:
10.1021/ic00123a008
PDF
Syntheses, Crystal Structures, and Properties of New Layered Alkali-Metal Molybdenum(VI) Methylphosphonates: Cs2(MoO3)3PO3CH3 and Rb2(MoO3)3PO3CH3
William T. A. Harrison, Laurie L. Dussack, and Allan J. Jacobson
pp 4774 - 4779; DOI:
10.1021/ic00123a009
PDF
New Approach to Cofacially Assembled Partially Oxidized Metal Phthalocyanine Low Dimensional Solids: Synthesis, Structure, and Electrical Conductivity Properties of the Fe(IV) Containing Species [(PcFe)2C](I3)0.66 Obtained by I2 Doping of .mu.-Carbido-bis[phthalocyaninatoiron(IV)]
A. M. Paoletti, G. Pennesi, G. Rossi, and C. Ercolani
pp 4780 - 4784; DOI:
10.1021/ic00123a010
PDF
The hexagonal prism shaped cluster [W2Ag4S8(AsPh3)4]: synthesis, crystal structure, and nonlinear optical properties
Genta Sakane, Takashi Shibahare, Hong W. Hou, Xin Q. Xin, and Shu Shi
pp 4785 - 4789; DOI:
10.1021/ic00123a011
PDF
An oxalate-linked copper(II) coordination polymer, [Cu2(oxalate)2(pyrazine)3]n, constructed with two different copper units: x-ray crystallographic and electronic structures
Susumu Kitagawa, Takashi Okubo, Satoshi Kawata, Mitsuru Kondo, Motomi Katada, and Hisayoshi Kobayashi
pp 4790 - 4796; DOI:
10.1021/ic00123a012
PDF
Multinuclear NMR, Raman, EXAFS, and X-ray diffraction studies of uranyl carbonate complexes in near-neutral aqueous solution. X-ray structure of [C(NH2)3]6[(UO2)3(CO3)6].cntdot.6.5H2O
P. G. Allen, J. J. Bucher, D. L. Clark, N. M. Edelstein, S. A. Ekberg, J. W. Gohdes, E. A. Hudson, N. Kaltsoyannis, W. W. Lukens, and et al.
pp 4797 - 4807; DOI:
10.1021/ic00123a013
PDF
Intramolecular Ferromagnetism in a Novel Hexanuclear (.mu.-Hydroxo)(.mu.-carbonato)copper(II) Bipyridine Complex. Structure of [Cu6(bpy)10(.mu.-CO3)2(.mu.-OH)2](ClO4)6.cntdot.4H2O and of a Dinuclear .mu.-Carbonato Complex [Cu2(bpy)4(.mu.-CO3)](PF6)2.cntdot.2DMF
Paul E. Kruger, Gary D. Fallon, Boujemaa Moubaraki, Kevin J. Berry, and Keith S. Murray
pp 4808 - 4814; DOI:
10.1021/ic00123a014
PDF
The Ligand Cage Effect in Volumes of Activation for Electron Transfer Reactions of Cobalt(III/II) Complexes in Aqueous Solution
Richard D. Shalders and Thomas W. Swaddle
pp 4815 - 4820; DOI:
10.1021/ic00123a015
PDF
Intramolecular Donor-Site Exchange Processes in Square-Pyramidal Nickel(II) Complexes Containing Five Arsenic Donors
Michael G. Fitzpatrick, Lyall R. Hanton, and David A. McMorran
pp 4821 - 4827; DOI:
10.1021/ic00123a016
PDF
Di-, Tri-, and Tetranucleating Pyridyl Ligands Which Facilitate Multicenter Magnetic Exchange between Paramagnetic Molybdenum Centers
Angelo J. Amoroso, Alexander M. W. Cargill Thompson, John P. Maher, Jon A. McCleverty, and Michael D. Ward
pp 4828 - 4835; DOI:
10.1021/ic00123a017
PDF
Steric and Electronic Effects on the 103Rh NMR Shifts of (COD)Rh(phosphine) Complexes
Cornelis J. Elsevier, Bernd Kowall, and Hans Kragten
pp 4836 - 4839; DOI:
10.1021/ic00123a018
PDF
Cyclic Silylhydrazines and Their Borane Adducts
Norbert W. Mitzel, Matthias Hofmann, Klaus Angermaier, Annette Schier, Paul von Rague Schleyer, and Hubert Schmidbaur
pp 4840 - 4845; DOI:
10.1021/ic00123a019
PDF
Poly(pyrazolyl)germanium(II) and -Tin(II) Derivatives-Tuneable Monoanionic Ligands and Dinuclear Cationic Cages
Alexander Steiner and Dietmar Stalke
pp 4846 - 4853; DOI:
10.1021/ic00123a020
PDF
Synthesis and Characterization of Group 13 and 15 Selenolates and Tellurolates and the x-ray Crystal Structures of Ga[TeSi(SiMe3)3]3, In[SeC(SiMe3)3]3, {In[SeSi(SiMe3)3]3}2(.mu.-DMPE), and P[SeSi(SiMe3)3]3
Stephen P. Wuller, Allen L. Seligson, Gregory P. Mitchell, and John Arnold
pp 4854 - 4861; DOI:
10.1021/ic00123a021
PDF
Dissolution of Lanthanide and Actinide Metals Using Iodine and 2-Propanol. Synthesis and x-ray Crystal Structures of LnI3(HO-i-Pr)4 (Ln = La, Ce) and Th2I4(O-i-Pr)4(HO-i-Pr)2
David M. Barnhart, Tracey M. Frankcom, Pamela L. Gordon, Nancy N. Sauer, Julie A. Thompson, and John G. Watkin
pp 4862 - 4867; DOI:
10.1021/ic00123a022
PDF
Electronic spectra, optical activity, and crystal-field energy-level structure of Dy3+ in trigonal Na3[Dy(oda)3].cntdot.2NaClO4.cntdot.6H2O crystals
David H. Metcalf, Todd A. Hopkins, and F. S. Richardson
pp 4868 - 4878; DOI:
10.1021/ic00123a023
PDF
Optical Spectra and Electronic State Structure of Dy3+ in Hexagonal Na3[Yb1-xDyx(dpa)3].cntdot.NaClO4.cntdot.10H2O Crystals
Todd A. Hopkins, David H. Metcalf, and F. S. Richardson
pp 4879 - 4887; DOI:
10.1021/ic00123a024
PDF
Cleavage of the Nb:O Bond of Oxoniobium(V) Porphyrins. Synthesis and Characterization of Novel Niobium(V) Porphyrins with Two Distinct Catechols
Masato Kurihara, Noriyuki Katoh, Takahiko Kojima, Yoichi Ishii, and Yoshihisa Matsuda
pp 4888 - 4895; DOI:
10.1021/ic00123a025
PDF
Structures, Electronic Properties, and Oxidation-Reduction Reactivity of Halogenated Iron Porphyrins
Mark W. Grinstaff, Michael G. Hill, Eva R. Birnbaum, William P. Schaefer, Jay A. Labinger, and Harry B. Gray
pp 4896 - 4902; DOI:
10.1021/ic00123a026
PDF
Synthesis and Magnetic Properties of a Tetranuclear Copper(II) Complex with a .mu.-1,2,3,4-Squarato Coordination Mode. Crystal Structure of (.mu.-1,2,3,4-Squarato)tetrakis[(tris(2-aminoethyl)amine)copper(II)] Perchlorate
Isabel Castro, Jorunn Sletten, Maria Luisa Calatayud, Miguel Julve, Juan Cano, Francesc Lloret, and Andrea Caneschi
pp 4903 - 4909; DOI:
10.1021/ic00123a027
PDF
Synthesis, Characterization, Spectroscopy, and Magnetism of Dinuclear Azido- and Alkoxo-Bridged Copper(II) Complexes of Bis(2-benzimidazolyl)alkanes. X-ray Structures of [Cu2(tbz)2(CH3O)2](ClO4)2(CH3OH)2, [Cu2(tbz)2(NO3)(CH3O)2](NO3)(CH3OH)2, and [Cu(tbz)(N3)2]2(CH3OH)2 (tbz = Bis(2-benzimidazolyl)propane)
Gerard A. Van Albada, Miles T. Lakin, Nora Veldman, Anthony L. Spek, and Jan Reedijk
pp 4910 - 4917; DOI:
10.1021/ic00123a028
PDF
Molecular Structure and Magnetic Properties of Acetato-Bridged Lanthanide(III) Dimers
Athanassios Panagiotopoulos, Theodoros F. Zafiropoulos, Spyros P. Perlepes, Evangelos Bakalbassis, Isabelle Masson-Ramade, Olivier Kahn, Aris Terzis, and Catherine P. Raptopoulou
pp 4918 - 4920; DOI:
10.1021/ic00123a029
PDF
Complexation of the potentially heptadentate ligand H3dha3tren with lanthanides: architecture of a [Nd(NO3)3(H3dha3tren)]n polymer with profuse modes of nitrate coordination
Li-Wei Yang, Shuang Liu, Steven J. Rettig, and Chris Orvig
pp 4921 - 4925; DOI:
10.1021/ic00123a030
PDF
A New Three Dimensional Crystal Structure of a Cadmium Thiolate
Tobias Vossmeyer, Guenter Reck, Lynne Katsikas, Erhard T. K. Haupt, Burkhard Schulz, and Horst Weller
pp 4926 - 4929; DOI:
10.1021/ic00123a031
PDF
A Tripod Ligand with Three Different "Legs" and Some Chiral Zinc Complexes Thereof. [Erratum to document cited in CA122:329108]
Ahmed Abufarag and Heinrich Vahrenkamp
pp 4930 - 4930; DOI:
10.1021/ic00123a032
PDF

Issue 20


Syntheses and Crystal Structures of Two Heterobimetallic Polymeric Cluster Complexes [WS4Ag.cntdot.NH3C(CH2OH)3.cntdot.2DMF]n (Single Chain) and [WS4Ag.cntdot.NH3C(CH2OH)3.cntdot.H2O]n (Double Chain)
Qun Huang, Xintao Wu, Tianulu Sheng, and Quanming Wang
pp 4931 - 4932; DOI:
10.1021/ic00124a001
PDF
CO-Labilizing Ability of the Fluoride Ligand in Tungsten(0) Carbonyl Fluorides. X-ray Structure of [Et4N]3[W2(CO)6F3]
Donald J. Darensbourg, Kevin K. Klausmeyer, and Joseph H. Reibenspies
pp 4933 - 4934; DOI:
10.1021/ic00124a002
PDF
Lattice Energies of Crystals with Multiple Ions: A Generalized Kapustinskii Equation
Leslie Glasser
pp 4935 - 4936; DOI:
10.1021/ic00124a003
PDF
Anaerobic Photoinduced N7-Binding of cis-Dichlorobis(1,10-phenanthroline)rhodium(III) Chloride to 2'-Deoxyguanosine: A One-Electron-Transfer Chain Process
Herbert L. Harmon and Harry Morrison
pp 4937 - 4938; DOI:
10.1021/ic00124a004
PDF
Excess Enthalpy of Formation in the FeTiO3-Fe2O3 System: Insights via the Ionic Model
Jeremy K. Burdett, Nolan T. Flynn, and Stephen A. Gramsch
pp 4939 - 4942; DOI:
10.1021/ic00124a005
PDF
Thermodynamic Calculations for Reactions Involving Hydrogen Halide Polymers, Ions and Lewis Acid Adducts. 1. Polyfluorohydrogenate(1-) Anions (HnFn+1-), Polyfluorohydrogen(I) Cations (Hn+1Fn+), and Hydrogen Fluoride Polymers (HF)n
W. David Chandler, Keith E. Johnson, and John L. E. Campbell
pp 4943 - 4949; DOI:
10.1021/ic00124a006
PDF
90Mo NMR and kinetic studies of peroxomolybdic intermediates involved in the catalytic disproportionation of hydrogen peroxide by molybdate ions
V. Nardello, J. Marko, G. Vermeersch, and J. M. Aubry
pp 4950 - 4957; DOI:
10.1021/ic00124a007
PDF
Molecular Recognition by the Protonated Hexaaza Macrocyclic Ligand 3,6,9,16,19,22-Hexaaza-27,28-dioxatricyclo[22.2.1.111,14]octacosa-1(26),11,13,24-tetraene
Qin Lu, Ramunas J. Motekaitis, Joseph J. Reibenspies, and Arthur E. Martell
pp 4958 - 4964; DOI:
10.1021/ic00124a008
PDF
Structures and Spectroscopic Properties of Gold(I) Complexes of 1,3,5-Triaza-7-phosphaadamantane (TPA). 2. Multiple-State Emission from (TPA)AuX (X = Cl, Br, I) Complexes
Zerihun Assefa, Brian G. McBurnett, Richard J. Staples, and John P. Fackler
pp 4965 - 4972; DOI:
10.1021/ic00124a009
PDF
Proton-Coupled Electron-Transfer Reactions in [MnIV2(.mu.-O)3L'2]2+ (L' = 1,4,7-Trimethyl- 1,4,7-triazacyclononane)
Ronald Hage, Bert Krijnen, Johann B. Warnaar, Frantisek Hartl, Derk J. Stufkens, and Theo L. Snoeck
pp 4973 - 4978; DOI:
10.1021/ic00124a010
PDF
Antiferromagnetic interactions in charge-transfer salts of molybdocene dithiolene complexes: the example of [Cp2Mo(dddt)][TCNQ]
Marc Fourmigue, Christine Lenoir, Claude Coulon, Fabrice Guyon, and Jacques Amaudrut
pp 4979 - 4985; DOI:
10.1021/ic00124a011
PDF
Two New One-Dimensional Antiferromagnetic Nickel(II) Complexes Bridged by Azido Ligands in Cis Positions. Effect of the Counteranion on the Magnetic Properties
Joan Ribas, Montserrat Monfort, Carmen Diaz, Carles Bastos, Christine Mer, and Xavier Solans
pp 4986 - 4990; DOI:
10.1021/ic00124a012
PDF
Synthesis, Crystal Structure, Electronic Structure, and Magnetic Properties of In2ThBr6
Richard Dronskowski
pp 4991 - 4995; DOI:
10.1021/ic00124a013
PDF
Syntheses and Cadmium-113 NMR Studies of Five-Coordinate Complexes with CdN5, CdN3O2, and CdN3S2 Central Cores. Solid State Structures of [HB(3-Phpz)3]Cd[H2B(3,5-Me2pz)2] and [HB(3,5-Me2pz)3]Cd[S2CN(Et)2] (pz = Pyrazolyl)
Daniel L. Reger, Sheila M. Myers, Scott S. Mason, Arnold L. Rheingold, Brian S. Haggerty, and Paul D. Ellis
pp 4996 - 5002; DOI:
10.1021/ic00124a014
PDF
Cleft Reactivity in Skeletally-Stabilized Cyclotetraphosphazanes
Susan M. Young, Joseph M. Barendt, Vasili Carperos, R. Curtis Haltiwanger, Robert M. Hands, and Arlan D. Norman
pp 5003 - 5012; DOI:
10.1021/ic00124a015
PDF
Synthesis, Structure, and Magnetic Properties of a Novel Mixed-Valence Copper(I/II) Phosphate, Cu2PO4
Kristen M. S. Etheredge and Shiou-Jyh Hwu
pp 5013 - 5016; DOI:
10.1021/ic00124a016
PDF
Synthesis, Structure, and Bonding of Butterfly Clusters Containing .mu.4-Oxo and .mu.4-Sulfido Ligands: [(PPh3)2N][Fe3M(CO)12(.mu.4-E)] (E = O, S; M = Mn, Re)
Cynthia K. Schauer, Suzanne Harris, Michal Sabat, Eric J. Voss, and Duward F. Shriver
pp 5017 - 5028; DOI:
10.1021/ic00124a017
PDF
Condensation of Keggin Anions Containing Chromium(III) and Aluminum(III), Respectively. 1. Synthesis and X-ray Structural Determination of [{A-.alpha.-SiO4W9O30(OH)3Cr3}2(OH)3]11-
Knut Wassermann, Rosemarie Palm, Hans-Joachim Lunk, Joachim Fuchs, Norbert Steinfeldt, and Reinhard Stoesser
pp 5029 - 5036; DOI:
10.1021/ic00124a018
PDF
Synthesis and Reactions of Alkali Metal Derivatives of the Ph4P2N4S22- Dianion: X-ray Structure of Cp*Rh(.eta.3-Ph4P2N4S2-N,S,S')
Tristram Chivers, Mark Edwards, Xiaoliang Gao, Robert W. Hilts, Masood Parvez, and Rainer Vollmerhaus
pp 5037 - 5041; DOI:
10.1021/ic00124a019
PDF
K18Tl20Au3, A Novel Derivative of K8Tl11 with the Unprecedented Polyanion Tl9Au29-, the Parent Tl117- and an Isolated Au- Ion
Zhen-Chao Dong and John D. Corbett
pp 5042 - 5048; DOI:
10.1021/ic00124a020
PDF
Synthesis, Isolation and Chemistry of Perfluorinated Difluorocarbimides: Precursors to New Perfluorinated Tetrazanes
Burkhard Krumm, Robert L. Kirchmeier, and Jean'ne M. Shreeve
pp 5049 - 5054; DOI:
10.1021/ic00124a021
PDF
Halogenation at a Dimolybdenum(V) and Ditungsten(V) Sulfur Bridge: Metallosulfenyl Halides M2(.mu.-SX) and [M2(.mu.-SX3)]n. Charge-Transfer Interactions
June Q. Lee, Michael L. Sampson, John F. Richardson, and Mark E. Noble
pp 5055 - 5064; DOI:
10.1021/ic00124a022
PDF
Formation of Methoxy-Modified Interlayer Surface via the Reaction between Methanol and Layered Perovskite HLaNb2O7.cntdot.xH2O
Shun Takahashi, Teruyuki Nakato, Shigenobu Hayashi, Yoshiyuki Sugahara, and Kazuyuki Kuroda
pp 5065 - 5069; DOI:
10.1021/ic00124a023
PDF
2,2'-Biphosphinines and 1,4-Diphosphadienes as 8-Electron Donors toward Manganese Carbonyl
Pascal Le Floch, Nicole Maigrot, Louis Ricard, Claude Charrier, and Francois Mathey
pp 5070 - 5072; DOI:
10.1021/ic00124a024
PDF
Separation of the Rotational Isomers of Tetrakis(N-Methyl-2-pyridiniumyl)porphyrin and the Crystal Structure of .alpha.,.alpha.,.alpha.,.beta.-(Tetrakis(N-methyl-2-pyridiniumyl)porphyrin)copper Hexacyanoferrate
Tai Kaufmann, Bernard Shamsai, Roy Song Lu, Robert Bau, and Gordon M. Miskelly
pp 5073 - 5079; DOI:
10.1021/ic00124a025
PDF
Syntheses and Crystal and Molecular Structures of the Hexakis(N,N-dimethylformamide) Complexes of Ruthenium(II) and Ruthenium(III)
Robert J. Judd, Renhai Cao, Margret Biner, Thomas Armbruster, Hans-Beat Buergi, Andre E. Merbach, and Andreas Ludi
pp 5080 - 5083; DOI:
10.1021/ic00124a026
PDF
Synthesis of Heavy Metal Ion Selective Calix[4]arenes Having Sulfur Containing Lower-Rim Functionalities
Alex T. Yordanov, Joel T. Mague, and D. Max Roundhill
pp 5084 - 5087; DOI:
10.1021/ic00124a027
PDF
Transformations of Selenium-Iron Carbonylates in Hieber's Synthesis: Isolation of a Novel Intermediate Complex, [PhCH2NMe3]2[Se6Fe6(CO)12]
Minghuey Shieh, Mei-Huey Shieh, Yi-Chou Tsai, and Chuen-Her Ueng
pp 5088 - 5090; DOI:
10.1021/ic00124a028
PDF
Synthesis and x-ray Structural Studies on a New Class of Pentanuclear Copper(II) Complexes Containing a [Cu5(.mu.3-OH)2(.mu.-O2CMe)6]2+ Core and Terminal Imidazole Ligands
Shanmugam Meenakumari, Muthuvijayan Lakshminarayanan, Satish K. Tiwary, and Akhil R. Chakravarty
pp 5091 - 5093; DOI:
10.1021/ic00124a029
PDF
Luminescence and circularly polarized luminescence of optically active [RhIII(diamine)3]3+ complexes: conformation in the luminescent excited states
Taro Tsubomura, Sonoko Morishita, Hiroshi Andoh, and Makoto Morita
pp 5094 - 5096; DOI:
10.1021/ic00124a030
PDF
X-ray structure determination and magnetic behavior of the new uniform S = 1 chain [{Ni(Me2[14]-1,3-dieneN4)(.mu.-N3)}n](ClO4)n. Magneto-structural correlations. [Erratum to document cited in CA123:46276]
Ramon Vicente, Albert Escuer, Joan Ribas, M. Salah El Fallah, Xavier Solans, and Merce Font-Bardia
pp 5096 - 5096; DOI:
10.1021/ic00124a031
PDF

Issue 21


The First Complex with an M3Te7 Cluster Core: Synthesis and Molecular and Crystal Structure of Cs4.5[Mo3(.mu.3-Te)(.mu.2-Te2)3(CN)6]I2.5.cntdot.3H2O
Vladimir P. Fedin, Hideo Imoto, Taro Saito, William McFarlane, and A. Geoffrey Sykes
pp 5097 - 5098; DOI:
10.1021/ic00125a001
PDF
Vanadium(IV) Complexes of an Active-Site Peptide of a Protein Tyrosine Phosphatase
Charles R. Cornman, Edward P. Zovinka, and Molly H. Meixner
pp 5099 - 5100; DOI:
10.1021/ic00125a002
PDF
Synthesis and Characterization of the New Selenometalate Anion [Ir(Se4)3]3-
Thomas E. Albrecht-Schmitt, Jason A. Cody, Joseph T. Hupp, and James A. Ibers
pp 5101 - 5102; DOI:
10.1021/ic00125a003
PDF
Synthesis and Characterization of Tetrakis(trihalogermyl)methanes. Molecules Containing Sterically Strained Carbon Centers
Phillip T. Matsunaga, John Kouvetakis, and Thomas L. Groy
pp 5103 - 5104; DOI:
10.1021/ic00125a004
PDF
Preparation and Crystal Structure of the Nitridosilicates Ln3Si6N11 (Ln = La, Ce, Pr, Nd, Sm) and LnSi3N5 (Ln = Ce, Pr, Nd)
Michael Woike and Wolfgang Jeitschko
pp 5105 - 5108; DOI:
10.1021/ic00125a005
PDF
Mo K-edge EXAFS and S K-edge absorption studies of the amorphous molybdenum sulfides MoS4.7, MoS3, and MoS3.cntdot.nH2O (n .apprx. 2)
Simon J. Hibble, David A. Rice, David M. Pickup, and Michael P. Beer
pp 5109 - 5113; DOI:
10.1021/ic00125a006
PDF
Preparation and Study of Decavanadate-Pillared Hydrotalcite-like Anionic Clays Containing Transition Metal Cations in the Layers. 1. Samples Containing Nickel-Aluminum Prepared by Anionic Exchange and Reconstruction
F. Kooli, V. Rives, and M. A. Ulibarri
pp 5114 - 5121; DOI:
10.1021/ic00125a007
PDF
Preparation and Study of Decavanadate-Pillared Hydrotalcite-like Anionic Clays Containing Transition Metal Cations in the Layers. 2. Samples containing Magnesium-Chromium and Nickel-Chromium
F. Kooli, V. Rives, and M. A. Ulibarri
pp 5122 - 5128; DOI:
10.1021/ic00125a008
PDF
Chemistry of Iron with Dipicolinic Acid. 1. Mononuclear Complexes of Iron(II) or Iron(III)
P. Laine, A. Gourdon, and J.-P. Launay
pp 5129 - 5137; DOI:
10.1021/ic00125a009
PDF
Chemistry of Iron with Dipicolinic Acid. 2. Bridging Role of Carboxylate Groups in Solid State Structures
P. Laine, A. Gourdon, and J.-P. Launay
pp 5138 - 5149; DOI:
10.1021/ic00125a010
PDF
Chemistry of Iron with Dipicolinic Acid. 3. Heptacoordinated Iron in [(dipicH)2FeII(OH2)] and [(dipic)2FeII2(OH2)6].cntdot.2dipicH2
P. Laine, A. Gourdon, J.-P. Launay, and J.-P. Tuchagues
pp 5150 - 5155; DOI:
10.1021/ic00125a011
PDF
Chemistry of Iron with Dipicolinic Acid. 4. Mixed-Ligand Complexes of Iron(III) and Related Compounds
P. Laine, A. Gourdon, and J.-P. Launay
pp 5156 - 5165; DOI:
10.1021/ic00125a012
PDF
Iodine-Iodine Interactions in Dialkyldiiodophosphonium Iodides and Triiodides
Volkmar Stenzel, Joerg Jeske, Wolf-Walther du Mont, and Peter G. Jones
pp 5166 - 5170; DOI:
10.1021/ic00125a013
PDF
A New Type of Coordination in Copper(I) Complexes with Trivalent Phosphorus Compounds Containing Phosphorus-Sulfur Bonds
Olga N. Kataeva, Igor A. Litvinov, Viktor A. Naumov, Lydiya I. Kursheva, and Elvira S. Batyeva
pp 5171 - 5174; DOI:
10.1021/ic00125a014
PDF
Isotropic and Anisotropic Magnetic Exchange Interactions through .mu.-N1,N2 1,2,4-Triazole and .mu.-Sulfato Bridges: X-ray Crystal Structure, Magnetic Properties, and Single-Crystal EPR Study of (.mu.-4-Amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole-N',N1,N2,N'')(.mu.-sulfato-O,O')[(sulfato-O)aquacopper(II)]triaquacopper(II) Hydrate
Petra J. van Koningsbruggen, Dante Gatteschi, Rudolf A. G. de Graaff, Jaap G. Haasnoot, Jan Reedijk, and Claudia Zanchini
pp 5175 - 5182; DOI:
10.1021/ic00125a015
PDF
Photochemistry and Emission of the Dinuclear Complexes (CO)5MnRe(CO)3(L) (L = 2,2'-Bipyrimidine, 2,3-Bis(2-pyridyl)pyrazine) and Bridged Trinuclear Complexes (CO)5MnRe(CO)3(L)Re(Br)(CO)3 and (CO)5MnRe(CO)3(BPYM)W(CO)4: Effect of the Remote Metal Center on the Photodissociation of the Mn-Re Bond
J. W. M. van Outersterp, D. J. Stufkens, and A. Vlcek
pp 5183 - 5194; DOI:
10.1021/ic00125a016
PDF
Synthesis and Structure of Ca6MnN5: A New Nitridomanganate with Planar [MnN3]6- Anions
D. H. Gregory, M. G. Barker, P. P. Edwards, and D. J. Siddons
pp 5195 - 5198; DOI:
10.1021/ic00125a017
PDF
Oxidative Metal-Metal Bond Cleavage in Tp2Ru2(CO)4 (Tp = Hydridotris(pyrazolyl)borate)
Morten Sorlie and Mats Tilset
pp 5199 - 5204; DOI:
10.1021/ic00125a018
PDF
Metallic Complexation by Inner and Outer Nitrogens of Bis(diazine) Heterocycles: The Cases of 4,4'-Bipyrimidine and 2,2'-Bipyrazine
F. Bodar-Houillon, T. Humbert, A. Marsura, J.-B. Regnouf de Vains, O. Dusausoy, N. Bouhmaida, N. E. Ghermani, and Y. Dusausoy
pp 5205 - 5209; DOI:
10.1021/ic00125a019
PDF
Temperature Dependent Emission Properties of Rhenium(I) Tricarbonyl Complexes Containing Alkyl- and Aryl-Substituted Phenanthrolines as Ligands
Lynne Wallace, Donald C. Jackman, D. Paul Rillema, and Jon W. Merkert
pp 5210 - 5214; DOI:
10.1021/ic00125a020
PDF
New synthetic routes to B-halogenated derivatives of cobalt dicarbollide
Paul K. Hurlburt, Rebecca L. Miller, Kent D. Abney, Trudi M. Foreman, Raymond J. Butcher, and Scott A. Kinkhead
pp 5215 - 5219; DOI:
10.1021/ic00125a021
PDF
One Step Closer to Structural Models for HDS Catalysts: Thienyl-Oxo Complexes of Re(V)
Philip R. Stafford, Thomas B. Rauchfuss, and Scott R. Wilson
pp 5220 - 5225; DOI:
10.1021/ic00125a022
PDF
Dimolybdenum(II) Calixarene Complexes: Synthesis, Structure, Raman Spectroscopy, and Bonding
Jacqueline A. Acho, Tong Ren, Joanne W. Yun, and Stephen J. Lippard
pp 5226 - 5233; DOI:
10.1021/ic00125a023
PDF
Surface and Electrostatic Contributions to DNA-Promoted Reactions of Platinum(II) Complexes with Short Oligonucleotides: A Kinetic Study
Sofi K. C. Elmroth and Stephen J. Lippard
pp 5234 - 5243; DOI:
10.1021/ic00125a024
PDF
Ethylene Glycolate Derivatives of Aluminum: Tetra-, Penta-, and Hexacoordination
Graeme J. Gainsford, Tim Kemmitt, and Neil B. Milestone
pp 5244 - 5251; DOI:
10.1021/ic00125a025
PDF
Structural and Magnetic Studies of Manganese(II) Complexes of the Imidazole-Containing Ligand 5-NO2-salimH [5-NO2-salimH2 = 4-(2-((5-nitrosalicylidene)amino)ethyl)imidazole] with Varying Nuclearity
Michael J. Baldwin, Jeff W. Kampf, Martin L. Kirk, and Vincent L. Pecoraro
pp 5252 - 5260; DOI:
10.1021/ic00125a026
PDF
The Te(OTeF5)5- and FTe(OTeF5)4- Anions: Synthesis, X-ray Structure Determinations, and Raman Spectra of Te(OTeF5)4 and N(CH3)4+Te(OTeF5)5- and Solution Characterization of the FTe(OTeF5)4- and Te(OTeF5)5- Anions by 19F and 125Te NMR Spectroscopy
Helene P. A. Mercier, Jeremy C. P. Sanders, and Gary J. Schrobilgen
pp 5261 - 5273; DOI:
10.1021/ic00125a027
PDF
Reaction of 1,2-Dehydro-o-carborane with Acetylenes. Synthesis and Structure of a Carborane Analog of Benzocyclobutadiene
Douglas M. Ho, Rebecca J. Cunningham, Judson A. Brewer, Nanying Bian, and Maitland Jones
pp 5274 - 5278; DOI:
10.1021/ic00125a028
PDF
Synthesis and Characterization of Thiolato-Bridged Titanium-Platinum and -Palladium Heterobinuclear Complexes. Molecular Structure of [(.eta.5-C5H4SiMe3)2Ti(.mu.-SPh)2Pd(C6F5)2]
Ulises Amador, Esther Delgado, Juan Fornies, Elisa Hernandez, Elena Lalinde, and M. Teresa Moreno
pp 5279 - 5284; DOI:
10.1021/ic00125a029
PDF
Transition Metal Stannyl Complexes. 9. Reactivity of Li[Cp2M(SnPh3)] toward Metal Halides
Steffen Seebald, Brigitte Mayer, and Ulrich Schubert
pp 5285 - 5288; DOI:
10.1021/ic00125a030
PDF
Unusual Iron(IV) Complexes: Metal Atom Syntheses and Studies of (.eta.6-arene)Fe(H)2(SiCl3)2 (Arene = Benzene, Toluene, p-Xylene)
Zhengui Yao, Kenneth J. Klabunde, and A. Sam Asirvatham
pp 5289 - 5294; DOI:
10.1021/ic00125a031
PDF
Synthesis and Characterization of the First Group 2 Mixed .beta.-Diketonate Alkoxide Complexes. X-ray Crystal Structures of [Ca4(tmhd)4(OEt)4(EtOH)4], [Ca4(tmhd)6(OCH2CH2NMe2)2], and [H2Ba4(tmhd)6(OCH2CH2OPri)4]
V-Cumaran Arunasalam, Ian Baxter, Simon R. Drake, Michael B. Hursthouse, K. M. Abdul Malik, and David J. Otway
pp 5295 - 5306; DOI:
10.1021/ic00125a032
PDF
Solution Chemistry of Chalcohalide Hexanuclear Rhenium Cluster Monoanions: Substitution Reactions and Structural and LSIMS Characterization of the Heterosubstituted Cluster Dianions, (n-Bu4N)2[Re6Q5ECl8] (Q = S, E = O, S, Se; Q = Se, E = S, Se, Te)
Santiago Uriel, Kamal Boubekeur, Patrick Batail, Jesus Orduna, and Enric Canadell
pp 5307 - 5313; DOI:
10.1021/ic00125a033
PDF
Origin of Different Coordination Polyhedra for Cu[CF3C(O)CHC(O)CF3]2L (L = H2O, NH3)
Jirri Pinkas, John C. Huffman, Malcolm H. Chisholm, and Kenneth G. Caulton
pp 5314 - 5318; DOI:
10.1021/ic00125a034
PDF
Monomeric Nickel(II) Amido Complexes. Synthesis, Reactivity, and Dynamics
Daniel D. VanderLende, Khalil A. Abboud, and James M. Boncella
pp 5319 - 5326; DOI:
10.1021/ic00125a035
PDF
Lanthanide-Group 12 Metal Chalcogenolates: A Versatile Class of Compounds
M. Berardini, T. J. Emge, and J. G. Brennan
pp 5327 - 5334; DOI:
10.1021/ic00125a036
PDF
Coordination Chemistry of Tropolone-Based Antimitotic Drugs and the Antineoplastic Behavior of Some Ruthenium(II) and Platinum(II) Derivatives
Jeffrey B. Helms, Ling Huang, Reyn Price, B. Patrick Sullivan, and Beverly A. Sullivan
pp 5335 - 5340; DOI:
10.1021/ic00125a037
PDF
First Reported Aqueous Phosphoester Bond Cleavage Promoted by an Organometallic Complex
Louis Yi Kuo, Samuel Kuhn, and Dan Ly
pp 5341 - 5345; DOI:
10.1021/ic00125a038
PDF
New Ferrous Complexes Based on the 2,2'-Biimidazole Ligand: Structural, Moessbauer, and Magnetic Properties of [FeII(bimH2)2(CH3OH)2](OAc)2, [FeII(bimH2)3]CO3, [FeII(bimH)2]n, and {FeII(bim)}n
Maria Angeles Martinez Lorente, Francoise Dahan, Vasili Petrouleas, Azzedine Bousseksou, and Jean-Pierre Tuchagues
pp 5346 - 5357; DOI:
10.1021/ic00125a039
PDF
Electronic, Magnetic, Redox, and Ligand-Binding Properties of [MFe3S4] Clusters (M = Zn, Co, Mn) in Pyrococcus furiosus Ferredoxin
Michael G. Finnegan, Richard C. Conover, Jae-Bum Park, Zhi Hao Zhou, Michael W. W. Adams, and Michael K. Johnson
pp 5358 - 5369; DOI:
10.1021/ic00125a040
PDF
Determination of the Self-Exchange Rate Constant for Rusticyanin from Thiobacillus ferrooxidans and a Comparison with Values for Other Type 1 Blue Copper Proteins
Panayotis Kyritsis, Christopher Dennison, W. John Ingledew, William McFarlane, and A. Geoffrey Sykes
pp 5370 - 5374; DOI:
10.1021/ic00125a041
PDF
Photodissociation and Photoinduced Electron Detachment in Dinuclear Metal Carbonyl Anions
Brian T. Cooper, Jane A. Johnson, and Steven W. Buckner
pp 5375 - 5377; DOI:
10.1021/ic00125a042
PDF
Phosphido Complexes of the Lanthanides. Synthesis and x-ray Crystal Structure Determination of a Tris(phosphido) Species of Neodymium: Nd[P(SiMe3)2]3(thf)2
Gerd W. Rabe and Joseph W. Ziller
pp 5378 - 5379; DOI:
10.1021/ic00125a043
PDF
Copper(I) Carbonyl Complex of a Trifluoromethylated Tris(pyrazolyl)borate Ligand
H. V. Rasika Dias and Hui-Ling Lu
pp 5380 - 5382; DOI:
10.1021/ic00125a044
PDF
Molecule-Based Magnets: Ferro- and Antiferromagnetic Interactions in Nickel(II) Cyclohexasiloxanolate Sandwich Complexes
Andrea Cornia, Antonio C. Fabretti, Dante Gatteschi, Gyula Palyi, Eva Rentschler, Olga I. Shchegolikhina, and Alexandr A. Zhdanov
pp 5383 - 5387; DOI:
10.1021/ic00125a045
PDF
Molecular Structure of Dimeric Magnesium Phenyl Phosphatosulfate
Mitsunori Izumi, Kazuhiko Ichikawa, Mamoru Suzuki, Isao Tanaka, and Krzysztof W. Rudzinski
pp 5388 - 5389; DOI:
10.1021/ic00125a046
PDF
Coordination Complexes of Bis(triphenylphosphine) Copper(I) Carbonate and Bicarbonate
Donald J. Darensbourg, Matthew W. Holtcamp, Bandana Khandelwal, and Joseph H. Reibenspies
pp 5390 - 5394; DOI:
10.1021/ic00125a047
PDF
Dinuclear Metal Carbonyls Bridged by Pyridyl Ligands Incorporating an Alkyne Entity.[Erratum to document cited in CA122:254682]
Jiann T. Lin, Shih-Sheng Sun, Jiann Jung Wu, Liangshiu Lee, Kuan-Jiuh Lin, and Yi Fong Huang
pp 5394 - 5394; DOI:
10.1021/ic00125a048
PDF

Issue 22


Synthesis and x-ray Structure of [H3O+.cntdot.18-crown-6][I7-]. A New Infinite Sawhorse Geometry for I7- Crystallized from a Liquid Clathrate Medium
Peter C. Junk, Leonard R. MacGillivray, Michael T. May, Kerry D. Robinson, and Jerry L. Atwood
pp 5395 - 5396; DOI:
10.1021/ic00126a001
PDF
Cu4(AsO4)2(O): A New Copper Arsenate with Unusual Low Temperature Magnetic Properties
Richard D. Adams, Ralph Layland, and Christophe Payen
pp 5397 - 5398; DOI:
10.1021/ic00126a002
PDF
Ruthenium Formyl Complexes as the Branch Point in Two- and Multi-Electron Reductions of CO2
Kiyotsuna Toyohara, Hirotaka Nagao, Tetsunori Mizukawa, and Koji Tanaka
pp 5399 - 5400; DOI:
10.1021/ic00126a003
PDF
Complex Multinary Compounds from Molten Alkali Metal Polyselenophosphate Fluxes. Layers and Chains in A4Ti2(P2Se9)2(P2Se7) and ATiPSe5 (A = K, Rb). Isolation of [P2Se9]4-, a Flux Constituent Anion
Konstantinos Chondroudis and Mercouri G. Kanatzidis
pp 5401 - 5402; DOI:
10.1021/ic00126a004
PDF
A Crystalline [H9O4]+ Hydronium Ion Salt with a Weakly Coordinating Anion
Zuowei Xie, Robert Bau, and Christopher A. Reed
pp 5403 - 5404; DOI:
10.1021/ic00126a005
PDF
Stereoselective Formation of the R,S Isomer of a Methylene-Bridged Diphosphine Derivative of p-tert-Butylcalix[4]arene and Subsequent Reactivity
Igor Shevchenko, Hongming Zhang, and Michael Lattman
pp 5405 - 5409; DOI:
10.1021/ic00126a006
PDF
Silver(I)-Selective Thioether Ligands. Solution NMR and X-ray Structural Studies on the Interaction of 2,5,8-Trithia[9]-m-cyclophane and Related Ligands with Silver(I)
Jaume Casabo, Teresa Flor, M. N. Stuart Hill, Hilary A. Jenkins, Joyce C. Lockhart, Stephen J. Loeb, Isobel Romero, and Francesc Teixidor
pp 5410 - 5415; DOI:
10.1021/ic00126a007
PDF
Solution Study of the Ambient Temperature Monomer-Dimer Equilibrium Th2(OR)8 .dblharw. 2Th(OR)4 (R = CH-i-Pr2) and X-ray Crystal Structures of Th2(OCH-i-Pr2)8, Th(OCH-i-Pr2)4(quin), and ThI(OCH-i-Pr2)3(py)2
David M. Barnhart, David L. Clark, John C. Gordon, John C. Huffman, John G. Watkin, and Bill D. Zwick
pp 5416 - 5423; DOI:
10.1021/ic00126a008
PDF
An Efficient Reduction Process Leading to Titanium(II) and Niobium(II): Preparation and Structural Characterization of trans-MCl2(py)4 Compounds, M = Ti, Nb, and Mn
Miguel A. Araya, F. Albert Cotton, John H. Matonic, and Carlos A. Murillo
pp 5424 - 5428; DOI:
10.1021/ic00126a009
PDF
Synthesis of Amphiphilic Metal Organics Using p-Monothiohydroquinolate, an Ambidentate Ligand That Bears a Hard and a Soft Donor. One- and Two-Dimensional Solid-State Structures of Fe2(CO)6(.mu.-SC6H4-4-OH)2.cntdot.nSolv (Solv = C6H6, n = 1; Solv = HSC6H4-4-OH, n = 2)
Michael T. Ashby
pp 5429 - 5436; DOI:
10.1021/ic00126a010
PDF
New Organometallic Heteronuclear .mu.-Oxo Complexes. X-ray Structure of [Cp*3Ti3Cl(.mu.-O2SO2)](.mu.-O)3.cntdot.C6H5CH3
Angel Abarca, Avelino Martin, Miguel Mena, and Paul R. Raithby
pp 5437 - 5440; DOI:
10.1021/ic00126a011
PDF
Platinum-Assisted C-C Bond Formation. Synthesis of Platinum Imidoyl Phosphorus Ylide Complexes and the First Crystal Structure of an Imidoyl Phosphorus Ylide Complex
Jose Vicente, Maria-Teresa Chicote, Maria-Cristina Lagunas, and Peter G. Jones
pp 5441 - 5445; DOI:
10.1021/ic00126a012
PDF
Structure, Physical and Photophysical Properties, and Charge Separation Studies of Re(bpm)(CO)3Ln+ Complexes (L = CH3CN, py, MeQ+, py-PTZ)
Randy J. Shaver, Marc W. Perkovic, D. Paul Rillema, and Clifton Woods
pp 5446 - 5454; DOI:
10.1021/ic00126a013
PDF
Synthesis, Characterization, and Molecular Orbital Analysis of [Et4N]2[(OC)5MoAsMo3(CO)9(.mu.3-OR)3Mo(CO)3] (R = Me, Et). X-ray Structure of [Et4N]2[(OC)5MoAsMo3(CO)9(.mu.3-OMe)3Mo(CO)3].cntdot.0.6thf
Jaap W. van Hal, Kenton H. Whitmire, Bachir Zouchoune, Jean-Francois Halet, and Jean-Yves Saillard
pp 5455 - 5460; DOI:
10.1021/ic00126a014
PDF
Reactivity of Deprotonated Mn2(.mu.-H)(.mu.-PCyH)(CO)8: Selective Monoauration to Mn2(.mu.-AuPR3)(.mu.-PCyH)(CO)8 and Mn2(.mu.-H)(.mu.3-PCy(AuPR3))(CO)8 (R = Cy, Ph, p-C6H4F, p-C6H4OMe) and Kinetic Studies of their Conversion
H.-J. Haupt, M. Schwefer, H. Egold, and U. Floerke
pp 5461 - 5467; DOI:
10.1021/ic00126a015
PDF
Ammoniacal Synthesis of Lanthanum Aryloxide Complexes and Observation of a Unique Interconversion between Oxygen- and .eta.-Arene-Bridged Dimeric Species. X-ray Crystal Structures of La2(OAr)6(NH3)n (n = 0, 2), La(OAr)3(NH3)4, and La(OAr)3(THF)2 (Ar = 2,6-i-Pr2C6H3)
Raymond J. Butcher, David L. Clark, Steven K. Grumbine, Rebecca L. Vincent-Hollis, Brian L. Scott, and John G. Watkin
pp 5468 - 5476; DOI:
10.1021/ic00126a016
PDF
Novel Volatile Azatranes of Group 4 Metals
Zhibang Duan, Ahmad A. Naiini, Jong-Hwan Lee, and John G. Verkade
pp 5477 - 5482; DOI:
10.1021/ic00126a017
PDF
Transition Metal Chemistry of Main Group Hydrazides. Part 16: (Phosphanyl)hydrazines R2PN(Me)N(Me)PR2 As a Novel Class of Chelating Bis(phosphines). Synthesis, Coordination Chemistry, and X-ray Structures of cis-[PdCl2{(p-BrC6H4O)2PN- (Me)N(Me)P(OC6H4Br-p)2}] and cis-[W(CO)4{(PhO)2PN(Me)N(Me)P(OPh)2}]
V. Streenivasa Reddy, Kattesh V. Katti, and Charles L. Barnes
pp 5483 - 5488; DOI:
10.1021/ic00126a018
PDF
Chemistry in Interphases: Chemical Exchange in a Polysiloxane-Bound Chlorohydridotris(ether-phosphine)ruthenium(II) Complex. An Investigation by Solid-State NMR Spectroscopy
Ekkehard Lindner, Martin Kemmler, Theodor Schneller, and Hermann A. Mayer
pp 5489 - 5495; DOI:
10.1021/ic00126a019
PDF
TEM Study of the Misfit Intercalation Compounds .alpha.-Hg1.19TaS2 and .beta.-Hg1.3TaS2
P. Moreau, P. Ganal, A. M. Marie, and G. Ouvrard
pp 5496 - 5500; DOI:
10.1021/ic00126a020
PDF
Synthesis, Crystal Structure, Optical and Magnetic Properties of a Novel Two-Dimensional Copper(II) Network formed conjointly with .mu.-Bipyrimidine, .mu.-Oxalato, and .mu.-Chloro Ligands
Silvio Decurtins, Helmut W. Schmalle, Philippe Schneuwly, Li-Min Zheng, Juergen Ensling, and Andreas Hauser
pp 5501 - 5506; DOI:
10.1021/ic00126a021
PDF
Hexanuclear and Dodecanuclear Macrocyclic Copper(II) and Nickel(II) Complexes with Almost Planar "Benzene-like" Metal Arrays
Santokh S. Tandon, Laurence K. Thompson, J. N. Bridson, and Cristiano Benelli
pp 5507 - 5515; DOI:
10.1021/ic00126a022
PDF
Interpretation of the Temperature Dependence of the EPR Spectrum of Cu2+-Doped (NH4)2[Cd(NH3)2(CrO4)2] and Crystal Structures of the High- and Low-Temperature Forms of the Host Lattice
Henrietta Headlam, Michael A. Hitchman, Horst Stratemeier, Jan M. M. Smits, Paul T. Beurskens, Engbert de Boer, Gerrit Janssen, Bryan M. Gatehouse, Glen B. Deacon, Greg N. Ward, Mark J. Riley, and Deming Wang
pp 5516 - 5523; DOI:
10.1021/ic00126a023
PDF
Main Group Element Size and Substitution Effects on the Structural Dimensionality of Zirconium Tellurides of the ZrSiS Type
Chwanchin Wang and Timothy Hughbanks
pp 5524 - 5529; DOI:
10.1021/ic00126a024
PDF
Ferromagnetic Exchange through Unoccupied Bridging Ligand Orbitals. Optical Spectroscopic Investigation of .mu.-1,1-Azido Copper(II) Dimers
Ingo von Seggern, Felix Tuczek, and Wolfgang Bensch
pp 5530 - 5547; DOI:
10.1021/ic00126a025
PDF
ESR Study of Reduced Monosubstituted Ruthenium(II) Diimine Complexes
Alan C. Samuels and M. Keith DeArmond
pp 5548 - 5551; DOI:
10.1021/ic00126a026
PDF
ESR Characterization of the Organic Superconducting Salts of the BEDT-TTF Donor Molecule with the Novel Organometallic Anion [Cu(CF3)4]- [BEDT-TTF = Bis(ethylenedithio)tetrathiafulvalene]
H. Hau Wang, John A. Schlueter, Urs Geiser, Jack M. Williams, D. Naumann, and T. Roy
pp 5552 - 5557; DOI:
10.1021/ic00126a027
PDF
EPR Study of S = 2 and S = 3 States of Fe-O-Fe Dimers in Na4[Fe(edta)]2O.cntdot.3H2O and {[Fe(phen)2]2O}(NO3)4.cntdot.7H2O. X-ray Structure Determination of Na4[Fe(edta)]2O.cntdot.3H2O
Andrzej Ozarowski, Bruce R. McGarvey, and John E. Drake
pp 5558 - 5566; DOI:
10.1021/ic00126a028
PDF
Synthesis of New Types of Dithiolene Ligands
Zong-Qiang Tian, James P. Donahue, and R. H. Holm
pp 5567 - 5572; DOI:
10.1021/ic00126a029
PDF
Luminescence spectra of single crystals of Cs2ZrCl6:UO2Cl42- at low temperatures. vibronic structure of UO22+ doped in a cubic host
David H. Metcalf, Sheng Dai, G. D. Del Cul, and L. M. Toth
pp 5573 - 5577; DOI:
10.1021/ic00126a030
PDF
Optical Spectroscopy of Single Crystal [Re(bpy)(CO)4](PF6): Mixing between Charge Transfer and Ligand Centered Excited States
Geoffrey F. Strouse, Hans U. Guedel, Valerio Bertolasi, and Valeria Ferretti
pp 5578 - 5587; DOI:
10.1021/ic00126a031
PDF
Effect of Coordination Environment on the Electronic Structure and Properties of Mo6-Based Systems: A Density Functional Treatment
L. M. Robinson, R. L. Bain, D. F. Shriver, and D. E. Ellis
pp 5588 - 5596; DOI:
10.1021/ic00126a032
PDF
Properties and Stabilities of MX, MX2, and M2X2 Compounds (M = Zn, Cd, Hg; X = F, Cl, Br, I)
Meng-sheng Liao, Qian-er Zhang, and W. H. Eugen Schwarz
pp 5597 - 5605; DOI:
10.1021/ic00126a033
PDF
A functional model for carbonic anhydrase: thermodynamic and kinetic study of a tetraazacyclododecane complex of zinc(II)
Xiaoping Zhang and Rudi van Eldik
pp 5606 - 5614; DOI:
10.1021/ic00126a034
PDF
Perturbation of the Racemic Equilibrium between D3 Lanthanide Complexes through the Addition of Sugars
Ewa Huskowska and James P. Riehl
pp 5615 - 5621; DOI:
10.1021/ic00126a035
PDF
Synthesis and Ligational Properties of Two New Binucleating Oxa-Aza Macrocyclic Receptors
Carla Bazzicalupi, Andrea Bencini, Antonio Bianchi, Vieri Fusi, Piero Paoletti, Gianna Piccardi, and Barbara Valtancoli
pp 5622 - 5631; DOI:
10.1021/ic00126a036
PDF
Solution Chemistry and Crystal Structure of Nickel Tetrakis(2,3,5,6-tetrafluoro-N,N,N-trimethyl-4-aniliniumyl)porphyrin Trifluoromethanesulfonate (NiTF4TMAP(CF3SO3)4)
Timothy La, Rosalie A. Richards, Roy S. Lu, Robert Bau, and Gordon M. Miskelly
pp 5632 - 5640; DOI:
10.1021/ic00126a037
PDF
Synthesis, X-ray Structure, and Dynamic Behavior of a Scandium-Oxacalix[3]arene Complex
Charles E. Daitch, Philip D. Hampton, and Eileen N. Duesler
pp 5641 - 5645; DOI:
10.1021/ic00126a038
PDF
Preparation, Crystal Structures, and Properties of the Acetate-Bridged Platinum(III) Compounds [{(H2O)Pt(.mu.-CH3CO2)2}2]A2 (A- = ClO4-, CF3SO3-)
Trevor G. Appleton, Karl A. Byriel, Jodie M. Garrett, John R. Hall, Colin H. L. Kennard, Michael T. Mathieson, and Robert Stranger
pp 5646 - 5655; DOI:
10.1021/ic00126a039
PDF
Simultaneous First- and Second-Sphere Coordination. Organopalladium Metalloreceptors for Water, Ammonia, Amines, Hydrazine, and the Hydrazinium Ion
James E. Kickham and Stephen J. Loeb
pp 5656 - 5665; DOI:
10.1021/ic00126a040
PDF
Factors Determining the Ligand Field Stabilization Energies of the Hexaaqua 2+ Complexes of the First Transition Series and the Irving-Williams Order
David A. Johnson and Peter G. Nelson
pp 5666 - 5671; DOI:
10.1021/ic00126a041
PDF
Solvent Exchange Kinetics and Proton Relaxation in Solutions of Cobalt(II) Dioximes
K. Wang and R. B. Jordan
pp 5672 - 5679; DOI:
10.1021/ic00126a042
PDF
Influences of pH and Ionic Strength on Aqueous Vanadate Equilibria
Alan S. Tracey, Jaswinder S. Jaswal, and Sarah J. Angus-Dunne
pp 5680 - 5685; DOI:
10.1021/ic00126a043
PDF
Improved synthesis of 2,2-bis(fluoroxy)perfluoropropane.
Alessandro Zedda and Darryl D. Des Marteau
pp 5686 - 5688; DOI:
10.1021/ic00126a044
PDF
Imidazole-Zinc Catalysts for RNA Hydrolysis
Feiya Chu, Joseph Smith, Vincent M. Lynch, and Eric V. Anslyn
pp 5689 - 5690; DOI:
10.1021/ic00126a045
PDF
Disproportionation of Diiron Nonacarbonyl in THF Solution: Formation and Structure of Fe(THF)4[HFe3(CO)11]
David J. R. Brook, Vincent Lynch, and Tad H. Koch
pp 5691 - 5693; DOI:
10.1021/ic00126a046
PDF
Synthesis and Characterization of Primary and Secondary Allenyl- and Alkynylarsines
Laurent Lassalle, Stephanie Legoupy, and Jean-Claude Guillemin
pp 5694 - 5697; DOI:
10.1021/ic00126a047
PDF
2D Polymeric Silver(I) Complexes Consisting of Markedly Undulated Sheets of Squares. X-ray Crystal Structures of [Ag(ppz)2](BF4) and [Ag(pyz)2](PF6) (ppz = Piperazine, pyz = Pyrazine)
Lucia Carlucci, Gianfranco Ciani, Davide M. Proserpio, and Angelo Sironi
pp 5698 - 5700; DOI:
10.1021/ic00126a048
PDF

Issue 23


Synthesis and reactivity of silicon transition metal complexes. 38. Metallo-silanols and siloxanes. 12. C5R5(OC)2(Me3P)M-Substituted silanetriols of molybdenum and tungsten (R = H, Me). Synthesis via oxofunctionalization of metallotrihydridosilanes and transformation into the multifunctionalized metallotetrasiloxane C5Me5(OC)2(Me3P)WSi(OSiMe2H)3
Wolfgang Malisch, Reiner Lankat, Siegfried Schmitzer, and Joachim Reising
pp 5701 - 5702; DOI:
10.1021/ic00127a001
PDF
Metalloporphyrins with X[N2O2]- Ligands. Novel High-Spin (N-Phenyl-N-nitrosohydroxylaminato)(meso-tetraarylporphyrinato)iron(III)
Geun-Bae Yi, Masood A. Khan, and George B. Richter-Addo
pp 5703 - 5704; DOI:
10.1021/ic00127a002
PDF
Synthesis and Structural Characterization of a New Rare-Earth Selenodiphosphate: KLaP2Se6
John H. Chen and Peter K. Dorhout
pp 5705 - 5706; DOI:
10.1021/ic00127a003
PDF
Structure and Magnetic Behavior of a New Two-Dimensional Antiferromagnetic Manganese(II)-.mu.-1,3-Azido System
Albert Escuer, Ramon Vicente, Mohamed A. S. Goher, and Franz A. Mautner
pp 5707 - 5708; DOI:
10.1021/ic00127a004
PDF
Na15K6Tl18H: A Remarkable Hydrogen-Stabilized Zintl Phase with Isolated (Tl6H)7- and (Tl12Na)13- Polyanions
Zhen-Chao Dong and John D. Corbett
pp 5709 - 5710; DOI:
10.1021/ic00127a005
PDF
Carboxylates of Organotitanium Fluorides: Preparation of Cp- and Cp*- Titanium fluoro Trifluoroacetates and Pentafluorobenzoates
Judith Gindl, Feng-Quan Liu, Mathias Noltemeyer, Hans-Georg Schmidt, and Herbert W. Roesky
pp 5711 - 5714; DOI:
10.1021/ic00127a006
PDF
Reactions of Singlet Oxygen with Organometallic Complexes. 3. Kinetics and Scope of the Oxidative Addition Reaction of Singlet Oxygen with Iridium(I), Rhodium(I), and Platinum(II) Complexes
Matthias Selke, William L. Karney, Saeed I. Khan, and Christopher S. Foote
pp 5715 - 5720; DOI:
10.1021/ic00127a007
PDF
New Mixed-Metal Carbonyl Tellurido Clusters from Solvothermal Synthesis
Birinchi K. Das and Mercouri G. Kanatzidis
pp 5721 - 5725; DOI:
10.1021/ic00127a008
PDF
Functional and Structural Model for the Molybdenum-Pterin Binding Site in Dimethyl Sulfoxide Reductase. Synthesis, Crystal Structure, and Spectroscopic Investigations of Trichloro(quinoid-N(8)H-6,7-dihydropterin)oxomolybdenum(IV)
Berthold Fischer, Helmut Schmalle, Erich Dubler, Andrea Schaefer, and Max Viscontini
pp 5726 - 5734; DOI:
10.1021/ic00127a009
PDF
Synthesis, Tuning of the Stereochemistry, and Physical Properties of Cobalt(II) Tropocoronand Complexes
B. Scott Jaynes, Linda H. Doerrer, Shuncheng Liu, and Stephen J. Lippard
pp 5735 - 5744; DOI:
10.1021/ic00127a010
PDF
Synthesis and Characterization of Vanadium(II,III,IV) Complexes of Pyridine-2-thiolate
John G. Reynolds, Shawn C. Sendlinger, Ann M. Murray, John C. Huffman, and George Christou
pp 5745 - 5752; DOI:
10.1021/ic00127a011
PDF
Noble Metal (RuIII, PdII, PtII) Substituted "Sandwich" Type Polyoxometalates: Preparation, Characterization, and Catalytic Activity in Oxidations of Alkanes and Alkenes by Peroxides
Ronny Neumann and Alexander M. Khenkin
pp 5753 - 5760; DOI:
10.1021/ic00127a012
PDF
Vanadium(II) Salts in Pyridine and Acetonitrile Solvents
Phalguni Ghosh, Henry Taube, Tai Hasegawa, and Reiko Kuroda
pp 5761 - 5775; DOI:
10.1021/ic00127a013
PDF
Tris(oxalato) Complexes of Silicon as Precursors to Porous Silicate Materials: Synthesis and Structure
Kenneth J. Balkus, Irina S. Gabrielova, and Simon G. Bott
pp 5776 - 5780; DOI:
10.1021/ic00127a014
PDF
Solubilities of Copper(II) and Chromium(III) .beta.-Diketonates in Supercritical Carbon Dioxide
Anthony F. Lagalante, Brian N. Hansen, Thomas J. Bruno, and Robert E. Sievers
pp 5781 - 5785; DOI:
10.1021/ic00127a015
PDF
Structural Variations in Hexanuclear Ruthenium Clusters with Thioureato Ligands: Syntheses and Molecular Structures of [Ru6(CO)14(.mu.-CO)2(.mu.4-S)(.mu.3,.eta.2-SCNHPhNPh)(.mu.3,.eta.2-NPhCNHPh)] and [(.mu.-H)6Ru6(CO)14(.mu.3,.eta.2-SCNHPhNPh)2]
Lisa Hoferkamp, Gerd Rheinwald, Helen Stoeckli-Evans, and Georg Suess-Fink
pp 5786 - 5790; DOI:
10.1021/ic00127a016
PDF
Enantiomerically Pure Chiral RuII(L-L)2 Building Blocks for Coordination Compounds
Xiao Hua and Alex von Zelewsky
pp 5791 - 5797; DOI:
10.1021/ic00127a017
PDF
The nido-Pb94- and the Jahn-Teller Distorted closo-Pb93- Zintl Anions: Syntheses, X-ray Structures, and Theoretical Studies
Janette Campbell, David A. Dixon, Helene P. A. Mercier, and Gary J. Schrobilgen
pp 5798 - 5809; DOI:
10.1021/ic00127a018
PDF
Monocarbonyl Complexes of the Type Re2X4(.mu.-dppm)2(CO) (X = Cl, Br; dppm = Ph2PCH2PPh2) Revisited. Reactions of the Bromo Complex Re2Br4(.mu.-dppm)2(CO) with tert-Butyl and Xylyl Isocyanides
Wengan Wu, Phillip E. Fanwick, and Richard A. Walton
pp 5810 - 5817; DOI:
10.1021/ic00127a019
PDF
Electrochemical Studies of Structurally Related Triply-Bridged Dinuclear Tris(bipyridine)iron(II) Complexes: An Electrostatic Model for Site-Site Interaction
Suzanne Ferrere and C. Michael Elliott
pp 5818 - 5824; DOI:
10.1021/ic00127a020
PDF
NMR Evidence for Interconversion between Two Enantiomeric Forms of Macrocyclic Schiff Base Lanthanide(III) Complexes Through Reversible Ring Contraction and Expansion
S. Aime, M. Botta, U. Casellato, S. Tamburini, and P. A. Vigato
pp 5825 - 5831; DOI:
10.1021/ic00127a021
PDF
Studies of Manganate(V), -(VI), and -(VII) Tetraoxyanions by Pulse Radiolysis. Optical Spectra of Protonated Forms
J. D. Rush and B. H. J. Bielski
pp 5832 - 5838; DOI:
10.1021/ic00127a022
PDF
Oxidation of Chloride Ions by Hydrogen Peroxide, Catalyzed by Methylrhenium Trioxide
Peter J. Hansen and James H. Espenson
pp 5839 - 5844; DOI:
10.1021/ic00127a023
PDF
Theoretical Study of Host.cntdot..cntdot..cntdot.Guest Interactions in Clathrates with a Cd(CN)2 Host
Eliseo Ruiz and Santiago Alvarez
pp 5845 - 5851; DOI:
10.1021/ic00127a024
PDF
Synthetic Manipulation of Excited State Decay Pathways in a Series of Ruthenium(II) Complexes Containing Bipyrazine and Substituted Bipyridine Ligands
Milan Sykora and James R. Kincaid
pp 5852 - 5856; DOI:
10.1021/ic00127a025
PDF
Spectroscopic and Magnetostructural Correlations in Oxo-Bridged Dinuclear Vanadium(III) Complexes of Potential Biological Significance
Marcus R. Bond, Roman S. Czernuszewicz, Bakul C. Dave, Qing Yan, Madan Mohan, Ruben Verastegue, and Carl J. Carrano
pp 5857 - 5869; DOI:
10.1021/ic00127a026
PDF
Tetranuclear, Hexanuclear, and Octanuclear Copper(II) Complexes of a Series of Novel Dendritic Poly(phthalazine) Ligands
Yisheng Zhang, Laurence K. Thompson, John N. Bridson, and Monica Bubenik
pp 5870 - 5877; DOI:
10.1021/ic00127a027
PDF
Reactivity of Glutathione and Cysteine toward Platinum(II) in the Presence and Absence of Guanosine 5'-Monophosphate
Rathindra N. Bose, Shadi Moghaddas, Evelyne L. Weaver, and Elizabeth H. Cox
pp 5878 - 5883; DOI:
10.1021/ic00127a028
PDF
Syntheses, Reactivity and Molecular Structures of RSRS-[Ni(tmc)SC6H5](PF6), RRSS-[Ni(tmc)SC6H5](CF3SO3) and RRSS-[Ni(tmc)](CF3SO3) (tmc = 1,4,8,11-Tetramethyl-1,4,8,11-tetraazacyclotetradecane)
M. S. Ram, Charles G. Riordan, Robert Ostrander, and Arnold L. Rheingold
pp 5884 - 5892; DOI:
10.1021/ic00127a029
PDF
Metrical Comparison and Alkali Metal NMR Spectroscopic Investigation of a Congener Set of Alkali Metalated Titanium(IV) Isopropoxides: X-ray Structures of [NaTi(OCHMe2)5].infin. and [KTi(OCHMe2)5].infin.
Timothy J. Boyle, Donald C. Bradley, Mark J. Hampden-Smith, Anil Patel, and Joseph W. Ziller
pp 5893 - 5899; DOI:
10.1021/ic00127a030
PDF
Syntheses of the Phenylchalcogenolate Complexes (.eta.5-C5Me5)2Zr(EPh)2 (E = O, S, Se, Te) and (.eta.5-C5H5)2Zr(OPh)2: Structural Comparisons within a Series of Complexes Containing Zirconium-Chalcogen Single Bonds
William A. Howard, Tina M. Trnka, and Gerard Parkin
pp 5900 - 5909; DOI:
10.1021/ic00127a031
PDF
Copper(II) and Copper(I) Complexes Stabilized by Phosphine Oxides: Synthesis and Characterization of the Cationic Complexes [Cu(odppf)2(EtOH)]2+, and [Cu(odppf)2]2+ Precursors of the Novel Copper(I) Adduct [Cu(odppf)2]+ (odppf = 1,1'-Bis(oxodiphenylphosphoranyl)ferrocene). Crystal Structure of [Cu(odppf)2(EtOH)](BF4)2 and [Cu(odppf)2](BF4)2
Giuseppe Pilloni, Giovanni Valle, Carlo Corvaja, Bruno Longato, and Benedetto Corain
pp 5910 - 5918; DOI:
10.1021/ic00127a032
PDF
Heterometallic Eu/M(II) Benzenethiolates (M = Zn, Cd, Hg): Synthesis, Structure, and Thermolysis Chemistry
Meggan Brewer, Jongseong Lee, and J. G. Brennan
pp 5919 - 5924; DOI:
10.1021/ic00127a033
PDF
X-ray Crystallographic Structure of a 7-Aza-nido-undecaborane Derivative: (NB2tBu3H)NB10H12
Matthias Mueller, Ulli Englert, and Peter Paetzold
pp 5925 - 5926; DOI:
10.1021/ic00127a034
PDF
Heteropolyagostic Interactions in Lanthanide(III) Diisopropylamido Complexes
William J. Evans, Reiner Anwander, Joseph W. Ziller, and Saeed I. Khan
pp 5927 - 5930; DOI:
10.1021/ic00127a035
PDF

Issue 24


Synthesis and Thermolysis of a Phosphorus(III) Oxalate. Evidence for the Generation of an Arylphosphinidene Oxide
Alan H. Cowley, Francois P. Gabbaie, Siegfried Corbelin, and Andreas Decken
pp 5931 - 5932; DOI:
10.1021/ic00128a001
PDF
A model for the interaction of alcohol with the zinc thiolate site of alcohol dehydrogenase
Steven C. Shoner, Kristi J. Humphreys, David Barnhart, and Julie A. Kovacs
pp 5933 - 5934; DOI:
10.1021/ic00128a002
PDF
Formation and deoxygenation kinetics of oyhemerythrin and oxyhemocyanin. A pressure dependence study
H.-D. Projahn, S. Schindler, R. van Eldik, D. G. Fortier, C. R. Andrew, and A. G. Sykes
pp 5935 - 5941; DOI:
10.1021/ic00128a003
PDF
Nature and Ligation of Vanadium within Whole Blood Cells and Henze Solution from the Tunicate Ascidia ceratodes, As Investigated by Using X-ray Absorption Spectroscopy
Patrick Frank, Kenneth Kustin, William E. Robinson, Linda Linebaugh, and Keith O. Hodgson
pp 5942 - 5949; DOI:
10.1021/ic00128a004
PDF
Dioxomolybdenum(VI) Complexes of Tripodal Nitrogen-Donor Ligands: Syntheses and Spectroscopic, Structural, and Electrochemical Studies, Including the Generation of EPR-Active Molybdenum(V) Species in Solution
Zhiguang Xiao, Michael A. Bruck, Colleen Doyle, John H. Enemark, Carina Grittini, Robert W. Gable, Anthony G. Wedd, and Charles G. Young
pp 5950 - 5962; DOI:
10.1021/ic00128a005
PDF
Transition-Metal Complexes with Sulfur Ligands. 113. Syntheses, X-ray Crystal Structures, and Reactivity of Molybdenum(II) Complexes with Thioetherthiolate Ligands Having XS4 Donor Atom Sets (X = S, O, NH)
Dieter Sellmann, Beate Hadawi, Falk Knoch, and Matthias Moll
pp 5963 - 5972; DOI:
10.1021/ic00128a006
PDF
Near-Infrared Fourier Transform Raman Spectroscopy of B12 Models. 4. Steric and Electronic Factors Affecting the Co-C Bond in Organocobalt Complexes
Manu Chopra, Tom S. M. Hun, Wa-Hung Leung, and Nai-Teng Yu
pp 5973 - 5978; DOI:
10.1021/ic00128a007
PDF
4,4'-Bis(2-picolinimino)-2,2'-bibenzimidazoles: A New Class of Dinucleating Ligands Which Allow for a Tuning of the Metal-Metal Distance. Structures and Properties of a Dicopper(II) Complex and of Two Oxygenation Products of a Dicopper(I) Complex; a Tentative Coordination Chemical Modeling of Hemocyanin
Edgar Muller, Gerald Bernardinelli, and Jan Reedijk
pp 5979 - 5988; DOI:
10.1021/ic00128a008
PDF
Computer-Aided Design of Metallopharmaceuticals: A Molecular Mechanics Force Field for Gadolinium Complexes
Thomas R. Cundari, Eddie W. Moody, and Shaun O. Sommerer
pp 5989 - 5999; DOI:
10.1021/ic00128a009
PDF
Theory of the NMR Paramagnetic Shift of Pseudotetrahedral Complexes of Nickel(II) and Cobalt(II)
Bruce R. McGarvey
pp 6000 - 6007; DOI:
10.1021/ic00128a010
PDF
The Sequence of Ligand Reductions in Heteroleptic Ruthenium-Diimine Complexes: Calculation of Redox Potentials as a Diagnostic Tool
S. Zalis, M. Krejcik, V. Drchal, and A. A. Vlcek
pp 6008 - 6014; DOI:
10.1021/ic00128a011
PDF
Kinetic and Equilibrium Studies of the Reactions of Cysteine and Penicillamine with Aqueous Iron(III)
M. J. Sisley and R. B. Jordan
pp 6015 - 6023; DOI:
10.1021/ic00128a012
PDF
Redox- and Thermally-Induced Nitro-Nitrito Linkage Isomerizations of Ruthenium(II) Complexes Having Nitrosyl as a Spectator Ligand
Dai Ooyama, Noriharu Nagao, Hirotaka Nagao, Yoshimasa Miura, Akiko Hasegawa, Ken-ichi Ando, F. Scott Howell, Masao Mukaida, and Koji Tanaka
pp 6024 - 6033; DOI:
10.1021/ic00128a013
PDF
Uranium(VI)-Catalyzed Photooxidation of Hydrocarbons with Molecular Oxygen
Wei-Dong Wang, Andreja Bakac, and James H. Espenson
pp 6034 - 6039; DOI:
10.1021/ic00128a014
PDF
Reactions of Nitroplatinum Complexes. 2. Reactions of K2[Pt(NO2)4] and Related Complexes with Aqueous Acids (CH3CO2H, HClO4, CF3SO3H, HNO3, and H2SO4): Pathways to Platinum(III) Complexes with Acetate Bridges. Crystal Structure of K2[{Pt(NO2)2(.mu.-CH3CO2)}2].cntdot.H2O
Trevor G. Appleton, Kevin J. Barnham, Karl A. Byriel, John R. Hall, Colin H. L. Kennard, Michael T. Mathieson, and Kerry G. Penman
pp 6040 - 6052; DOI:
10.1021/ic00128a015
PDF
Effect of Conformational Constraints on Gated Electron-Transfer Kinetics. A Multifaceted Study on Copper(II/I) Complexes with cis- and trans-Cyclohexanediyl-[14]aneS4
Cynthia A. Salhi, Qiuyue Yu, Mary Jane Heeg, Nicole M. Villeneuve, Kerri L. Juntunen, Ronald R. Schroeder, L. A. Ochrymowycz, and D. B. Rorabacher
pp 6053 - 6064; DOI:
10.1021/ic00128a016
PDF
Reactions of the Tetrachlorobis(imidazole)ruthenium(III) and Pentachloro(imidazole)ruthenium(III) Anions with Imidazole and N6,N6-Dimethyladenine
Craig Anderson and Andre L. Beauchamp
pp 6065 - 6073; DOI:
10.1021/ic00128a017
PDF
Manganese(II) and Gadolinium(III) Complexes with New 13- and 16-Membered Dioxopolyazacycloalkanes with Pendant Hydroxy and Carboxymethyl Groups
Michiko B. Inoue, Rosa Elena Navarro, Motomichi Inoue, and Quintus Fernando
pp 6074 - 6079; DOI:
10.1021/ic00128a018
PDF
Evidence of Reversible N-H Exchange in a Three-Coordinate Amidozinc Complex. Syntheses and Structures of 1-Methyl-2-((N-tert-butylamino)methyl)benzimidazole Complexes of Zinc
Mitchell S. Chinn and Jiazhong Chen
pp 6080 - 6084; DOI:
10.1021/ic00128a019
PDF
Synthesis of Polyfluoro Aromatic Ethers: A Facile Route Using Polyfluoroalkoxides Generated from Carbonyl and Trimethysilyl Compounds
Masakazu Nishida, Ashwani Vij, Robert L. Kirchmeier, and Jean'ne M. Shreeve
pp 6085 - 6092; DOI:
10.1021/ic00128a020
PDF
Kinetics and Mechanisms of the Oxidation of Hydroxylamine by Aqueous Iodine
Rong Ming Liu, Michael R. McDonald, and Dale W. Margerum
pp 6093 - 6099; DOI:
10.1021/ic00128a021
PDF
Aluminum Derivatives of N-Isopropyl-2-(isopropylamino)troponimine
H. V. Rasika Dias, Wiechang Jin, and Robert E. Ratcliff
pp 6100 - 6105; DOI:
10.1021/ic00128a022
PDF
Synthesis, Reactivity, and Structural Characterization of Octahedral Ruthenium(II) Complexes with Small Molecules Containing Hemilabile Ether-Phosphine Ligands
Ekkehard Lindner, Michael Gepraegs, Karlheinz Gierling, Riad Fawzi, and Manfred Steimann
pp 6106 - 6117; DOI:
10.1021/ic00128a023
PDF
Synthesis and Characterization of Dinuclear Palladium Complexes with Bridging Selenide or Selenoxide Ligands, Including X-ray Characterization of anti-Pd2Cl2(.mu.-Se)(.mu.-dpmMe)2 [dpmMe = 1,1-Bis(diphenylphosphino)ethane]
Gabor Besenyei, Laszlo Parkanyi, Laszlo I. Simandi, and Brian R. James
pp 6118 - 6123; DOI:
10.1021/ic00128a024
PDF
Synthesis, Structure, and Characterization of N-Ligated Tungsten Selenide Cluster Complexes W6Se8L6
Xiaobing Xie and Robert E. McCarley
pp 6124 - 6129; DOI:
10.1021/ic00128a025
PDF
Synthesis and Characterization of K3Mo14O22, K1.66Pb1.34Mo14O22, and K1.29Sn1.71Mo14O22: Oligomeric Clusters with Three Trans Edge-Shared Mo Octahedra
George L. Schimek, S. C. Chen, and Robert E. McCarley
pp 6130 - 6140; DOI:
10.1021/ic00128a026
PDF
Cleavage of Bis(thiophosphinyl)disulfanes, R2P(S)SSP(S)R2 (R = Et, Ph), by a Low-Valent Palladium Dimer
Richard Landtiser, Joel T. Mague, Mark J. Fink, Cristian Silvestru, and Ionel Haiduc
pp 6141 - 6144; DOI:
10.1021/ic00128a027
PDF
Designed Synthesis of Mononuclear Tris(heteroleptic) Ruthenium Complexes Containing Bidentate Polypyridyl Ligands
Peter A. Anderson, Glen B. Deacon, Klaus H. Haarmann, F. Richard Keene, Thomas J. Meyer, David A. Reitsma, Brian W. Skelton, Geoffrey F. Strouse, Nicholas C. Thomas, and et al.
pp 6145 - 6157; DOI:
10.1021/ic00128a028
PDF
Synthesis and Structural Features of N-Mono- and N,N-Bis(trimethylstannyl)acetamide Derivatives
S. Geetha, Maochun Ye, and J. G. Verkade
pp 6158 - 6162; DOI:
10.1021/ic00128a029
PDF
Aryldiazenido Complexes: Syntheses of Iridium Complexes with Doubly-Bent Aryldiazenido Ligands and x-ray Structure of [Cp*Ir(PMe3)2(p-N2C6H4OMe)][BF4]
Grace Chi-Young Kim, Raymond J. Batchelor, Xiaoqian Yan, Frederick W. B. Einstein, and Derek Sutton
pp 6163 - 6172; DOI:
10.1021/ic00128a030
PDF
Manganese(III) Complexes Containing Optically Active Tetradentate Schiff Base Ligands. Effect of Phenyl Substituents
Masakazu Hirotsu, Kiyohiko Nakajima, Masaaki Kojima, and Yuzo Yoshikawa
pp 6173 - 6178; DOI:
10.1021/ic00128a031
PDF
Europium Pyridinethiolates: Synthesis, Structure, and Thermolysis
M. Berardini and J. Brennan
pp 6179 - 6185; DOI:
10.1021/ic00128a032
PDF
Photoreduction of Diaryl Disulfides by Quadruply Bonded Dimolybdenum and Ditungsten Complexes
Tsui-Ling C. Hsu, Sara A. Helvoigt, Colleen M. Partigianoni, Claudia Turro, and Daniel G. Nocera
pp 6186 - 6190; DOI:
10.1021/ic00128a033
PDF
Photooxidation of Matrix-Isolated Nickel Tetracarbonyl in the Presence of Dioxygen
Anthony J. Downs, Tim M. Greene, and Charles M. Gordon
pp 6191 - 6198; DOI:
10.1021/ic00128a034
PDF
Chalcogenospecific Synthesis of 1,2-Se2S6 Using ZnS6(TMEDA)
Atul K. Verma and Thomas B. Rauchfuss
pp 6199 - 6201; DOI:
10.1021/ic00128a035
PDF
Chalcogen Polycations by Oxidation of Elemental Chalcogens with Transition Metal Halides: Synthesis and Crystal Structure of [Se17][WCl6]2
Johannes Beck and Joerg Wetterau
pp 6202 - 6204; DOI:
10.1021/ic00128a036
PDF
Preparation and Properties of New Dinitrogen Osmium(II) Complexes
Gabriele Albertin, Stefano Antoniutti, Daniela Baldan, and Emilio Bordignon
pp 6205 - 6210; DOI:
10.1021/ic00128a037
PDF
Synthesis of Thiolate-Bridged Ruthenium(I) Complexes. The Crystal Structure of [Ru2(.mu.-S2(CH2)3)(CO)4(PPh3)2]
Josep Soler, Josep Ros, M. Rosa Carrasco, Aurora Ruiz, Angel Alvarez-Larena, and Joan F. Piniella
pp 6211 - 6214; DOI:
10.1021/ic00128a038
PDF
Resonance Raman Spectroscopy of Ruthenium(II) and Osmium(II) Polypyridyl Complexes Containing the N-Methyl-4,4'-Bipyridinium Radical (MQ.bul.) as a Ligand: Evidence for a M(d.pi.) .fwdarw. MQ.bul.(.pi.*) Metal-to-Ligand Charge Transfer (MLCT) Transition
W. Douglas Bates, Pingyun Chen, Carlo A. Bignozzi, Jon R. Schoonover, and Thomas J. Meyer
pp 6215 - 6217; DOI:
10.1021/ic00128a039
PDF
KSb2, a New Structure Composed of Ribbons of Edge-Shared Six-Membered Sb Rings
Anette Rehr, Francisco Guerra, Sean Parkin, Haakon Hope, and Susan M. Kauzlarich
pp 6218 - 6220; DOI:
10.1021/ic00128a040
PDF
Chloroxyfluoroxydifluoromethane.
Antonio Russo and Darryl D. DesMarteau
pp 6221 - 6222; DOI:
10.1021/ic00128a041
PDF
Structural Diversity in the Carbamato Chemistry of Zinc: X-ray Single-Crystal Structures of [(Me2NCH2)2Zn(O2CN(C2H5)2)2] and [C5H5NZn2Me(O2CN(C2H5)2)3]
M. Azad Malik, Majid Motevalli, and Paul O'Brien
pp 6223 - 6225; DOI:
10.1021/ic00128a042
PDF
Synthesis and Solid-State Structure of [HB(3,5-Me2pz)3]In(S4)(3,5-Me2pzH) (pz = Pyrazolyl): The First Neutral Indium Polysulfide Complex
Daniel L. Reger and Paul S. Coan
pp 6226 - 6227; DOI:
10.1021/ic00128a043
PDF
27Al and 13C NMR Relaxation Studies in Aminoalanes
Charles L. Watkins, Larry K. Krannich, and Steven J. Schauer
pp 6228 - 6230; DOI:
10.1021/ic00128a044
PDF

Issue 25


Optically Active Transition Metal Complexes. 5. A Novel Type of Optically Active Diketonate Ligand and Its Rhodium Complex
Ulli Englert, Markus Kaeser, and Albrecht Salzer
pp 6231 - 6232; DOI:
10.1021/ic00129a001
PDF
New Thermally Stable and Highly Volatile Precursors for Lanthanum MOCVD: Synthesis and Characterization of Lanthanum .beta.-Diketonate Glyme Complexes
Graziella Malandrino, Rosalia Licata, Francesco Castelli, Ignazio L. Fragala, and Cristiano Benelli
pp 6233 - 6234; DOI:
10.1021/ic00129a002
PDF
A Versatile Preparative Route to 5-Substituted-1,10-Phenanthroline Ligands via 1,10-Phenanthroline 5,6-Epoxide
Yibing Shen and B. Patrick Sullivan
pp 6235 - 6236; DOI:
10.1021/ic00129a003
PDF
Direct Synthesis of Polyoxovanadate-Pillared Layered Double Hydroxides
Fathi Kooli and William Jones
pp 6237 - 6238; DOI:
10.1021/ic00129a004
PDF
Facile Abstraction of Successive Oxygen Atoms from Perchlorate Ions by Methylrhenium Dioxide
Mahdi M. Abu-Omar and James H. Espenson
pp 6239 - 6240; DOI:
10.1021/ic00129a005
PDF
Isolation and Vis-Absorption Spectrum of trans-[Ni(OH2)2(cyclam)]Cl2.cntdot.4H2O
Katsura Mochizuki and Takeshi Kondo
pp 6241 - 6243; DOI:
10.1021/ic00129a006
PDF
Structure of FeI2.cntdot.[16]aneS4: Square-Planar or Octahedral Iron Coordination?
H. Paulsen, M. Kroeckel, M. Grodzicki, E. Bill, A. X. Trautwein, G. J. Leigh, and J. Silver
pp 6244 - 6249; DOI:
10.1021/ic00129a007
PDF
Extraction and Isolation of the [(Zr6B)Cl18]5- Cluster from a Solid State Precursor
Yunchao Tian and Timothy Hughbanks
pp 6250 - 6254; DOI:
10.1021/ic00129a008
PDF
Magnetic Exchange through Oxalate Bridges: Synthesis and Characterization of (.mu.-Oxalato)dimetal(II) Complexes of Manganese, Iron, Cobalt, Nickel, Copper, and Zinc
Jorgen Glerup, Patricia A. Goodson, Derek J. Hodgson, and Kirsten Michelsen
pp 6255 - 6264; DOI:
10.1021/ic00129a009
PDF
Synthesis, 77Se and 119Sn NMR Study, and X-ray Crystal Structure of the Sn4Se104- Anion and Raman Spectra of SnSe44- and Sn4Se104-
Janette Campbell, David P. DiCiommo, Helene P. A. Mercier, Ayaaz M. Pirani, Gary J. Schrobilgen, and Marc Willuhn
pp 6265 - 6272; DOI:
10.1021/ic00129a010
PDF
Magnetism and Electronic Structure of the (Pentamethylcyclopentadienyl)dichlororuthenium Dimer
Ulrich Koelle, Heiko Lueken, Klaus Handrick, Helmut Schilder, Jeremy K. Burdett, and Scarlett Balleza
pp 6273 - 6278; DOI:
10.1021/ic00129a011
PDF
Metallosulfoxides and -sulfones: Sulfur Oxygenates of [1,5-Bis(2-mercaptoethyl)-1,5-diazacyclooctanato]palladium(II)
Thawatchai Tuntulani, Ghezai Musie, Joseph H. Reibenspies, and Marcetta Y. Darensbourg
pp 6279 - 6286; DOI:
10.1021/ic00129a012
PDF
Structure/Function Relationships in Ligand-Based SO2/O2 Conversion to Sulfate As Promoted by Nickel and Palladium Thiolates
Marcetta Y. Darensbourg, Thawatchai Tuntulani, and Joseph H. Reibenspies
pp 6287 - 6294; DOI:
10.1021/ic00129a013
PDF
An Unusual Coordination Mode for Amides: Lone-Pair Binding via Nitrogen
Jesse C. Lee, Beat Mueller, Paul Pregosin, Glenn P. A. Yap, Arnold L. Rheingold, and Robert H. Crabtree
pp 6295 - 6301; DOI:
10.1021/ic00129a014
PDF
Synthesis and Spectroscopy of Coordination Compounds of a Versatile Bridging Ligand. Molecular Structures of the Dinuclear Compounds [Co2(bdnol)(NCS)3], [Zn2(bdnol)Cl(NCS)2], and [Cu2(bdnol)(NO3)3] and of the Polymeric Copper(I) Compound [Cu2(Hbdnol)(NCS)2]
Elisabeth Bouwman, Paul Evans, Rudolf A. G. de Graaff, Huub Kooijman, Richard Poinsot, Pierre Rabu, Jan Reedijk, and Anthony L. Spek
pp 6302 - 6311; DOI:
10.1021/ic00129a015
PDF
Photochemistry of the Clusters Os3(CO)10(L) (L = 2,2'-Bipyridine, 2,2'-Bipyrimidine, 2,3-Dipyrid-2-ylpyrazine, 2,3-Dipyrid-2-ylbenzoquinoxaline). Reversible Opening of an Os-Os Bond with Formation of a Zwitterion
J. W. M. van Outersterp, M. T. Garriga Oostenbrink, H. A. Nieuwenhuis, D. J. Stufkens, and F. Hartl
pp 6312 - 6318; DOI:
10.1021/ic00129a016
PDF
Syntheses and Structures of the Five-Coordinate Complexes [M(N-N)([9]aneS3)](PF6)2 (M = Pd, (N-N) = 2,2'-Bipyridine; M = Pt, (N-N) = 1,10-Phenanthroline; ([9]aneS3) = 1,4,7-Trithiacyclononane)
Hans Nikol, Hans-Beat Buergi, Kenneth I. Hardcastle, and Harry B. Gray
pp 6319 - 6322; DOI:
10.1021/ic00129a017
PDF
Spectroscopic and Electrochemical Studies of Rhenium(I) Bimetallic Complexes with Asymmetric Polypyridyl Bridging Ligands
Timothy J. Simpson and Keith C. Gordon
pp 6323 - 6329; DOI:
10.1021/ic00129a018
PDF
Luminescence Studies of Gold(I) Thiolate Complexes
Jennifer M. Forward, David Bohmann, John P. Fackler, and Richard J. Staples
pp 6330 - 6336; DOI:
10.1021/ic00129a019
PDF
Low-Energy Pyrocatechol to Cobalt(III) Electron Transfer in the Cobaloxime-Catalyzed Oxidation of 3,5-Di-tert-butylpyrocatechol
Laszlo I. Simandi, Terez Barna, Gy. Argay, and Tatiana L. Simandi
pp 6337 - 6340; DOI:
10.1021/ic00129a020
PDF
Terminal Sulfido, Selenido, and Tellurido Complexes of Tungsten
Daniel Rabinovich and Gerard Parkin
pp 6341 - 6361; DOI:
10.1021/ic00129a021
PDF
Model Studies of Nitrosyl Intermediates in the Catalytic Cycle of Dissimilatory Nitrite Reductases
Shinji Ozawa, Eigo Sakamoto, Taroh Ichikawa, Yoshihito Watanabe, and Isao Morishima
pp 6362 - 6370; DOI:
10.1021/ic00129a022
PDF
Hydrolysis of Monobutyltin Trialkoxides: Synthesis and Characterizations of {(BuSn)12O14(OH)6}(OH)2
Frederic Banse, F. Ribot, P. Toledano, J. Maquet, and C. Sanchez
pp 6371 - 6379; DOI:
10.1021/ic00129a023
PDF
Oxygenation of Substituted Phenols Using Molecular Oxygen and Cobalt(II) Cyclidene Complexes
Yanpei Deng and Daryle H. Busch
pp 6380 - 6386; DOI:
10.1021/ic00129a024
PDF
A Comparison of Solution, Microcrystalline Solid, and Thin Film Phase Voltammetry of [Co(mtas)2](X)n (mtas = bis(2-(dimethylarsino)phenyl)methylarsine; X = BF4-, n = 3; X = ClO4-, n = 2, 3; X = BPh4-, n = 2)
Alison J. Downard, Alan M. Bond, Lyall R. Hanton, and Graham A. Heath
pp 6387 - 6395; DOI:
10.1021/ic00129a025
PDF
Rhenium(V) Oxo-Alkoxide Complexes: Syntheses and Oxidation to Aldehydes
Darin D. DuMez and James M. Mayer
pp 6396 - 6401; DOI:
10.1021/ic00129a026
PDF
Pairwise Mobility of Metal-Metal Bonds in (MeC5H4)4Ru4S3(SMe)n+
Eric J. Houser, Anne Venturelli, Thomas B. Rauchfuss, and Scott R. Wilson
pp 6402 - 6408; DOI:
10.1021/ic00129a027
PDF
A Seven Coordinate Co-EDTA Complex. Crystal and Molecular Structure of Aquo(ethylenediaminetriacetatoacetic acid)cobalt(III) Dihydrate
Jeffrey D. Zubkowski, Dale L. Perry, Edward J. Valente, and Stevie Lott
pp 6409 - 6411; DOI:
10.1021/ic00129a028
PDF
Two-Electron Reductive Coupling of Acetonitrile To Form a (.mu.-Butane-2,3-diimino(2-)-N:N')Ditungsten Complex
Charles G. Young, Craig C. Philipp, Peter S. White, and Joseph L. Templeton
pp 6412 - 6414; DOI:
10.1021/ic00129a029
PDF

Issue 26


Diazabutadiene (DAB) Complexes of Aluminum. A New Mode of Coordination for a DAB Ligand
David S. Brown, Andreas Decken, Christopher A. Schnee, and Alan H. Cowley
pp 6415 - 6416; DOI:
10.1021/ic00130a001
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[Fe(en)3]2(Hg2Te9): A Novel Tellurometalate Containing One-Dimensional Chains of Weakly Bound Zintl Anions (Hg2Te9)4-
Brendan G. Rafferty, Jing Li, Suzanne Mulley, and Davide M. Proserpio
pp 6417 - 6418; DOI:
10.1021/ic00130a002
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Regioselective Fluorination of CB11H12-. New Weakly Coordinating Anions
Sergei V. Ivanov, Anthony J. Lupinetti, Susie M. Miller, Oren P. Anderson, Konstantin A. Solntsev, and Steven H. Strauss
pp 6419 - 6420; DOI:
10.1021/ic00130a003
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Application of Resonance Raman Spectroscopy to Electronic Structure in Metal Complex Excited States. Excited-State Ordering and Electron Delocalization in Dipyrido[3,2-a:2',3'-c]phenazine (dppz): Complexes of Re(I) and Ru(II)
Jon R. Schoonover, W. Douglas Bates, and Thomas J. Meyer
pp 6421 - 6422; DOI:
10.1021/ic00130a004
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Synthesis and Characterization of a Water soluble Metallopeptide That Resembles a Parallel .beta.-Pleated Sheet
Michael Y. Ogawa, Alexei B. Gretchikhine, Sunil-Datta Soni, and Steven M. Davis
pp 6423 - 6424; DOI:
10.1021/ic00130a005
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[Pt2(dppf)2(.mu.-S)2] as a Heterometallic Ligand. Simple Assembly of an Electroactive Interpolymetallic Complex [Pt2Tl(dppf)2(.mu.3-S)2]X (X = NO3, PF6) (dppf = 1,1'-bis(diphenylphosphino)ferrocene)
Meisheng Zhou, Yan Xu, Ai-Min Tan, Pak-Hing Leung, K. F. Mok, L. L. Koh, and T. S. Andy Hor
pp 6425 - 6429; DOI:
10.1021/ic00130a006
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Palladium-Assisted Cyano Substitution Reactions of (PMe2Ph)2Pd(B9H9As2) and (PMe2Ph)2Pd(B9C2H11). X-ray Crystal and Molecular Structures of 5-CN-1,1-(PMe2Ph)2-closo-1,2,3-PdAs2B9H8, 1-tBuNC-5-CN-1-(PMe2Ph)-closo-1,2,3-PdAs2B9H8, and 4,5-(CN)2-1,1-(PMe2Ph)2-closo-1,2,3-PdC2B9H9
Steve A. Jasper, John C. Huffman, and Lee J. Todd
pp 6430 - 6439; DOI:
10.1021/ic00130a007
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The Hexadentate Ligand 1,4,7-Tris(o-aminobenzyl)-1,4,7-triazacyclononane and Its Complexes with Zinc(II), Cadmium(II), and Mercury(II) in Solution and in the Solid State
Oliver Schlager, Karl Wieghardt, Hiltrud Grondey, Anna Rufinska, and Bernhard Nuber
pp 6440 - 6448; DOI:
10.1021/ic00130a008
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Divalent Transition Metal Complexes [LMII](ClO4)2 (M = Mn, Fe, Co, Ni, Cu, Pd) of the Hexadentate Ligand 1,4,7-Tris(o-aminobenzyl)-1,4,7-triazacyclononane (L)
Oliver Schlager, Karl Wieghardt, and Bernhard Nuber
pp 6449 - 6455; DOI:
10.1021/ic00130a009
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Trivalent Transition Metal Complexes [MIII(L-3H)] (M = Fe, Co) of the Triply Deprotonated Hexadentate Ligand 1,4,7-Tris(o-aminobenzyl)-1,4,7-triazacyclononane (L). Crystal Structure of [MnIV(L-3H)]BPh4
Oliver Schlager, Karl Wieghardt, and Bernhard Nuber
pp 6456 - 6462; DOI:
10.1021/ic00130a010
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Octadecanuclearity in Manganese Carboxylate Chemistry: Preparation and Properties of K4[Mn18O16(O2CPh)22(phth)2(H2O)4].cntdot.10MeCN
Rachel C. Squire, Sheila M. J. Aubin, Kirsten Folting, William E. Streib, George Christou, and David N. Hendrickson
pp 6463 - 6471; DOI:
10.1021/ic00130a011
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Synthesis, Stability, and Crystal Structure Studies of Some Ca2+, Cu2+, and Zn2+ Complexes of Macrocyclic Polyamino Carboxylates
Krishan Kumar, M. F. Tweedle, M. F. Malley, and J. Z. Gougoutas
pp 6472 - 6480; DOI:
10.1021/ic00130a012
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Ruthenium(II) Complexes with 1,4,5,8,9,12-Hexaazatriphenylene and 1,4,5,8-Tetraazaphenanthrene Ligands: Key Role Played by the Photoelectron Transfer in DNA Cleavage and Adduct Formation
Jean-Paul Lecomte, Andree Kirsch-De Mesmaeker, Martin M. Feeney, and John M. Kelly
pp 6481 - 6491; DOI:
10.1021/ic00130a013
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Kinetics and Mechanism of Metal-Substitution Reaction of Homodinuclear Mercury(II) Porphyrin with Zinc(II) with Particular Reference to a Heterodinuclear Metalloporphyrin Intermediate
Masaaki Tabata, Wakako Miyata, and Nurun Nahar
pp 6492 - 6496; DOI:
10.1021/ic00130a014
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Kinetic Isotope Effects on Metal to Nitrogen Proton Transfers
Kjell-Tore Smith, Mats Tilset, S. Soley Kristjansdottir, and Jack R. Norton
pp 6497 - 6504; DOI:
10.1021/ic00130a015
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Formation of Thioarsenide from the Reductive Coupling of Dithionite and Arsenite under Hydrothermal Conditions. Synthesis of (Ph4P)[Fe2(AsS)(CO)6]
Birinchi K. Das and Mercouri G. Kanatzidis
pp 6505 - 6508; DOI:
10.1021/ic00130a016
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Organotransition-Metal Metallacarboranes. 42. Synthesis and Cluster Fusion of Iron-Centered Tetradecker Sandwiches
Xiaotai Wang, Michal Sabat, and Russell N. Grimes
pp 6509 - 6513; DOI:
10.1021/ic00130a017
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Synthesis, Structural Characterization, and Spectroscopic Studies of Heterodimetallic [NBu4][(C6F5)3Pt(.mu.-Pb)(.mu.-X)Pt(C6F5)3] (X = Cl, OH) Complexes
Jose Maria Casas, Juan Fornies, Antonio Martin, Victor M. Orera, A. Guy Orpen, and Angel J. Rueda
pp 6514 - 6519; DOI:
10.1021/ic00130a018
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Intercalated Vanadyl Vanadates: Syntheses, Crystal Structures, and Magnetic Properties
Didier Riou and Gerard Ferey
pp 6520 - 6523; DOI:
10.1021/ic00130a019
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Application of X-ray Absorption Spectroscopy in Determining the Crystal Structure of Low-Dimensional Compounds. Iron Oxychloride and its Alkoxy Substituents
Jin-Ho Choy, Joo-Byoung Yoon, Dong-Kuk Kim, and Sung-Ho Hwang
pp 6524 - 6531; DOI:
10.1021/ic00130a020
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Control of the Thermal and Photochemical Aquation of the Hexacyanochromate(III) and Aquapentacyanochromate(III) Ions by Formation of a Supramolecular Structure with [32]ane-N8
Joao Sotomayor, A. Jorge Parola, Fernando Pina, Edoardo Zinato, Pietro Riccieri, M. Francesca Manfrin, and Luca Moggi
pp 6532 - 6537; DOI:
10.1021/ic00130a021
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Synthesis and X-ray Crystal Structures of {Mo(CO)(Et2PC2H4PEt2)2}2(.mu.-N2) with an End-On Bridging Dinitrogen Ligand and Mo(CO)(Bui2PC2H4PBui2)2 Containing an Agostic Mo.cntdot..cntdot..cntdot.H-C Interaction
Xiao-Liang Luo, Gregory J. Kubas, Carol J. Burns, Ray J. Butcher, and Jeffrey C. Bryan
pp 6538 - 6545; DOI:
10.1021/ic00130a022
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Structures and Electronic States of the Electron Donor-Acceptor Complexes NH3-X2 (X = F and Cl): An ab-Initio MO Study
Hiroto Tachikawa and Emiko Komatsu
pp 6546 - 6549; DOI:
10.1021/ic00130a023
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Models of the active site of dihydroorotase: structure of diaquabis(L-dihydroorotato)zinc(II) reveals an unexpected coordination mode for the L-dihydroorotato ligands
Trevor W. Hambley, Richard I. Christopherson, and Evan S. Zvargulis
pp 6550 - 6552; DOI:
10.1021/ic00130a024
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Crystal Structure of [LiBr.cntdot.Et2O]4: First Example of a Diethyl Ether-Solvated LiBr Lattice Fragment
Frank Neumann, Frank Hampel, and Paul v. Rague Schleyer
pp 6553 - 6555; DOI:
10.1021/ic00130a025
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Binding of Thioether Sulfur to Trivalent Chromium. A Family of CrS2N2O2 Complexes Derived from Acyclic Ligands
Sujay Pattanayak, Diganta Kumar Das, Partha Chakraborty, and Animesh Chakravorty
pp 6556 - 6558; DOI:
10.1021/ic00130a026
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B3H3X3+ (X = H, F, and Li): Ab Initio MO Study
Eluvathingal D. Jemmis and G. Subramanian
pp 6559 - 6561; DOI:
10.1021/ic00130a027
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Synthesis and Molecular Structure of a Pentacoordinated Nickel(II) Complex with a Mixed S2N3 Coordination Sphere
Rainer Hahn, Akira Nakamura, Koji Tanaka, and Yuushou Nakayama
pp 6562 - 6564; DOI:
10.1021/ic00130a028
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Metal .pi. Complexes of Benzene Derivatives. 46. Communication between Chromium(I) and Molybdenum(III) in the Hetera[3]metallocyclophane {[(Me2P-.eta.6-C6H5)2Cr](Pri-.eta.5-C5H4)MoCl2}+.bul..bul.
Christoph Elschenbroich, Thomas Isenburg, and Andreas Behrendt
pp 6565 - 6567; DOI:
10.1021/ic00130a029
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